|
|
Compounds of barium:
barium (II) chloride 2-water
- Formula as commonly written: BaCl2.2H2O
- Hill system formula: Ba1Cl2H4O2
- CAS registry number: [10326-27-9]
- Formula weight: 244.263
- Class: chloride
aquo
Synonyms
- barium (II) chloride 2-water
- barium chloride 2-water
- barium dichloride 2-water
Physical properties
- Colour: white
- Appearance: crystalline solid
- Melting point: 120°C (dehydrates)
- Boiling point:
- Density: 3097 kg m-3
Suppliers
Coming soon...
Element analysis and oxidation numbers
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
| Element |
% |
Formal oxidation state |
Formal electronic configuration |
|
Ba |
56.22 |
2 |
[Xe] |
|
Cl |
29.03 |
-1 |
[Ne].3s2.3p6 |
|
H |
1.65 |
1 |
1s0 |
|
O |
13.10 |
-2 |
[He].2s2.2p6 |
Synthesis
Barium chloride dihydrate is made by the neutralization of barium hydroxide with HCl in water. The product crystallizes as the dihydrate BaCl2.2H2O. If this heated, dehydration to anhydrous BaCl2 occurs.
Ba(OH)2 + 2HCl(aq) → BaCl2(aq) + 2H2O
Isotope pattern
What follows is the calculated isotope pattern for the BaCl2.2H2O unit with the most intense ion set to 100%.
Formula: Ba1Cl2H4O2
mass %
236 0.1 237 0.0 238 0.2 239 0.0 240 3.2 __ 241 8.6 ____ 242 12.2 ______ 243 20.1 __________ 244 100.0 __________________________________________________ 245 10.4 _____ 246 61.0 ______________________________ 247 1.6 _ 248 9.8 _____ 249 0.0 250 0.0
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
|
|
|