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Compounds of barium:
barium (II) bromide 2-water
- Formula as commonly written: BaBr2.2H2O
- Hill system formula: Ba1Br2H4O2
- CAS registry number: [7791-28-8]
- Formula weight: 333.166
- Class: bromide
aquo
Synonyms
- barium (II) bromide 2-water
- barium bromide 2-water
- barium dibromide 2-water
Physical properties
- Colour: white
- Appearance: crystalline solid
- Melting point: 75°C (decomposes, loses H2O)
- Boiling point: 120
- Density: 3700 kg m-3
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Element analysis and oxidation numbers
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
| Element |
% |
Formal oxidation state |
Formal electronic configuration |
|
Ba |
41.22 |
2 |
[Xe] |
|
Br |
47.97 |
-1 |
[Ar].3d10.4s2.4p6 |
|
H |
1.21 |
1 |
1s0 |
|
O |
9.60 |
-2 |
[He].2s2.2p6 |
Synthesis
Barium bromide is made by the neutralization of barium carbonate with HBr in water. The product crystallizes as the hydrate BaBr2.2H2O. If this heated, dehydration to anhydrous BaBr2 occurs.
BaCO3 + 2HBr(aq) → BaBr2(aq)
Isotope pattern
What follows is the calculated isotope pattern for the BaBr2.2H2O unit with the most intense ion set to 100%.
Formula: Ba1Br2H4O2
mass %
324 0.1 325 0.0 326 0.2 327 0.0 328 1.8 _ 329 4.5 __ 330 8.6 ____ 331 16.3 ________ 332 60.7 ______________________________ 333 19.2 __________ 334 100.0 __________________________________________________ 335 7.4 ____ 336 46.5 _______________________ 337 0.1 338 0.2
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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