Argon - 18Ar: the essentials
Argon atoms have 18 electrons and the shell structure is 2.8.8. The ground state electronic configuration of neutral argon is [Ne].3s2.3p6 and the term symbol of argon is 1S0.
Argon is a colourless and odourless gas present to a very small extent in the atmosphere. Argon is very inert (indeed it is referred to as one of the noble gases) and is not known to form true chemical compounds. It makes a good atmosphere for working with air-sensitive materials since it is heavier than air and less reactive than N2. Today, the chemical symbol for argon is Ar but until 1957 its sybol was simply A.
Image adapted with permission from Prof James Marshall's (U. North Texas, USA) Walking Tour of the elements CD.
Argon: physical properties
Argon: heat properties
- Melting point: 83.8 [‑189.3 °C (‑308.7 °F)] K
- Boiling point: 87.3 [‑185.8 °C (‑302.4 °F)] K
- Enthalpy of fusion: 20.5 kJ mol-1
Argon: atom sizes
- Atomic radius (empirical): (no data) pm
- Molecular single bond covalent radius: 96 (coordination number 1,2) ppm
- van der Waals radius: 183 ppm
- Pauling electronegativity: (no data) (Pauling units)
- Allred Rochow electronegativity: 3.20 (Pauling units)
- Mulliken-Jaffe electronegativity: 3.19 (12.5% s orbital)
Argon: orbital properties
- First ionisation energy: 1520.57 kJ mol‑1
- Second ionisation energy: 2665.86 kJ mol‑1
- Third ionisation energy: 3930 kJ mol‑1
Argon: crystal structure
Argon: biological data
- Human abundance by weight: (no data) ppb by weight
Argon has no biological role.
Reactions of argon as the element with air, water, halogens, acids, and bases where known.
Argon: binary compounds
Binary compounds with halogens (known as halides), oxygen (known as oxides), hydrogen (known as hydrides), and other compounds of argon where known.
Argon: compound properties
Bond strengths; lattice energies of argon halides, hydrides, oxides (where known); and reduction potentials where known.
Argon: historyArgon was discovered by Sir William Ramsay, Lord Rayleigh in 1894 at UCL, London, England. Origin of name: from the Greek word "argos" meaning "inactive".
Argon isotopes are used as precursors in the production of radioisotopes. Ar-40 and Ar-38 are used in the production of radioactive K-38 which can be used as a blood flow tracer. Ar-40 is used in the production of radioactive Ar-41 which is used to trace gas flows.
Isolation: argon is present to a small extent in the atmosphere and is obtained as a byproduct from the liquefaction and separation of air. This would not normally be carried out in the laboratory and argon is available commercially in cylinders at high pressure.