WebElements mini logoChemistry: WebElements Periodic Table: Professional Edition: Copper: compound data [copper (I) chloride]
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Copper

29
Cu
63.546(3)
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Compounds of copper:

copper (I) chloride

  • Formula as commonly written: CuCl
  • Hill system formula: Cl1Cu1
  • CAS registry number: [7758-89-6]
  • Formula weight: 98.999
  • Class: chloride

Synonyms

  • copper (I) chloride
  • copper chloride
  • cuprous chloride

Physical properties

  • Colour: white
  • Appearance: crystalline solid. Turns green in moist air.
  • Melting point: 422°C; 430°C
  • Boiling point: 1490°C
  • Density: 4.14 (25°C relative to water at 4°C)

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Element analysis and oxidation numbers

For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
Element % Formal oxidation state Formal electronic configuration
Cl 35.81 -1 [Ne].3s2.3p6
Cu 64.19 1 [Ar].3d10

Synthesis

Not available

Solid state structure

  • Geometry of copper:
  • Prototypical structure: ZnS (sphalerite, zinc blende)

Crystal structure of copper (I) chloride

Isotope pattern

What follows is the calculated isotope pattern for the CuCl unit with the most intense ion set to 100%.

Formula: Cu1Cl1

mass  %
 98 100.0 __________________________________________________
99 0.0
100 76.6 ______________________________________
101 0.0
102 14.3 _______

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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