WebElements mini logoChemistry: WebElements Periodic Table: Professional Edition: Calcium: key information
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Calcium

20
Ca
40.078(4)
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The essentials

Description speak description of calcium (requires RealPlayer)

Here is a brief description of calcium.

calcium
This sample is from The Elements Collection, an attractive and safely packaged collection of the 92 naturally occurring elements that is available for sale.

Calcium is a metallic element, fifth in abundance in the earth's crust, of which it forms more than 3%. It is an essential constituent of leaves, bones, teeth, and shells.

The metal is a silvery colour and is rather hard. Chemically it is one of the alkaline earth elements; it readily forms a white coating of nitride in air, reacts with water, burns with a yellow-red flame, forming largely the nitride.

Calcium does not occur free in nature. Calcium is found mostly as limestone, gypsum and fluorite. Stalagmites and stalactites contain calcium carbonate.

Isolation

Here is a brief summary of the isolation of calcium.

Calcium metal is readily available commercially and there is no need to make it in the laboratory. Commercially it can be made by the electrolysis of molten calcium chloride, CaCl2.

cathode: Ca2+(l) + 2e- → Ca anode: Cl-(l) → 1/2Cl2 (g) + e-

The calcium chloride is made by the action of hydrochloric acid upon calcium carbonate. Calcium chloride is also a byproduct in the Solway process used to make sodium carbonate.

CaCO3 + 2HCl → CaCl2 + H2O + CO2

Alternatively, and on small scale, calcium can be made through the reduction of CaO with aluminium or of CaCl2 with sodium metal

6CaO + 2Al→ 3Ca + Ca3Al2O6

CaCl2 + 2Na→ Ca + 2NaCl

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compounds
Fluorides
Chlorides
Bromides
Iodides
Hydrides
Oxides
Sulfides
Selenides
Tellurides
Nitrides
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Document served: Friday 9th May, 2008