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Barium compounds: barium dichloride
The barium in barium dichloride formally is in the oxidation state 2.

Barium dichloride
- Formula as often written: BaCl2
- Hill system formula: Ba1Cl2
- CAS registry number: [10361-37-2]
- Formula weight: 208.232
- Class: chloride
Synonyms
- barium dichloride
- barium(II) chloride
- barium chloride
Physical properties
- Colour: white
- Appearance: crystalline solid
- Melting point: 962°C
- Boiling point: 1560°C
- Density: 3900 kg m-3
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Element analysis
Element percentages for the elements in barium dichloride
| Element |
% |
| Ba |
65.95 |
| Cl |
34.05 |
Synthesis
Barium chloride is made by the neutralization of barium hydroxide with HCl in water. The product crystallizes as the hydrate BaCl2.2H2O [10326-27-9]. If this heated, dehydration to anhydrous BaCl2 occurs.
Ba(OH)2 + 2HCl(aq) → BaCl2(aq) + 2H2O
Solid state structure
- Geometry of barium: 4 coordinate: tetrahedral
- Prototypical structure: CaF2 (fluorite)

Isotope pattern
What follows is the calculated isotope pattern for the BaCl2 unit with the most intense ion set to 100%.
Formula: Ba1Cl2
mass %
200 0.1 201 0.0 202 0.2 203 0.0 204 3.2 __ 205 8.6 ____ 206 12.2 ______ 207 20.1 __________ 208 100.0 __________________________________________________ 209 10.2 _____ 210 60.6 ______________________________ 211 1.5 _ 212 9.5 _____
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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