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Compounds of hafnium:
hafnium (IV) selenide
- Formula as commonly written: HfSe2
- Hill system formula: Hf1Se2
- CAS registry number: [12162-21-9]
- Formula weight: 336.41
- Class: selenide
Synonyms
- hafnium (IV) selenide
- hafnium diselenide
- hafnium selenide
Physical properties
- Colour: brown
- Appearance: crystalline solid
- Melting point:
- Boiling point:
- Density: 7500 kg m-3
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Element analysis and oxidation numbers
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
| Element |
% |
Formal oxidation state |
Formal electronic configuration |
|
Hf |
53.06 |
4 |
[Xe].4f14 |
|
Se |
46.94 |
-2 |
[Ar].3d10.4s2.4p6 |
Synthesis
Not available
Solid state structure
- Geometry of hafnium:
- Prototypical structure:

Isotope pattern
What follows is the calculated isotope pattern for the HfSe2 unit with the most intense ion set to 100%.
Formula: Hf1Se2
mass %
324 0.0 325 0.0 326 0.1 327 0.2 328 0.7 329 1.5 _ 330 4.1 __ 331 6.9 ___ 332 15.8 ________ 333 21.0 __________ 334 42.7 _____________________ 335 40.7 ____________________ 336 79.3 ________________________________________ 337 53.0 __________________________ 338 100.0 __________________________________________________ 339 33.1 _________________ 340 73.9 _____________________________________ 341 8.1 ____ 342 20.0 __________ 343 0.7 344 1.7 _
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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