Neodymium: properties of free atoms

Neodymium atoms have 60 electrons and the shell structure is  2.8.18.22.8.2.

The ground state electron configuration of ground state gaseous neutral neodymium is  [Xe].4f4.6s2 and the term symbol is  5I4.

Atomic spectrum

 

A representation of the atomic spectrum of neodymium.

Electronic configuration of neutral atomic neodymium

Electronic configuration of neodymium

The electronic configuration of neodymium.

Kossel shell structure of neodymium

The Kossel shell structure of neodymium.

Ionisation Energies and electron affinity

The electron affinity of neodymium is 50 kJ mol‑1. The ionisation energies of neodymium are given below.

Ionisation energies of neodymium
Ionisation energy number Enthalpy / kJ mol‑1
1st533.1
2nd1040
3rd2130
4th3900

Effective Nuclear Charges

The following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.

Effective nuclear charges for neodymium
1s58.81  
2s44.22 2p55.76  
3s40.34 3p40.69 3d46.16  
4s30.99 4p30.01 4d26.81 4f22.27
5s18.74 5p16.96 5d(no data)  
6s9.31 6p(no data)  
7s   

References

These effective nuclear charges, Zeff, are adapted from the following references:

  1. E. Clementi and D.L.Raimondi, J. Chem. Phys. 1963, 38, 2686.
  2. E. Clementi, D.L.Raimondi, and W.P. Reinhardt, J. Chem. Phys. 1967, 47, 1300.

Electron binding energies

Electron binding energies for neodymium. All values of electron binding energies are given in eV. The binding energies are quoted relative to the vacuum level for rare gases and H2, N2, O2, F2, and Cl2 molecules; relative to the Fermi level for metals; and relative to the top of the valence band for semiconductors.
Label Orbital eV [literature reference]
K 1s43569 [1]
L I2s7126 [1]
L II2p1/26722 [1]
L III2p3/26208 [1]
M I3s1575 [1]
M II3p1/21403 [1]
M III3p3/21297 [1]
M IV3d3/21003.3 [2]
M V3d5/2980.4 [2]
N I4s319.2 [2]
N II4p1/2243.3 [1]
N III4p3/2224.6 [1]
N IV4d3/2120.5 [2]
N V4d5/2120.5 [2]
N VI4f5/21.5 [1]
N VII4f7/21.5 [1]
O I5s37.5 [1]
O II5p1/221.1 [1]
O III5p3/221.1 [1]

Notes

I am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).

References

  1. J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels," Rev. Mod. Phys., 1967, 39, 125.
  2. M. Cardona and L. Ley, Eds., Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
  3. Gwyn Williams WWW table of values
  4. D.R. Lide, (Ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
  5. J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals," J. Electron Spectrosc. Relat. Phenom., 1980, 21, 275.

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