Sodium: bond enthalpies in gaseous diatomic species

The bond energy in the gaseous diatomic species NaNa is 73.60 ±0.25 kJ mol-1.

The following values refer to neutral heterodiatomic molecules in the gas phase. These numbers may well differ considerably from, say, single bond energies in a solid. All values are given in kJ mol-1.

Table of diatomic NaX bond enthalpies. All values are quoted in kJ mol-1. Each formula in the table (NaO, NaF, and so on) is a link - select these to see visual periodicity representations for bond enthalpies involving sodium to elements of your choice.

Period 1

NaH             NaHe
185.69 ±0.25              

Period 2

NaLi NaBe NaB NaC NaN NaO NaF NaNe
87.181 ±0.001         256.1 ±16.7 519  

Period 3

NaNa NaMg NaAl NaSi NaP NaS NaCl NaAr
73.60 ±0.25           412.1 ±8  

Period 4

NaK NaCa NaGa NaGe NaAs NaSe NaBr NaKr
65.994 ±0.008           367.4 ±0.8  

Period 5

NaRb NaSr NaIn NaSn NaSb NaTe NaI NaXe
63.25           304.2 ±2.1  

Period 6

NaCs NaBa NaTl NaPb NaBi NaPo NaAt NaRn
63.2 ±1.3              

Period 7

NaFr NaRa            
               

Notes

I am grateful to Professor J.A. Kerr (University of Birmingham, UK) for the provision of the bond strengths of diatomic molecules data.

The values given here are at 298 K. All values are quoted in kJ mol-1. Generally, these data were obtained by spectroscopic or mass spectrometric means. You should consult reference 1 for further details. A note of caution: the strength of, say, the C-H bond in the gaseous diatomic species CH (not an isolable species) is not necessarily, the same as the strength of a C-H bond in, say, methane.

The strongest bond for a diatomic species is that of carbon monoxide, CO (1076.5 ± 0.4 kJ mol-1). The strongest bond for a homonuclear diatomic species is that of dinitrogen, N2 (945.33 ± 0.59 kJ mol-1).

References

  1. J.A. Kerr in CRC Handbook of Chemistry and Physics 1999-2000 : A Ready-Reference Book of Chemical and Physical Data (CRC Handbook of Chemistry and Physics, D.R. Lide, (ed.), CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.

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sodium atomic number