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Compounds of cadmium:
cadmium (II) nitride
- Formula as commonly written: Cd3N2
- Hill system formula: Cd3N2
- CAS registry number: [12380-95-9]
- Formula weight: 365.246
- Class: nitride
Synonyms
- cadmium (II) nitride
- cadmium nitride
- tricadmium dinitride
Physical properties
- Colour: black
- Appearance: powder
- Melting point:
- Boiling point:
- Density:
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Element analysis and oxidation numbers
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
| Element |
% |
Formal oxidation state |
Formal electronic configuration |
|
Cd |
92.33 |
2 |
[Kr].4d10 |
|
N |
7.67 |
-3 |
[He].2s2.2p6 |
Synthesis
Cadmium nitride is made by heating cadmium amide.
3Cd(NH2)2(s) (180°C) → Cd3N2(s) + 4NH3(g)
Isotope pattern
What follows is the calculated isotope pattern for the Cd3N2 unit with the most intense ion set to 100%.
Formula: Cd3N2
mass %
350 0.1 351 0.1 352 0.1 353 0.1 354 0.7 355 0.9 356 2.6 _ 357 3.2 __ 358 7.4 ____ 359 9.8 _____ 360 20.5 __________ 361 27.5 ______________ 362 49.3 _________________________ 363 59.0 ______________________________ 364 84.8 __________________________________________ 365 83.3 __________________________________________ 366 100.0 __________________________________________________ 367 76.7 ______________________________________ 368 79.4 ________________________________________ 369 44.0 ______________________ 370 43.9 ______________________ 371 13.3 _______ 372 16.5 ________ 373 1.6 _ 374 3.5 __ 375 0.0 376 0.3
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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