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Element number 114: flerovium (symbol Fl) and element number 116: livermorium (symbol Lv)
The International Union of Pure and Applied Chemistry (IUPAC) has recommended names for elements 114 and 116. Scientists from the Lawrence Livermore National Laboratory (LLNL) and at Dubna proposed the names as Flerovium for element 114 and Livermorium for element 116.
Flerovium (atomic symbol Fl) was chosen to honor Flerov Laboratory of Nuclear Reactions, where superheavy elements, including element 114, were synthesized. Georgiy N. Flerov (1913-1990) was a renowned physicist who discovered the spontaneous fission of uranium and was a pioneer in heavy-ion physics. He is the founder of the Joint Institute for Nuclear Research. In 1991, the laboratory was named after Flerov - Flerov Laboratory of Nuclear Reactions (FLNR).
Livermorium (atomic symbol Lv) was chosen to honor Lawrence Livermore National Laboratory (LLNL) and the city of Livermore, Calif. A group of researchers from the Laboratory, along with scientists at the Flerov Laboratory of Nuclear Reactions, participated in the work carried out in Dubna on the synthesis of superheavy elements, including element 116. (Lawrencium -- Element 103 -- was already named for LLNL's founder E.O. Lawrence.)
In 1989, Flerov and Ken Hulet (1926-2010) of LLNL established collaboration between scientists at LLNL and scientists at FLNR; one of the results of this long-standing collaboration was the synthesis of elements 114 and 116.
The creation of elements 116 and 114 involved smashing calcium ions (with 20 protons each) into a curium target (96 protons) to create element 116. Element 116 decayed almost immediately into element 114. The scientists also created element 114 separately by replacing curium with a plutonium target (94 protons).
The creation of elements 114 and 116 generate hope that the team is on its way to the "island of stability," an area of the periodic table in which new heavy elements would be stable or last long enough for applications to be found.
The new names were submitted to the IUPAC in late October. The new names will not be official until about five months from now when the public comment period is over.
Nobel Chemistry Prize 2006
The Royal Swedish Academy of Sciences has decided to award the Nobel Prize in Chemistry for 2006 to Prof Roger D. Kornberg of Stanford University (Stanford, CA, USA) "for his studies of the molecular basis of eukaryotic transcription".
In order for our bodies to make use of the information stored in the genes, a copy must first be made and transferred to the outer parts of the cells. There it is used as an instruction for protein production – it is the proteins that in their turn actually construct the organism and its function. The copying process is called transcription. Roger Kornberg was the first to create an actual picture of how transcription works at a molecular level in the important group of organisms called eukaryotes (organisms whose cells have a well-defined nucleus). Mammals like ourselves are included in this group, as is ordinary yeast.
Transcription is necessary for all life. This makes the detailed description of the mechanism that Roger Kornberg provides exactly the kind of "most important chemical discovery" referred to by Alfred Nobel in his will.
If transcription stops, genetic information is no longer trans ferred into the different parts of the body. Since these are then no longer renewed, the organism dies within a few days. This is what happens in cases of poisoning by certain toadstools, like the death cap, since the toxin stops the transcription process. Understanding of how transcription works also has a fundamental medical importance. Disturbances in the transcription process are involved in many human illnesses such as cancer, heart disease and various kinds of inflammation.
The capacity of stem cells to develop into different types of specific cells with well-defined functions in different organs, is also linked to how the transcription is regulated. Understanding more about the transcription process is therefore important for the development of different therapeutic applications of stem cells.
Forty-seven years ago, the then twelve-year-old Roger Kornberg came to Stockholm to see his father, Arthur Kornberg, receive the Nobel Prize in Physiology or Medicine (1959) for his studies of how genetic information is transferred from one DNA-molecule to another. Kornberg senior had described how genetic information is transferred from a mother cell to its daughters. What Roger Kornberg himself has now done is to describe how the genetic information is copied from DNA into what is called messenger-RNA. The messenger-RNA carries the information out of the cell nucleus so that it can be used to construct the proteins.
Kornberg's contribution has culminated in his creation of detailed crystallographic pictures describing the transcription apparatus in full action in a eukaryotic cell. In his pictures (all of them created since 2000) we can see the new RNA-strand gradually developing, as well as the role of several other molecules necessary for the transcription process. The pictures are so detailed that separate atoms can be distinguished and this makes it possible to understand the mechanisms of transcription and how it is regulated.
Germanium nanocrystals melt 200°C higher in glass than in bulk
Scientists at the Lawrence Berkeley National Laboratory in California, USA, have discovered that nanocrystals of germanium embedded in silica glass don't melt until the temperature rises almost 200 degrees Kelvin above the melting temperature of germanium in bulk. What's even more surprising, these melted nanocrystals have to be cooled more than 200 K below the bulk melting point before they resolidify. Such a large and nearly symmetrical "hysteresis" -- the divergence of melting and freezing temperatures above and below the bulk melting point -- has never before been observed for embedded nanoparticles.
"Melting and freezing points for materials in bulk have been well understood for a long time," says Eugene Haller (one of the authors) , "but whenever an embedded nanoparticle's melting point goes up instead of down, it requires an explanation. With our observations of germanium in amorphous silica and the application of a classical thermodynamic theory that successfully explains and predicts these observations, we've made a good start on a general explanation of what have until now been regarded as anomalous events."
The research was conducted because the properties of germanium nanoparticles embedded in amorphous silicon dioxide matrices have promising applications. "Germanium nanocrystals in silica have the ability to accept charge and hold it stably for long periods, a property which can be used in improved computer memory systems. Moreover, germanium dioxide (germania) mixed with silicon dioxide (silica) offers particular advantages for forming optical fibers for long-distance communication."1
- 1. Large Melting-Point Hysteresis of Ge Nanocrystals Embedded in SiO2,
, Physical Review Letters, Volume 97, Number 15, p.155701, (2006)
Synthesis of the isotopes of elements 118 and 116 in the Cf249 and Cm245+Ca48 fusion reactions
Element 118 discovery retracted
The team of Berkeley Lab scientists that announced two years ago (1999) the observation of what appeared to be Element 118 (heaviest undiscovered transuranic element at the time) has retracted its original paper after several confirmation experiments failed to reproduce the results. This means that the pages for element 118 and parts of the data for element 116 are wrong.
