Lanthanum: properties of free atoms

Lanthanum atoms have 57 electrons and the shell structure is  2.8.18.18.9.2.

The ground state electron configuration of ground state gaseous neutral lanthanum is  [Xe].5d1.6s2 and the term symbol is  2D3/2.

Atomic spectrum

 

A representation of the atomic spectrum of lanthanum.

Electronic configuration of neutral atomic lanthanum

Electronic configuration of lanthanum

The electronic configuration of lanthanum.

Kossel shell structure of lanthanum

The Kossel shell structure of lanthanum.

Ionisation Energies and electron affinity

The electron affinity of lanthanum is 48 kJ mol‑1. The ionisation energies of lanthanum are given below.

Ionisation energies of lanthanum
Ionisation energy number Enthalpy / kJ mol‑1
1st538.1
2nd1067
3rd1850.3
4th4819
5th5940

Effective Nuclear Charges

The following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.

Effective nuclear charges for lanthanum
1s55.87  
2s41.95 2p52.80  
3s37.94 3p38.14 3d43.06  
4s28.80 4p27.71 4d24.73 4f1.36
5s17.81 5p15.90 5d(no data)  
6s9.31 6p(no data)  
7s   

References

These effective nuclear charges, Zeff, are adapted from the following references:

  1. E. Clementi and D.L.Raimondi, J. Chem. Phys. 1963, 38, 2686.
  2. E. Clementi, D.L.Raimondi, and W.P. Reinhardt, J. Chem. Phys. 1967, 47, 1300.

Electron binding energies

Electron binding energies for lanthanum. All values of electron binding energies are given in eV. The binding energies are quoted relative to the vacuum level for rare gases and H2, N2, O2, F2, and Cl2 molecules; relative to the Fermi level for metals; and relative to the top of the valence band for semiconductors.
Label Orbital eV [literature reference]
K 1s38925 [1]
L I2s6266 [1]
L II2p1/25891 [1]
L III2p3/25483 [1]
M I3s1362 [2, values derived from reference 1]
M II3p1/21209 [2, values derived from reference 1]
M III3p3/21128 [2, values derived from reference 1]
M IV3d3/2853 [2]
M V3d5/2836 [2]
N I4s274.7 [2]
N II4p1/2205.8 [1]
N III4p3/2196 [2]
N IV4d3/2105.3 [2]
N V4d5/2102.5 [2]
N VI4f5/2 -
N VII4f7/2 -
O I5s34.3 [2]
O II5p1/219.3 [2]
O III5p3/216.8 [2]

Notes

I am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).

References

  1. J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels," Rev. Mod. Phys., 1967, 39, 125.
  2. M. Cardona and L. Ley, Eds., Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
  3. Gwyn Williams WWW table of values
  4. D.R. Lide, (Ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
  5. J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals," J. Electron Spectrosc. Relat. Phenom., 1980, 21, 275.

WebElements Shop

You can buy periodic table posters, mugs, T-shirts, fridge magnets, games, molecular models, and more at the WebElements shop