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Compounds of sulphur:
sulphur (II) fluoride
- Formula as commonly written: SF2
- Hill system formula: F2S1
- CAS registry number: [13814-25-0]
- Formula weight: 70.063
- Class: fluoride
Synonyms
- sulphur (II) fluoride
- sulphur difluoride
- sulphur fluoride
Physical properties
- Colour:
- Appearance: decomposes below room temperature
- Melting point: (decomposes below room temperature)
- Boiling point:
- Density:
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Element analysis and oxidation numbers
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
| Element |
% |
Formal oxidation state |
Formal electronic configuration |
|
F |
54.23 |
-1 |
[He].2s2.2p6 |
|
S |
45.77 |
2 |
[Ne].3s2.3p2 |
Synthesis
Not available
Solid state structure
- Geometry of sulphur: 2 coordinate: bent
- Prototypical structure:

Isotope pattern
What follows is the calculated isotope pattern for the SF2 unit with the most intense ion set to 100%.
Formula: S1F2
mass %
70 100.0 __________________________________________________ 71 0.8 72 4.4 __ 73 0.0 74 0.0
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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