Ruthenium 44 Ru 101.07(2)   Switch element to... actinium aluminium aluminum americium antimony argon arsenic astatine barium berkelium beryllium bismuth bohrium boron bromine cadmium caesium calcium californium carbon cerium cesium chlorine chromium cobalt copper curium darmstadtium dubnium dysprosium einsteinium erbium europium fermium fluorine francium gadolinium gallium germanium gold hafnium hassium helium holmium hydrogen indium iodine iridium iron krypton lanthanum lawrencium lead lithium lutetium magnesium manganese meitnerium mendelevium mercury molybdenum neodymium neon neptunium nickel niobium nitrogen nobelium osmium oxygen palladium phosphorus platinum plutonium polonium potassium praseodymium promethium protactinium radium radon rhenium rhodium roentgenium rubidium ruthenium rutherfordium samarium scandium seaborgium selenium silicon silver sodium strontium sulfur sulphur tantalum technetium tellurium terbium thallium thorium thulium tin titanium tungsten ununbium ununhexium ununoctium ununpentium ununquadium ununtrium uranium vanadium xenon ytterbium yttrium zinc zirconium Go adjacent... Mn Fe Co Tc Ru Rh Re Os Ir

Compounds of ruthenium:

ruthenium (O) carbonyl

• Formula as commonly written: Ru(CO)₅
• Hill system formula: C₅O₅Ru₁
• CAS registry number: [16406-48-7]
• Formula weight: 241.12
• Class: carbonyl

Synonyms

• ruthenium (O) carbonyl
• ruthenium carbonyl
• ruthenium pentacarbonyl

Physical properties

• Colour: colourless
• Appearance: liquid
• Melting point: -22°C
• Boiling point:
• Density:

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Element analysis and oxidation numbers

Synthesis

This was first made through the direct carbonylation of ruthenium metal with carbon monoxide at 180⁸C at 200 atm.

Isotope pattern

What follows is the calculated isotope pattern for the Ru(CO)₅ unit with the most intense ion set to 100%.

Formula: Ru₁C₅O₅

mass  %
236  16.9 ________
237   1.0 
238   5.9 ___
239  39.1 ____________________
240  40.8 ____________________
241  54.6 ___________________________
242 100.0 __________________________________________________
243   6.2 ___
244  58.3 _____________________________
245   3.4 __
246   0.7 
247   0.0 

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

• R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
• N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
• F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
• A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
• R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
• A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
• A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
• J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
• D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
• J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
• J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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