WebElements mini logoChemistry: WebElements Periodic Table: Professional Edition: Thallium: key information
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Thallium

81
Tl
204.3833(2)
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The essentials

Description speak description of thallium (requires RealPlayer)

Here is a brief description of thallium.

thallium

When freshly exposed to air, thallium exhibits a metallic lustre, but soon develops a bluish-grey tinge, resembling lead in appearance. A heavy oxide builds up on thallium if left in air, and in the presence of water the hydroxide is formed. The metal is very soft and malleable. It can be cut with a knife.

The element and its compounds are toxic and should be handled carefully. Thallium may cause cancer.

Nearing Zero cartoon for thallium
Nearing Zero cartoon included by kind permission of Nick Kim.

Isolation

Here is a brief summary of the isolation of thallium.

Thallium metal would not normally be made in the laboratory as it is available commercially. Crude thallium is present as a component in flue dust along with arsenic, cadmium, indium, germanium, lead, nickel, selenium, tellurium, and zinc. This is done by dissolving in dilute acid, precipitating out lead sulphate, and then adding HCl to precipitate thallium chloride, TlCl. Further purification can be achieve by electrolysis of soluble thallium salts.

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compounds
Fluorides
Chlorides
Bromides
Iodides
Hydrides
Oxides
Sulfides
Selenides
Tellurides
Nitrides
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Document served: Friday 9th May, 2008