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Compounds of polonium:
polonium (II) chloride
- Formula as commonly written: PoCl2
- Hill system formula: Cl2Po1
- CAS registry number: [60816-56-0]
- Formula weight: 280.888
- Class: chloride
Synonyms
- polonium (II) chloride
- polonium chloride
- polonium dichloride
Physical properties
- Colour: dark ruby red
- Appearance: solid
- Melting point: 355°C
- Boiling point: 130°C
- Density:
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Element analysis and oxidation numbers
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
| Element |
% |
Formal oxidation state |
Formal electronic configuration |
|
Cl |
25.24 |
-1 |
[Ne].3s2.3p6 |
|
Po |
74.76 |
2 |
[Xe].4f14.5d10.6s2.6p2 |
Synthesis
Formed during the decomposition of PoCl2 at temperatures in excess of 200°C.
Solid state structure
- Geometry of polonium:
- Prototypical structure:

Isotope pattern
What follows is the calculated isotope pattern for the PoCl2 unit with the most intense ion set to 100%.
Formula: Po1Cl2
mass %
279 100.0 __________________________________________________ 280 0.0 281 64.0 ________________________________ 282 0.0 283 10.2 _____
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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