Compounds of platinum:
platinum (II) chloride
Formula as commonly written: Pt6 Cl12
Hill system formula: Cl12 Pt6
CAS registry number: [10025-65-7]
Formula weight: 1595.9
Class: chloride
Synonyms
platinum (II) chloride
platinum chloride
platinum chloride (beta form)
platinum dichloride
Physical properties
Colour: olive green
Appearance: crystalline solid (alpha form is black-red)
Melting point: 581°C (decomposes)
Boiling point:
Density: 6000 kg m-3
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Element analysis and oxidation numbers
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p -block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
Element
%
Formal oxidation state
Formal electronic configuration
Cl
26.66
-1
[Ne].3s2 .3p6
Pt
73.34
2
[Xe].4f14 .5d8
Synthesis
Not available
Isotope pattern
What follows is the calculated isotope pattern for the Pt6 Cl12 unit with the most intense ion set to 100%.
Formula: Pt6 Cl12
mass %
1581 0.0 1582 0.0 1583 0.0 1584 0.2 1585 0.6 1586 1.9 _ 1587 4.5 __ 1588 9.5 _____ 1589 17.5 _________ 1590 29.0 ______________ 1591 43.4 ______________________ 1592 59.5 ______________________________ 1593 75.2 ______________________________________ 1594 88.4 ____________________________________________ 1595 96.9 ________________________________________________ 1596 100.0 __________________________________________________ 1597 97.0 ________________________________________________ 1598 89.2 _____________________________________________ 1599 77.6 _______________________________________ 1600 64.4 ________________________________ 1601 50.7 _________________________ 1602 38.3 ___________________ 1603 27.5 ______________ 1604 19.0 __________ 1605 12.5 ______ 1606 8.0 ____ 1607 4.8 __ 1608 2.8 _ 1609 1.6 _ 1610 0.8 1611 0.4 1612 0.2 1613 0.1 1614 0.0 1615 0.0 1616 0.0 1617 0.0
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
R.T. Sanderson in Chemical Periodicity , Reinhold, New York, USA, 1960.
N.N. Greenwood and A. Earnshaw in Chemistry of the Elements , 2nd edition, Butterworth, UK, 1997.
F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry , John Wiley & Sons, 1999.
A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry , Pergamon, Oxford, UK, 1973.
R.W.G. Wyckoff, in Crystal Structures , volume 1, Interscience, John Wiley & Sons, 1963.
A.R.West in Basic solid state chemistry Chemistry , John Wiley & Sons, 1999.
A.F. Wells in Structural inorganic chemistry , 4th edition, Oxford, UK, 1975.
J.D.H. Donnay, (ed.) in Crystal data determinative tables , ACA monograph number 5, American Crystallographic Association, USA, 1963.
D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics , CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry , volumes 1-16, Longmans, London, UK, 1922-1937.
J.E. Macintyre (ed.) in Dictionary of inorganic compounds , volumes 1-3, Chapman & Hall, London, UK, 1992.