Selenium: selenium dioxide
selenium dioxide is known by the following synonyms:
- selenium dioxide
- selenium(IV) oxide
- selenium oxide
The oxidation number of selenium in selenium dioxide is 4.
- Formula: SeO2
- Hill system formula: O2Se1
- CAS registry number: [7446-08-4]
- Formula weight: 110.959
- Class: oxide
- Colour: white
- Appearance: crystalline solid
- Melting point: 340°C
- Boiling point: 315°C
- Density: 3950 kg m-3
Selenium(IV) dioxide is formed by the combustion of elemental selenium in a mixture of oxygen and nitrogen dioxide. The yield is about 80%. Selenium(IV) dioxide is a white crystalline material that melts at 340°C.
Solid state structure
- Geometry of selenium:
- Prototypical structure:
Isotope pattern for SeO2
THe chart below shows the calculated isotope pattern for the formula SeO2 with the most intense ion set to 100%.
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.