WebElements mini logoChemistry: WebElements Periodic Table: Professional Edition: Mercury: compound data [mercury (II) sulphide]
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Mercury

80
Hg
200.59(2)
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Compounds of mercury:

mercury (II) sulphide

  • Formula as commonly written: HgS
  • Hill system formula: Hg1S1
  • CAS registry number: [1344-48-5]
  • Formula weight: 232.656
  • Class: sulphide

Synonyms

  • mercury (II) sulphide
  • mercury sulphide
  • cinnabar
  • mercuric sulphide

Physical properties

  • Colour: scarlet red (high temperature form black)
  • Appearance: crystalline solid
  • Melting point: 344°C (red to black form)
  • Boiling point: 580°C
  • Density: 8170 kg m-3

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Element analysis and oxidation numbers

For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
Element % Formal oxidation state Formal electronic configuration
Hg 86.22 2 [Xe].4f14.5d10
S 13.78 -2 [Ne].3s2.3p6

Synthesis

Not available

Solid state structure

  • Geometry of mercury:
  • Prototypical structure:

Crystal structure of mercury (II) sulphide

Isotope pattern

What follows is the calculated isotope pattern for the HgS unit with the most intense ion set to 100%.

Formula: Hg1S1

mass  %
228   0.5 
229 0.0
230 32.2 ________________
231 54.7 ___________________________
232 76.4 ______________________________________
233 45.5 _______________________
234 100.0 __________________________________________________
235 2.7 _
236 26.5 _____________
237 0.2
238 1.0
239 0.0
240 0.0

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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