Gallium: properties of free atoms

Gallium atoms have 31 electrons and the shell structure is  2.8.18.3.

The ground state electron configuration of ground state gaseous neutral gallium is  [Ar].3d10.4s2.4p1 and the term symbol is  2P1/2.

Atomic spectrum

 

A representation of the atomic spectrum of gallium.

Electronic configuration of neutral atomic gallium

Electronic configuration of gallium

The electronic configuration of gallium.

Kossel shell structure of gallium

The Kossel shell structure of gallium.

Ionisation Energies and electron affinity

The electron affinity of gallium is 28.9 kJ mol‑1. The ionisation energies of gallium are given below.

Ionisation energies of gallium
Ionisation energy number Enthalpy / kJ mol‑1
1st578.8
2nd1979.3
3rd2963
4th6180

Effective Nuclear Charges

The following are "Clementi-Raimondi" effective nuclear charges, Zeff. Follow the hyperlinks for more details and for graphs in various formats.

Effective nuclear charges for gallium
1s30.31  
2s22.60 2p27.09  
3s17.00 3p16.20 3d15.09  
4s7.07 4p6.22 4d(no data) 4f(no data)
5s(no data) 5p(no data) 5d(no data)  
6s(no data) 6p(no data)  
7s   

References

These effective nuclear charges, Zeff, are adapted from the following references:

  1. E. Clementi and D.L.Raimondi, J. Chem. Phys. 1963, 38, 2686.
  2. E. Clementi, D.L.Raimondi, and W.P. Reinhardt, J. Chem. Phys. 1967, 47, 1300.

Electron binding energies

Electron binding energies for gallium. All values of electron binding energies are given in eV. The binding energies are quoted relative to the vacuum level for rare gases and H2, N2, O2, F2, and Cl2 molecules; relative to the Fermi level for metals; and relative to the top of the valence band for semiconductors.
Label Orbital eV [literature reference]
K 1s10367 [1]
L I2s1299 [2, values derived from reference 1]
L II2p1/21143.2 [3]
L III2p3/21116.4 [3]
M I3s159.5 [3]
M II3p1/2103.5 [3]
M III3p3/2100 [3]
M IV3d3/218.7 [3]
M V3d5/218.7 [3]

Notes

I am grateful to Gwyn Williams (Jefferson Laboratory, Virginia, USA) who provided the electron binding energy data. The data are adapted from references 1-3. They are tabulated elsewhere on the WWW (reference 4) and in paper form (reference 5).

References

  1. J. A. Bearden and A. F. Burr, "Reevaluation of X-Ray Atomic Energy Levels," Rev. Mod. Phys., 1967, 39, 125.
  2. M. Cardona and L. Ley, Eds., Photoemission in Solids I: General Principles (Springer-Verlag, Berlin) with additional corrections, 1978.
  3. Gwyn Williams WWW table of values
  4. D.R. Lide, (Ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
  5. J. C. Fuggle and N. Mårtensson, "Core-Level Binding Energies in Metals," J. Electron Spectrosc. Relat. Phenom., 1980, 21, 275.

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