WebElements mini logoChemistry: WebElements Periodic Table: Professional Edition: Cadmium: compound data [cadmium (II) nitride]
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Cadmium

48
Cd
112.411(8)
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Compounds of cadmium:

cadmium (II) nitride

  • Formula as commonly written: Cd3N2
  • Hill system formula: Cd3N2
  • CAS registry number: [12380-95-9]
  • Formula weight: 365.246
  • Class: nitride

Synonyms

  • cadmium (II) nitride
  • cadmium nitride
  • tricadmium dinitride

Physical properties

  • Colour: black
  • Appearance: powder
  • Melting point:
  • Boiling point:
  • Density:

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Element analysis and oxidation numbers

For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
Element % Formal oxidation state Formal electronic configuration
Cd 92.33 2 [Kr].4d10
N 7.67 -3 [He].2s2.2p6

Synthesis

Cadmium nitride is made by heating cadmium amide.

3Cd(NH2)2(s) (180°C) → Cd3N2(s) + 4NH3(g)

Isotope pattern

What follows is the calculated isotope pattern for the Cd3N2 unit with the most intense ion set to 100%.

Formula: Cd3N2

mass  %
350   0.1 
351 0.1
352 0.1
353 0.1
354 0.7
355 0.9
356 2.6 _
357 3.2 __
358 7.4 ____
359 9.8 _____
360 20.5 __________
361 27.5 ______________
362 49.3 _________________________
363 59.0 ______________________________
364 84.8 __________________________________________
365 83.3 __________________________________________
366 100.0 __________________________________________________
367 76.7 ______________________________________
368 79.4 ________________________________________
369 44.0 ______________________
370 43.9 ______________________
371 13.3 _______
372 16.5 ________
373 1.6 _
374 3.5 __
375 0.0
376 0.3

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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