Technetium: the essentials

Since its discovery, searches for the element technetium in terrestrial materials have been made without success. Technetium has been found in the spectrum of S-, M-, and N-type stars, and its presence in stellar matter is leading to new theories of the production of heavy elements in the stars.

Technetium is a silvery-grey metal that tarnishes slowly in moist air. Until 1960, technetium was available only in small amounts. The chemistry of technetium is related to that of rhenium.

technetium
There is a thin plating of technetium-99 on this disk and this radioactive sample gives about 200 counts per minute. Image adapted with permission from Prof James Marshall's (U. North Texas, USA) Walking Tour of the elements CD.

Technetium: historical information

Technetium was discovered by Carlo Perrier, Emilio Segre in 1937 at Italy. Origin of name: from the Greek word "technikos" meaning "artificial".

Element 43 (technetium) was predicted on the basis of the periodic table by Mendeleev. He suggested that it should be very similar to manganese and gave it the name ekamanganese. Technetium was erroneously reported as having been discovered in 1925, at which time it was named masurium. The element was actually discovered by C. Perrier and Emilio Gino Segre in Italy in 1937. It was found in a sample of molybdenum bombarded by deuterons. Technetium was the first element to be produced artificially and all its isotopes are radioactive. It is named after the Greek technetos, artificial.

Technetium around us Read more »

Technetium has no biological role. Technetium does not occur naturally in the biosphere and so normally never presents a risk. All technetium compounds should be regarded as highly toxic, largely because of its radiological toxicity.

Technetium has been found in the spectra of S-, M-, and N-type stars, but is not found in earth's geosphere.

Abundances for cobalt in a number of different environments. More abundance data »
Location ppb by weight ppb by atoms Links
Universe (no data) (no data) Chemical elements abundance by weight in the universe on a miniature periodic table spark table
Crustal rocks (no data) (no data) Chemical elements abundance by weight in the earth's crust on a miniature periodic table spark table
Human (no data) ppb by weight (no data) atoms relative to C = 1000000 Chemical elements abundance by weight in humans on a miniature periodic table spark table

Physical properties Read more »

Heat properties Read more »

Crystal structure Read more »

The solid state structure of technetium is: hcp (hexagonal close-packed).

Technetium: orbital properties Read more »

Technetium atoms have 43 electrons and the shell structure is 2.8.18.14.1. The ground state electronic configuration of neutral Technetium is [Kr].4d6.5s1 and the term symbol of Technetium is 6S5/2.

Isolation

Isolation: it is never necessary to make a sample of techntium anywhere other than specialist laboratories. This is because technetium is radioactive. Technetium is a byproduct of the nuclear industry and is a product of uranium decay. Alternatively it can be made by the bombardment of molydenum targets with deuterium nuclei.

Because of the scale of the nuclear industry it is possible to make quite large quantities of technetium (kilograms). The metal itself may be made by the reaction of the sulphide Tc2S7 with hydrogen at 1100°C or of the pertechnate NH4TcO4 with hydrogen.

Technetium isotopes Read more »

Table. Stables isotopes of cobalt.
Isotope Mass
/Da
Natural
abund.
(atom %)
Nuclear
spin (I)
Nuclear
magnetic
moment (μ/μN)
nil

WebElements Shop

You can buy periodic table posters, mugs, T-shirts, fridge magnets, games, molecular models, and more at the WebElements shop