Crystallography
X-ray study of the alkali metals at low temperatures
Cold working of sodium metal converts body centred sodium metal to a mixture of a hexagonal form and body centred sodium at 5 K. The hexagonal from converts back to the body-centred form at 100-100 K.
Cold working of lithium metal converts body centred lithium metal to a mixture of a hexagonal form and body centred lithium at 78 K.
Potassium, rubidium, and caesium retain their body centred structure after cooling
X-ray study of the alkali metals at low temperatures, , Acta Crystallographica, 08/1956, Volume 9, Issue 8, p.671 - 677, (1956)Crystallographic Data. 177. Uranium Mononitride
Crystal structure of uranium nitride, UN. The structure is face-centered cubic with a lattice constant of 4889 ± 0.001 Å at 26°C and sodium chloride type. The theoretical density is 14315 kg m–3, and the U—N bond distance for coordination number 6 is 2.4449 Å.
Crystallographic Data. 177. Uranium Mononitride, , Analytical Chemistry, 01/1959, Volume 31, Issue 1, p.156 - 157, (1959)Die Kristallstrukturen von ScCl3, TiCl3 und VCl3
ScCl3, TiCl3 und VCl3 kristallisieren hexagonal-rhomboedrisch in dem gleichen Gitter wie FeCl3 (DO5-Typ).
Die Kristallstrukturen von ScCl3, TiCl3 und VCl3, , Zeitschrift für anorganische Chemie, 05/1947, Volume 253, Issue 3-4, p.218 - 225, (1947)Tb3N@C84 : An Improbable, Egg-Shaped Endohedral Fullerene that Violates the Isolated Pentagon Rule
Abstract.The structure of isomer 2 of Tb3N@C84 has been determined through single-crystal X-ray diffraction on Tb3N@C84·NiII(OEP)·2(C6H6). The carbon cage has a distinct egg shape due to the presence of a single pair of fused pentagons at one apex of the molecule. Thus, although 24 IPR structures are available to the C84 cage, Nature utilizes one of the 51 568 isomeric structures that do not conform to the IPR for this unusual molecule. The Tb3N portion of isomer 2 of Tb3N@C84 is strictly planar. One Tb atom is nestled within the fold of the fused pentagons, while the other Tb atoms are disordered over four pairs of sites.
Tb3N@C84 : An Improbable, Egg-Shaped Endohedral Fullerene that Violates the Isolated Pentagon Rule, , Journal of the American Chemical Society, 09/2006, Volume 128, Issue 35, p.11352 - 11353, (2006)Gypsum
Gypsum, cover from Geology; April 2007; v. 35; no. 4; p. 327-330; DOI: 10.1130/G23393A.11
- 1. Formation of natural gypsum megacrystals in Naica, Mexico,
, Geology, 2007, Volume 35, Issue 4, p.327, (2007)









