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Bond enthalpies in gaseous diatomic species

The bond energy in the gaseous diatomic species CaCa is <= 46 kJ mol-1. The following values refer to neutral heterodiatomic molecules in the gas phase. These numbers may well differ considerably from, say, single bond energies in a solid. All values are given in kJ mol-1.

Bond enthalpies in gaseous diatomic species

Group 1 diatomic CaX bond enthalpies

View charts... CaX bond Enthalpy [/ kJ mol-1]
CaH 167.8
CaLi 84.9 ±8.4
CaNa  
CaK  
CaRb  
CaCs  
  CaFr  

Group 2 diatomic CaX bond enthalpies

View charts... CaX bond Enthalpy [/ kJ mol-1]
CaBe  
CaMg  
CaCa <= 46
CaSr  
CaBa  
  CaRa  

Group 13 diatomic CaX bond enthalpies

View charts...CaX bondEnthalpy [/ kJ mol-1]
CaB  
CaAl  
CaGa  
CaIn  
CaTl  

Group 14 diatomic CaX bond enthalpies

View charts...CaX bondEnthalpy [/ kJ mol-1]
CaC  
CaSi  
CaGe  
CaSn  
CaPb  

Group 15 diatomic CaX bond enthalpies

View charts...CaX bondEnthalpy [/ kJ mol-1]
CaN  
CaP  
CaAs  
CaSb  
CaBi  

Group 16 diatomic CaX bond enthalpies

View charts...CaX bondEnthalpy [/ kJ mol-1]
CaO 402.1 ±16.7
CaS 337.6 ±18.8
CaSe  
CaTe  
 CaPo 

Group 17 diatomic CaX bond enthalpies

View charts...CaX bondEnthalpy [/ kJ mol-1]
CaF 527 ±21
CaCl 409 ±9
CaBr 310.9 ±9.2
CaI 284.7 ±8.4
 CaFr 

Group 18 diatomic CaX bond enthalpies

View charts...CaX bondEnthalpy [/ kJ mol-1]
CaHe  
 CaNe  
CaAr  
CaKr  
CaXe  
 CaRn  

Notes

I am grateful to Professor J.A. Kerr (University of Birmingham, UK) for the provision of the bond strengths of diatomic molecules data.

The values given here are at 298 K. All values are quoted in kJ mol-1. Generally, these data were obtained by spectroscopic or mass spectrometric means. You should consult reference 1 for further details. A note of caution: the strength of, say, the C-H bond in the gaseous diatomic species CH (not an isolable species) is not necessarily, the same as the strength of a C-H bond in, say, methane.

The strongest bond for a diatomic species is that of carbon monoxide, CO (1076.5 ± 0.4 kJ mol-1). The strongest bond for a homonuclear diatomic species is that of dinitrogen, N2 (945.33 ± 0.59 kJ mol-1).

References

  1. J.A. Kerr in CRC Handbook of Chemistry and Physics 1999-2000 : A Ready-Reference Book of Chemical and Physical Data (CRC Handbook of Chemistry and Physics, D.R. Lide, (ed.), CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.
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