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Compounds of gold:
gold (III) bromide
- Formula as commonly written: [AuBr3]2
- Hill system formula: Au2Br6
- CAS registry number: [10294-28-7]
- Formula weight: 873.357
- Class: bromide
Synonyms
- gold (III) bromide
- gold bromide
- gold tribromide
- auric bromide
- digold hexabromide
Physical properties
- Colour: red-brown
- Appearance: crystalline solid
- Melting point: 160°C (decomposes)
- Boiling point:
- Density:
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Element analysis and oxidation numbers
For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.
| Element |
% |
Formal oxidation state |
Formal electronic configuration |
|
Au |
45.11 |
3 |
[Xe].4f14.5d8 |
|
Br |
54.89 |
-1 |
[Ar].3d10.4s2.4p6 |
Synthesis
Au + Br2 (140°C) → Au2Br6
dimer [11092-53-8]
Solid state structure
- Geometry of gold:
- Prototypical structure:

Isotope pattern
What follows is the calculated isotope pattern for the [AuBr3]2 unit with the most intense ion set to 100%.
Formula: Au2Br6
mass %
868 5.4 ___ 869 0.0 870 31.7 ________________ 871 0.0 872 77.1 _______________________________________ 873 0.0 874 100.0 __________________________________________________ 875 0.0 876 73.0 ____________________________________ 877 0.0 878 28.4 ______________ 879 0.0 880 4.6 __
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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