Ruthenium: bond enthalpies in gaseous diatomic species

The bond energy in the gaseous diatomic species RuRu is (no data) kJ mol-1.

The following values refer to neutral heterodiatomic molecules in the gas phase. These numbers may well differ considerably from, say, single bond energies in a solid. All values are given in kJ mol-1.

Table of diatomic RuX bond enthalpies. All values are quoted in kJ mol-1. Each formula in the table (RuO, RuF, and so on) is a link - select these to see visual periodicity representations for bond enthalpies involving ruthenium to elements of your choice.

Period 1

RuH             RuHe
234 ±21              

Period 2

RuLi RuBe RuB RuC RuN RuO RuF RuNe
    446.9 ±20.9 616.2 ±10.5   528.4 ±41.8 402  

Period 3

RuNa RuMg RuAl RuSi RuP RuS RuCl RuAr
      397.1 ±20.0        

Period 4

RuK RuCa RuGa RuGe RuAs RuSe RuBr RuKr
               

Period 5

RuRb RuSr RuIn RuSn RuSb RuTe RuI RuXe
               

Period 6

RuCs RuBa RuTl RuPb RuBi RuPo RuAt RuRn
               

Period 7

RuFr RuRa            
               

Notes

I am grateful to Professor J.A. Kerr (University of Birmingham, UK) for the provision of the bond strengths of diatomic molecules data.

The values given here are at 298 K. All values are quoted in kJ mol-1. Generally, these data were obtained by spectroscopic or mass spectrometric means. You should consult reference 1 for further details. A note of caution: the strength of, say, the C-H bond in the gaseous diatomic species CH (not an isolable species) is not necessarily, the same as the strength of a C-H bond in, say, methane.

The strongest bond for a diatomic species is that of carbon monoxide, CO (1076.5 ± 0.4 kJ mol-1). The strongest bond for a homonuclear diatomic species is that of dinitrogen, N2 (945.33 ± 0.59 kJ mol-1).

References

  1. J.A. Kerr in CRC Handbook of Chemistry and Physics 1999-2000 : A Ready-Reference Book of Chemical and Physical Data (CRC Handbook of Chemistry and Physics, D.R. Lide, (ed.), CRC Press, Boca Raton, Florida, USA, 81st edition, 2000.

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ruthenium atomic number