Calcium

Synthesis of a new element with atomic number Z=117

A paper has just been accepted (5 April 2010) for publication in Physical Review Letters.1

International team discovers element 117

A new chemical element has been added to the Periodic Table: A paper on the discovery of element 117 has been accepted for publication in Physical Review Letters.

Oak Ridge National Laboratory is part of a team that includes the Joint Institute of Nuclear Research (Dubna, Russia), the Research Institute for Advanced Reactors (Dimitrovgrad), Lawrence Livermore National Laboratory, Vanderbilt University and the University of Nevada Las Vegas. ORNL's role included production of the berkelium-249 isotope necessary for the target, which was subjected to an extended, months-long run at the heavy ion accelerator facility at Dubna, Russia.

"Without the berkelium target, there could have been no experiment," says ORNL Director of Strategic Capabilities Jim Roberto, who is a principal author on the PRL paper and who helped initiate the experiment. The berkelium was produced at the High Flux Isotope Reactor and processed at the adjoining Radiochemical Engineering & Development Laboratory as part of the most recent campaign to produce californium-252, a radioisotope widely used in industry and medicine.

"Russia had proposed this experiment in 2004, but since we had no californium production at the time, we couldn't supply the berkelium. With the initiation of californium production in 2008, we were able to implement a collaboration," Roberto says.
Professor Joe Hamilton of Vanderbilt University (who helped establish the Joint Institute for Heavy Ion Research at ORNL) introduced Roberto to Yuri Oganessian of Russia's JINR. Five months of the Dubna JINR U400 accelerator's calcium-48 beam - one of the world's most powerful - was dedicated to the project.

The massive effort identified a total of six atoms of element 117 and the critical reams of data that substantiate their existence.
The two-year experimental campaign began with a 250-day irradiation in HFIR, producing 22 milligrams of berkelium-249, which has a 320-day half-life. The irradiation was followed by 90 days of processing at REDC to separate and purify the berkelium. The Bk-249 target was prepared at Dimitrovgrad and then bombarded for 150 days at the Dubna facility. Lawrence Livermore, which now has been involved in the discovery of six elements with Dubna (113, 114, 115, 116, 117, and 118), contributed data analysis, and the entire team was involved in the assessment of the results.

This is the second element that ORNL has had a role in discovering, joining element 61, promethium, which was discovered at the Graphite Reactor during the Manhattan project and reported in 1946. ORNL, by way of its production of radioisotopes for research, has contributed to the discovery of a total of seven new elements.

Members of the ORNL team include the Physics Division's Krzysztof Rykaczewsi, Porter Bailey of the Nonreactor Nuclear Facilities Division, and Dennis Benker, Julie Ezold, Curtis Porter and Frank Riley of the Nuclear S&T Division. Roberto says the success of the element-117 campaign underscores the value of international collaborations in science.
"This use of ORNL isotopes and Russian accelerators is a tremendous example of the value of working together," he says. "The 117 experiment paired one of the world's leading research reactors--capable of producing the berkelium target material--with the exceptional heavy ion accelerator and detection capabilities at Dubna."

Islands of Stability

Roberto also says the experiment, in addition to discovering a new chemical element, has pushed the Periodic Table further into the neutron-rich regime for heaviest elements. "New isotopes observed in these experiments continue a trend toward higher lifetimes for increased neutron numbers, providing evidence for the proposed "island of stability" for super-heavy nuclei," he says. "Because the half-lives are getting longer, there is potential to study the chemistry of these nuclei," Roberto says. "These experiments and discoveries essentially open new frontiers of chemistry."

—Bill Cabage

The news about the claim was announced in a press release from the Oak Ridge National Laboratory.

Synthesis and decay properties of superheavy elements

Abstract: A fundamental outcome of modern nuclear theory is the prediction of the "island of stability" in the region of hypothetical superheavy elements. A significant enhancement in nuclear stability at approaching the closed shells with Z = 114 (possibly 120 and 122) and N = 184 is expected for the nuclei with large neutron excess. For this reason, for the synthesis of nuclei with Z = 112-116 and 118, we chose the reactions 238U, 242,244Pu, 243Am, 245,248Cm, and 249Cf + 48Ca, which are characterized by fusion products with a maximal neutron excess. The formation and decay properties of the heaviest nuclei were registered with the use of a gas-filled recoil separator installed at a 48Ca-beam of the heavy-ion cyclotron. The new nuclides mainly undergo sequential α-decay, which ends with spontaneous fission (SF). The total time of decay ranges from 0.5 ms to ~1 d, depending on the proton and neutron numbers in the synthesized nuclei. The atomic number of the new elements 115 and 113 was confirmed also by an independent radiochemical experiment based on the identification of the neutron-rich isotope 268Db (TSF ~ 30 h), the final product in the chain of α-decays of the odd-odd parent nucleus 288115. The comparison of the decay properties of 29 new nuclides with Z = 104-118 and N = 162-177 gives evidence of the decisive influence of the structure of superheavy elements on their stability with respect to different modes of radioactive decay. The investigations connected with the search for superheavy elements in Nature are also presented.

Synthesis and decay properties of superheavy elements, Oganessian, Yuri , Pure and Applied Chemistry, 2006, Volume 78, Issue 5, p.889 - 904, (2006)

The Group 2 elements

The Group 2 elements are called the alkaline earth metals. The Group 2 elements are:

The electronic configuration of the elements all consist of two s-electrons outside an inner core of electron corresponding to the previous inert gas: the group configuration is therefore ns2.

Welcome back element 118 (ununoctium)

Experiments conducted at the Flerov Laboratory of Nuclear Reactions (Joint Institute for Nuclear Research) at Dubna in Russia indicate that element 118 (ununoctium, Uuo) was produced. Not too much though, one atom in the spring of 2002 and two more in 2005.1,2

The 2002 experiment involved firing a beam of 4820Ca at 24998Cf. The experiment took 4 months and involved a beam of 2.5 x 1019 calcium ions to produce the single event believed to be the synthesis of 294118Uuo.

24998Cf + 4820Ca → 294118Uuo + 31n

This ununoctium isotope loses three alpha particles in rapid succesion:

294118Uuo → 290116Uuh + 42He (1.29 milliseconds)

290116Uuh → 286114Uuq + 42He (14.4 milliseconds)

286114Uuq → 282112Uub + 42He (230 milliseconds)

The 282112Uub species then undergoes spontaneous fragmentation (denoted SF) to other species. It took a few years to carry out enough research to properly characterize the decompoition products.

In 2005 a similar experiment but with more sensitive detectors and a total beam dose of 1.6 x 1019 calcium ions resulted in the detection of two further events arising from the formation of 294118Uuo.

This work is particularly significant given the scandal associated with the first report (now withdrawn) of element 118.

Drink milk!

Virginia Tech (USA) researchers found that calcium intake among US adolescents has remained constant, if inadequate, since the 1970s and does not appear to be linked to soft drink consumption. Milk consumption among adolescent girls is low, with this group falling far below recommended dietary levels of calcium consumption. So drink some milk!

Conclusion: carbonated soft drink consumption among adolescent girls is modest and does not appear to be linked to decreased calcium intake. The analyses in this paper show that creative effective, efficient, and targeted policies should be considered to help adolescent girls increase calcium intake. Making low-fat milk products, flavored milks, calcium-fortified beverages and foods more attractive and available will help encourage girls to consume more of this important mineral. When adequate calcium intake is not achieved through foods, health professionals should consider recommending calcium supplements.

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