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pH-dependent assembly of two polyoxometalate host-guest structural isomers based on Keggin polyoxoanion templates

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16328-16334
DOI: 10.1039/C4DT02050B, PaperLei Zhang, Wenbin Yang, Xiaofei Kuang, Xiaoyuan Wu, Canzhong Lu
Two polyoxometalate-templated supramolecular isomers have been obtained by hydrothermal reactions under different pH values and their photoluminescence properties have been investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, structure and catalytic activity of a gold(I) complex containing 1,2-bis(diphenylphosphino)benzene monoxide

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16300-16309
DOI: 10.1039/C4DT02116A, PaperChristine Hahn, Leticia Cruz, Amanda Villalobos, Liliana Garza, Samuel Adeosun
A bisphosphine monoxide gold(I) complex, synthesized by a new protocol, is a highly active catalyst for the hydroarylation of ethylpropiolate.
The content of this RSS Feed (c) The Royal Society of Chemistry

The coexistence of interconnected and interweaved double helices in an octamolybdate-based compound: synthesis, structure, and photocatalytic properties

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16322-16327
DOI: 10.1039/C4DT02106A, PaperWenlong Sun, Chunjing Zhang, Huiyuan Ma, Haijun Pang, Shaobin Li
Assembly and photocatalytic properties of an unprecedented helical compound based on polyoxometalates, with the coexistence of both interconnected and interweaved double helices, are reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Control of the spin state by charge and ligand substitution: two-step spin crossover behaviour in a novel neutral iron(II) complex

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16387-16394
DOI: 10.1039/C4DT01885K, PaperMaksym Seredyuk, Kateryna O. Znovjyak, Joachim Kusz, Maria Nowak, M. Carmen Munoz, Jose Antonio Real
Observation of two-step spin crossover by fine-tuning the ligand field strength with two opposed effects: steric hindrance and charge.
The content of this RSS Feed (c) The Royal Society of Chemistry

A selective fluoride sensor and a digital processor with "Write-Read-Erase-Read" behaviour

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16164-16168
DOI: 10.1039/C4DT02093F, CommunicationBasant Kumar, Masood Ayoub Kaloo, Adiki Raja Sekhar, Jeyaraman Sankar
A ferrocene-DMN Schiff base presents a novel molecular scaffold for selective fluoride sensing and digital processing with "Write-Read-Erase-Read" behaviour.
The content of this RSS Feed (c) The Royal Society of Chemistry

A Cu(II) complex of an imidazolium-based ionic liquid: synthesis, X-ray structure and application in the selective electrochemical sensing of guanine

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16283-16288
DOI: 10.1039/C4DT01759E, PaperAmanpreet Singh, Ajnesh Singh, Narinder Singh
A Cu(II) complex of the imidazolium cation was explored as an electrochemical sensor for guanine, with a high selectivity and low detection limit of 45 nM.
The content of this RSS Feed (c) The Royal Society of Chemistry

Mechanistic investigation of the cleavage of phosphodiester catalyzed by a symmetrical oxyimine-based macrocyclic dinuclear zinc complex: a DFT study

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16289-16299
DOI: 10.1039/C4DT01491J, PaperXuepeng Zhang, Xiaowei Zheng, David Lee Phillips, Cunyuan Zhao
Detailed investigation of the hydrolysis mechanism of a DNA dinucleotide analogue promoted by a dinuclear zinc-complex in nine proposed pathways.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and structures of mononuclear 3,4-bis(trifluoromethyl)pyrrolyl complexes of Rh(I) and Ni(II)

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16275-16282
DOI: 10.1039/C4DT01742K, PaperJoseph H. Rivers, Richard A. Jones
The synthesis and structures of new mononuclear complexes of the 3,4-bis(trifluoromethyl)pyrrolyl ligand (3,4-(CF3)2-Pyr-) with Rh(I) and Ni(II) are reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Structural roles of amphiphilic peptide tails on silica biomineralization

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16169-16172
DOI: 10.1039/C4DT01352B, CommunicationZhehao Huang, Haiying Jin, Shunai Che
By changing the tails of amphiphilic peptides, the nanostructures after silica biomineralization were varied due to the conformation changes.
The content of this RSS Feed (c) The Royal Society of Chemistry

F, Ca co-doped TiO2 nanocrystals with enhanced photocatalytic activity

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16160-16163
DOI: 10.1039/C4DT01908C, CommunicationWeiwei Fu, Shuang Ding, Ying Wang, Lele Wu, Daming Zhang, Zhengwei Pan, Runwei Wang, Zongtao Zhang, Shilun Qiu
F, Ca co-doped TiO2 exhibited a higher photocatalytic activity because of the smaller band gap from F doping and the effect of smaller crystal size from Ca doping.
The content of this RSS Feed (c) The Royal Society of Chemistry

Scandium carbide/cyanide alloyed cluster inside fullerene cage: synthesis and structural studies of Sc3([small mu ]3-C2)([small mu ]3-CN)@Ih-C80

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16270-16274
DOI: 10.1039/C4DT01781A, PaperTaishan Wang, Jingyi Wu, Yongqiang Feng
A new metallofullerene Sc3(C2)(CN)@Ih-C80 encaging a scandium carbide/cyanide alloyed cluster was investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry

Unusual assembly of lacunary heteropolymolybdates with cyanometalate fragment

Dalton Transactions - 18 October, 2014 - 19:17

Dalton Trans., 2014, 43,16147-16151
DOI: 10.1039/C4DT01875C, CommunicationYa Wang, Ning Jiang, Fengyan Li, Yanzhen Zheng, Lin Xu, Minghui Sun
Two new cyanide-bridged heteropolymolybdate complexes have been synthesized by a facile self-assembly process in aqueous solution, which demonstrates a successful tactic to incorporate the cyanometalate fragment into lacunary heteropolymolybdate.
The content of this RSS Feed (c) The Royal Society of Chemistry

Influence of Side-Chain Regiochemistry on the Transistor Performance of High-Mobility, All-Donor Polymers

J. Am. Chem. Soc. - 18 October, 2014 - 12:00

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Journal of the American Chemical SocietyDOI: 10.1021/ja508798s

Decarboxylative allylations of ester enolate equivalents

Org. and Biomol. Chem. - 18 October, 2014 - 07:54

Org. Biomol. Chem., 2014, 12,8386-8389
DOI: 10.1039/C4OB01752H, CommunicationYamuna Ariyarathna, Jon A. Tunge
A variety of ester enolate equivalents are generated in situ and undergo [small alpha]-allylation in high yields via palladium-catalyzed decarboxylative allylation.
The content of this RSS Feed (c) The Royal Society of Chemistry

Dissecting Reactions of Nonlinear Precursor Peptide Processing of the Class III Lanthipeptide Curvopeptin

J. Am. Chem. Soc. - 17 October, 2014 - 20:43

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Journal of the American Chemical SocietyDOI: 10.1021/ja5062054

Clickable Protein Nanocapsules for Targeted Delivery of Recombinant p53 Protein

J. Am. Chem. Soc. - 17 October, 2014 - 20:43

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Journal of the American Chemical SocietyDOI: 10.1021/ja508083g

Effects of Chemical Aging on the Ice Nucleation Activity of Soot and Polycyclic Aromatic Hydrocarbon Aerosols

J. Phys. Chem. A - 17 October, 2014 - 20:24

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The Journal of Physical Chemistry ADOI: 10.1021/jp508809y

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