Francium: the essentials
Francium occurs as a result of α disintegration of actinium. Francium is found in uranium minerals, and can be made artificially by bombarding thorium with protons. It is the most unstable of the first 101 elements. The longest lived isotope, 223Fr, a daughter of 227Ac, has a half-life of 22 minutes. This is the only isotope of francium occurring in nature, but at most there is only 20-30 g of the element present in the earth's crust at any one time. No weighable quantity of the element has been prepared or isolated. There are about 20 known isotopes.
This sample of uraninite contains some francium because of a steady-state decay chain. An estimate suggests there is about 10-20 grammes of francium (about 1 atom!) at any one time. Image adapted with permission from Prof James Marshall's (U. North Texas, USA) Walking Tour of the elements CD.
Francium: historical information
Francium was discovered in 1939 by Marguerite Perey of the Curie Institute in Paris, (France) but its existence was predicted by Mendeleev during the 1870's. Since its properties should track those of caesium rather closely, he called it eka-caesium. Marguerite Perey noticed an α decay product from actinium, now recognized as 22387Fr. This is the longest-lived isotope of actinium with a half life of about 22 minutes. She called the new element Francium after her country.
Francium around us Read more »
Francium has no biological role.
Very small amounts of francium are found in uranium ores. The longest lived isotope, 223Fr, a "daughter" of 227Ac, has a half-life of about 22 minutes. This is the only isotope of francium occurring in nature, but at most there is only 20-30 g of the element present in the earth's crust at any one time.
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Physical properties Read more »
- Density of solid: 2900 (estimated) kg m-3
- Molar volume: 77 (rough estimate based upon density estimate) cm3
- Thermal conductivity: 15 (estimate) W m‑1 K‑1
Heat properties Read more »
- Melting point: maybe about 300 [about 30 °C, estimate] K
- Boiling point: 871 [598 °C (1108 °F)] K
- Enthalpy of fusion: about 2 kJ mol-1
Crystal structure Read more »
The solid state structure of francium is: .
Francium: orbital properties Read more »
Francium atoms have 87 electrons and the shell structure is 22.214.171.124.18.8.1. The ground state electronic configuration of neutral Francium is [Rn].7s1 and the term symbol of Francium is 2S1/2.
- Pauling electronegativity: 0.7 (Pauling units)
- First ionisation energy: 380 kJ mol‑1
- Second ionisation energy: (no data) kJ mol‑1
Isolation: francium is vanishingly rare and is found only as very small traces in some uranium minerals. It has never been isolated as the pure element. As it is so radioactive, any amount formed would decompose to other elements.
Actinium decays by β decay most of the time but about 1% of the decay is by α decay. The "daughter" element of this reaction, which used to be called actinium-K, is now recognized as 22387Fr - the longest-lived isotope of actinium with a half life of about 22 minutes.
Francium isotopes Read more »