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The conversion of allenes to strained three-membered heterocycles

Chem. Soc. Rev. - 3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,3136-3163
DOI: 10.1039/C3CS60416K, Review ArticleC. S. Adams, C. D. Weatherly, E. G. Burke, J. M. Schomaker
The addition of heteroatoms to an allenic double bond yields strained heterocycles that serve as scaffolds for further useful transformations.
The content of this RSS Feed (c) The Royal Society of Chemistry

Electrophilic activation of allenenes and allenynes: analogies and differences between Bronsted and Lewis acid activation

Chem. Soc. Rev. - 3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2916-2926
DOI: 10.1039/C4CS00023D, Tutorial ReviewT. Caneque, F. M. Truscott, R. Rodriguez, G. Maestri, M. Malacria
This review focuses on electrophilic activation of allenes by an acid. Key mechanistic features are presented together with recent synthetic applications.
The content of this RSS Feed (c) The Royal Society of Chemistry

[4+2] and [4+3] catalytic cycloadditions of allenes

Chem. Soc. Rev. - 3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2904-2915
DOI: 10.1039/C4CS00024B, Tutorial ReviewFernando Lopez, Jose L. Mascarenas
This review summarizes the different catalytic [4+2] and [4+3] cycloadditions that have been developed by using allenes as 2C, 3C or even 4C atom partners.
The content of this RSS Feed (c) The Royal Society of Chemistry

Cyclization reactions of bis(allenes) for the synthesis of polycarbo(hetero)cycles

Chem. Soc. Rev. - 3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,3106-3135
DOI: 10.1039/C3CS60462D, Review ArticleBenito Alcaide, Pedro Almendros, Cristina Aragoncillo
This review presents the reactivity of a variety of substituted bis(allenes) under different reaction conditions, showing the high number of complex structures that can be obtained.
The content of this RSS Feed (c) The Royal Society of Chemistry

Allenes and computational chemistry: from bonding situations to reaction mechanisms

Chem. Soc. Rev. - 3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,3041-3105
DOI: 10.1039/C3CS60457H, Review ArticleElena Soriano, Israel Fernandez
This review covers the state-of-the-art applications of computational chemistry to understand and rationalize the bonding situation and vast reactivity of allenes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Alkoxyallenes as building blocks for organic synthesis

Chem. Soc. Rev. - 3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2888-2903
DOI: 10.1039/C3CS60429B, Tutorial ReviewReinhold Zimmer, Hans-Ulrich Reissig
This Tutorial Review demonstrates the synthetic versatility of alkoxyallenes and the use of synthons derived from these C3 building blocks.
The content of this RSS Feed (c) The Royal Society of Chemistry

[2+2+1] Cyclization of allenes

Chem. Soc. Rev. - 3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2956-2978
DOI: 10.1039/C3CS60382B, Review ArticleS. Kitagaki, F. Inagaki, C. Mukai
This review focuses on the origin and progress of the allenic (or heterocumulenic) [2+2+1] cyclocarbonylation, including the chirality transfer of the allene and its synthetic applications.
The content of this RSS Feed (c) The Royal Society of Chemistry

Palladium-catalysed inter- and intramolecular formation of C-O bonds from allenes

Chem. Soc. Rev. - 3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,3003-3040
DOI: 10.1039/C3CS60379B, Review ArticleJean Le Bras, Jacques Muzart
This review highlights the Pd-catalysed formation of a C-O bond from allenes via the inter- or intramolecular reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry

Amino Acid Networks in a (β/α)8 Barrel Enzyme Change during Catalytic Turnover

J. Am. Chem. Soc. - 2 May, 2014 - 21:48

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Journal of the American Chemical SocietyDOI: 10.1021/ja501602t

Oxygen Vacancies Confined in Ultrathin Indium Oxide Porous Sheets for Promoted Visible-Light Water Splitting

J. Am. Chem. Soc. - 2 May, 2014 - 21:48

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Journal of the American Chemical SocietyDOI: 10.1021/ja501866r

Stimuli Responsive Systems Constructed Using Cucurbit[n]uril-Type Molecular Containers

Acc. Chem. Res. - 2 May, 2014 - 20:50

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Accounts of Chemical ResearchDOI: 10.1021/ar500075g

Dynamically Analyte-Responsive Macrocyclic Host–Fluorophore Systems

Acc. Chem. Res. - 2 May, 2014 - 18:45

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Accounts of Chemical ResearchDOI: 10.1021/ar500116d

Stereochemistry in Subcomponent Self-Assembly

Acc. Chem. Res. - 2 May, 2014 - 18:29

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Accounts of Chemical ResearchDOI: 10.1021/ar5000924

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