Mercury 80 Hg 200.59(2)   Switch element to... actinium aluminium aluminum americium antimony argon arsenic astatine barium berkelium beryllium bismuth bohrium boron bromine cadmium caesium calcium californium carbon cerium cesium chlorine chromium cobalt copper curium darmstadtium dubnium dysprosium einsteinium erbium europium fermium fluorine francium gadolinium gallium germanium gold hafnium hassium helium holmium hydrogen indium iodine iridium iron krypton lanthanum lawrencium lead lithium lutetium magnesium manganese meitnerium mendelevium mercury molybdenum neodymium neon neptunium nickel niobium nitrogen nobelium osmium oxygen palladium phosphorus platinum plutonium polonium potassium praseodymium promethium protactinium radium radon rhenium rhodium roentgenium rubidium ruthenium rutherfordium samarium scandium seaborgium selenium silicon silver sodium strontium sulfur sulphur tantalum technetium tellurium terbium thallium thorium thulium tin titanium tungsten ununbium ununhexium ununoctium ununpentium ununquadium ununtrium uranium vanadium xenon ytterbium yttrium zinc zirconium Go adjacent... Ag Cd In Au Hg Tl Rg Uub Uut

Compounds of mercury:

mercury (I) chloride

• Formula as commonly written: Hg₂Cl₂
• Hill system formula: Cl₂Hg₂
• CAS registry number: [10112-91-1]
• Formula weight: 472.085
• Class: chloride

Synonyms

• mercury (I) chloride
• mercury chloride
• mercury monochloride
• calomel
• dimercury dichloride
• mercurous chloride

Physical properties

• Colour: white
• Appearance: crystalline solid. Light sensitive
• Melting point: 525°C (turns yellow on heating)
• Boiling point: 383°C
• Density: 7160 kg m^-3

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Element analysis and oxidation numbers

Synthesis

Not available

Solid state structure

• Geometry of mercury: 2 coordinate: linear
• Prototypical structure:

Isotope pattern

What follows is the calculated isotope pattern for the Hg₂Cl₂ unit with the most intense ion set to 100%.

Formula: Hg₂Cl₂

mass  %
464   0.1 
465   0.2 
466   3.9 __
467  12.4 ______
468  29.6 _______________
469  45.4 _______________________
470  74.5 _____________________________________
471  83.5 __________________________________________
472 100.0 __________________________________________________
473  77.8 _______________________________________
474  88.3 ____________________________________________
475  36.0 __________________
476  48.9 ________________________
477   7.9 ____
478  15.6 ________
479   0.7 
480   2.6 _
481   0.0 
482   0.2 

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

• R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
• N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
• F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
• A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
• R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
• A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
• A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
• J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
• D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
• J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
• J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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