Rhodium: properties of free atoms

Rhodium atoms have 45 electrons and the shell structure is  2.8.18.16.1.

The ground state electron configuration of ground state gaseous neutral rhodium is  [Kr].4d85s1 and the term symbol is  4F9/2.

Atomic spectrum

 

A representation of the atomic spectrum of rhodium.

Electronic configuration of neutral atomic rhodium

Electronic configuration of rhodium

The electronic configuration of rhodium.

Kossel shell structure of rhodium

The Kossel shell structure of rhodium.

Ionisation Energies and electron affinity

The electron affinity of rhodium is 109.7 kJ mol‑1. The ionisation energies of rhodium are given below.

Ionisation energies of rhodium
Ionisation energy number Enthalpy / kJ mol‑1
1st719.7
2nd1740
3rd2997

Effective Nuclear Charges

The following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.

Effective nuclear charges for rhodium
1s44.08  
2s33.15 2p40.94  
3s28.44 3p28.15 3d30.41  
4s18.58 4p17.14 4d13.44 4f(no data)
5s6.64 5p(no data) 5d(no data)  
6s(no data) 6p(no data)  
7s   

References

These effective nuclear charges, Zeff, are adapted from the following references:

  1. E. Clementi and D.L.Raimondi, J. Chem. Phys. 1963, 38, 2686.
  2. E. Clementi, D.L.Raimondi, and W.P. Reinhardt, J. Chem. Phys. 1967, 47, 1300.

Electron binding energies

Electron binding energies for rhodium. All values of electron binding energies are given in eV. The binding energies are quoted relative to the vacuum level for rare gases and H2, N2, O2, F2, and Cl2 molecules; relative to the Fermi level for metals; and relative to the top of the valence band for semiconductors.
Label Orbital eV [literature reference]
K 1s23220 [1]
L I2s3412 [1]
L II2p1/23146 [1]
L III2p3/23004 [1]
M I3s628.1 [3]
M II3p1/2521.3 [3]
M III3p3/2496.5 [3]
M IV3d3/2311.9 [3]
M V3d5/2307.2 [3]
N I4s81.4 [2, values derived from reference 1]
N II4p1/250.5 [3]
N III4p3/247.3 [3]

Notes

I am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).

References

  1. J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels," Rev. Mod. Phys., 1967, 39, 125.
  2. M. Cardona and L. Ley, Eds., Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
  3. Gwyn Williams WWW table of values
  4. D.R. Lide, (Ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
  5. J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals," J. Electron Spectrosc. Relat. Phenom., 1980, 21, 275.

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