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Helicity inversion and redox chemistry of chiral manganese(II) cubanes

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,12917-12925
DOI: 10.1039/C4DT01590H, PaperClaire Deville, Matteo Granelli, Alan M. Downward, Celine Besnard, Laure Guenee, Alan F. Williams
N-methylation of a benzimidazole ligand switches the helicity of a tetranuclear manganese complex and changes the redox behavior.
The content of this RSS Feed (c) The Royal Society of Chemistry

Stability and toxicity of heteroleptic organometallic Bi(V) complexes towards Leishmania major

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,12904-12916
DOI: 10.1039/C4DT00957F, PaperYih Ching Ong, Victoria L. Blair, Lukasz Kedzierski, Philip C. Andrews
A series of organometallic bismuth(V) dicarboxylates, [BiPh3(O2CR[prime or minute])2], were synthesised and evaluated for their anti-leishmanial activity. The complexes are effective against parasite promastigotes (0.6-2.5 [small mu ]M), but prone to slow reductive decomposition.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and characterisation of first row transition metal complexes of functionalized 1,2,4-benzothiadiazines

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,12996-13005
DOI: 10.1039/C4DT01413H, PaperEwan R. Clark, Muhammad U. Anwar, Bryce J. Leontowicz, Yassine Beldjoudi, John J. Hayward, Wesley T. K. Chan, Emma L. Gavey, Melanie Pilkington, Eli Zysman-Colman, Jeremy M. Rawson
The 3-(2[prime or minute]-pyridyl)-benzo-1,2,4-thiadiazine ligand forms a range of N,N[prime or minute]-chelate complexes with first row transition metal ligands.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and characterization of the ZnO/mpg-C3N4 heterojunction photocatalyst with enhanced visible light photoactivity

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13105-13114
DOI: 10.1039/C4DT01347F, PaperDaimei Chen, Kewei Wang, Tiezhen Ren, Hao Ding, Yongfa Zhu
The photocatalytic activity enhancement of the ZnO/mpg-C3N4 is due to the high separation and easy transfer of photogenerated electron-hole pairs.
The content of this RSS Feed (c) The Royal Society of Chemistry

Facile synthesis of novel MoS2@SnO2 hetero-nanoflowers and enhanced photocatalysis and field-emission properties

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13136-13144
DOI: 10.1039/C4DT01436G, PaperJinzhu Li, Ke Yu, Yinghua Tan, Hao Fu, Qingfeng Zhang, Weitao Cong, Changqing Song, Haihong Yin, Ziqiang Zhu
A novel MoS2@SnO2 hetero-nanoflower was successfully synthesized by a facile hydrothermal method. The composite showed more excellent photocatalytic and field emission properties than that of MoS2.
The content of this RSS Feed (c) The Royal Society of Chemistry

Au nanoparticles in carbon nanotubes with high photocatalytic activity for hydrocarbon selective oxidation

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,12982-12988
DOI: 10.1039/C4DT01077A, PaperJuan Liu, Ruihua Liu, Haitao Li, Weiqian Kong, Hui Huang, Yang Liu, Zhenhui Kang
High conversion efficiency (14.7%) and high selectivity (86.88% for cyclohexanone) catalytic oxidation of cyclohexane under mild conditions is achieved with Au confined in carbon nanotubes.
The content of this RSS Feed (c) The Royal Society of Chemistry

New triethoxysilylated 10-vertex closo-decaborate clusters. Synthesis and controlled immobilization into mesoporous silica

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13087-13095
DOI: 10.1039/C4DT00772G, PaperFatima Abi-Ghaida, Zahra Laila, Ghassan Ibrahim, Daoud Naoufal, Ahmad Mehdi
Triethoxysilylated borate clusters comprising the closo-decaborate cage were synthesized and immobilized into the pores of SBA-15 mesoporous silica.
The content of this RSS Feed (c) The Royal Society of Chemistry

Alkaline earth metal-based metal-organic framework: hydrothermal synthesis, X-ray structure and heterogeneously catalyzed Claisen-Schmidt reaction

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13006-13017
DOI: 10.1039/C4DT00575A, PaperDebraj Saha, Tanmoy Maity, Subratanath Koner
Two alkaline earth metal based carboxylate framework systems, [Mg(HL)(H2O)2]n (1) and [Ca(H2L)2]n (2) (H3L = chelidamic acid) have been hydrothermally synthesized and characterized. Both compound 1 and its dehydrated species heterogeneously catalyze Claisen-Schmidt reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry

A series of 3D metal organic frameworks based on [24-MC-6] metallacrown clusters: structure, magnetic and luminescence properties

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,12989-12995
DOI: 10.1039/C4DT01593B, PaperKai Wang, Hua-Hong Zou, Zi-Lu Chen, Zhong Zhang, Wei-Yin Sun, Fu-Pei Liang
Four isostructural MOFs based on [24-MC-6] metallacrown cluster SUBs have been reported. They have a (4,6)-connected 3D frameworks and exhibit interesting magnetic and luminescence properties, as well as magnetocaloric effect.
The content of this RSS Feed (c) The Royal Society of Chemistry

DNA/protein interaction and cytotoxic activity of imidazole terpyridine derived Cu(II)/Zn(II) metal complexes

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13018-13031
DOI: 10.1039/C4DT01378F, PaperV. M. Manikandamathavan, T. Weyhermuller, R. P. Parameswari, M. Sathishkumar, V. Subramanian, Balachandran Unni Nair
Metal centre plays an important role in the mode of DNA binding, cleavage, protein binding and cytotoxicity.
The content of this RSS Feed (c) The Royal Society of Chemistry

Continuous-Flow Heck–Matsuda Reaction: Homogeneous versus Heterogeneous Palladium Catalysts

J. Org. Chem. - 12 August, 2014 - 20:11

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The Journal of Organic ChemistryDOI: 10.1021/jo501468z

Photoinduced Electron Transfer in Donor–Acceptor Complexes of Ethylene with Molecular and Atomic Iodine

J. Phys. Chem. A - 12 August, 2014 - 19:28

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The Journal of Physical Chemistry ADOI: 10.1021/jp412212h

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