Tetraphosphorus trisulphide

  • Formula: P4S3
  • Hill system formula: P4S3
  • CAS registry number: [1314-51-8]
  • Formula weight: 220.093
  • Class: sulphide
  • Colour: yellow-green
  • Appearance:
  • Melting point: 174°C
  • Boiling point: 408°C
  • Density: 2030 kg m-3

The following are some synonyms of tetraphosphorus trisulphide:

  • tetraphosphorus trisulphide
  • phosphorus sulphide
  • phosphorus sulfide
  • phosphorus trisulfide
  • phosphorus trisulphide
  • tetraphosphorus trisulfide

The oxidation number of phosphorus in tetraphosphorus trisulphide is .


Not available

Solid state structure

  • Geometry of phosphorus: 3 coordinate: pyramidal
  • Prototypical structure:

Crystal structure of tetraphosphorus trisulphide

Element analysis

The table shows element percentages for P4S3 (tetraphosphorus trisulphide).

Element %
P 56.29
S 43.71

Isotope pattern for P4S3

The chart below shows the calculated isotope pattern for the formula P4S3 with the most intense ion set to 100%.


The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

Explore periodic propertes from these links