Niobium: properties of free atoms

Niobium atoms have 41 electrons and the shell structure is  2.8.18.12.1.

The ground state electron configuration of ground state gaseous neutral niobium is  [Kr].4d4.5s1 and the term symbol is  6D1/2.

Atomic spectrum

 

A representation of the atomic spectrum of niobium.

Electronic configuration of neutral atomic niobium

Electronic configuration of niobium

The electronic configuration of niobium.

Kossel shell structure of niobium

The Kossel shell structure of niobium.

Ionisation Energies and electron affinity

The electron affinity of niobium is 86.1 kJ mol‑1. The ionisation energies of niobium are given below.

Ionisation energies of niobium
Ionisation energy number Enthalpy / kJ mol‑1
1st652.1
2nd1380
3rd2416
4th3700
5th4877
6th9847
7th12100

Effective Nuclear Charges

The following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.

Effective nuclear charges for niobium
1s40.14  
2s30.13 2p36.98  
3s25.17 3p24.62 3d26.25  
4s15.28 4p14.08 4d11.24 4f(no data)
5s5.92 5p(no data) 5d(no data)  
6s(no data) 6p(no data)  
7s   

References

These effective nuclear charges, Zeff, are adapted from the following references:

  1. E. Clementi and D.L.Raimondi, J. Chem. Phys. 1963, 38, 2686.
  2. E. Clementi, D.L.Raimondi, and W.P. Reinhardt, J. Chem. Phys. 1967, 47, 1300.

Electron binding energies

Electron binding energies for niobium. All values of electron binding energies are given in eV. The binding energies are quoted relative to the vacuum level for rare gases and H2, N2, O2, F2, and Cl2 molecules; relative to the Fermi level for metals; and relative to the top of the valence band for semiconductors.
Label Orbital eV [literature reference]
K 1s18986 [1]
L I2s2698 [1]
L II2p1/22465 [1]
L III2p3/22371 [1]
M I3s466.6 [3]
M II3p1/2376.1 [3]
M III3p3/2360.6 [3]
M IV3d3/2205 [3]
M V3d5/2202.3 [3]
N I4s56.4 [3]
N II4p1/232.6 [3]
N III4p3/230.8 [3]

Notes

I am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).

References

  1. J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels," Rev. Mod. Phys., 1967, 39, 125.
  2. M. Cardona and L. Ley, Eds., Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
  3. Gwyn Williams WWW table of values
  4. D.R. Lide, (Ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
  5. J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals," J. Electron Spectrosc. Relat. Phenom., 1980, 21, 275.

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