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A novel polynorbornene-based chemosensor for the fluorescence sensing of Zn2+ and Cd2+ and subsequent detection of pyrophosphate in aqueous solutions

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00542F, PaperPei-Shui Yao, Zhanghua Liu, Jin-Zhu Ge, Yong Chen, Qian-Yong Cao
A novel 8-hydroxyquinoline anchored polynorbornene for the fluorescence sensing of Zn2+/Cd2+ and subsequent detection of pyrophosphate in aqueous solutions and its biological application is introduced.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Imidazol-2-ylidene-N[prime or minute]-phenylureate ligands in alkali and alkaline earth metal coordination spheres - heterocubane core to polymeric structural motif formation

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00490J, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kishor Naktode, Jayeeta Bhattacharjee, Hari Pada Nayek, Tarun K. Panda
Synthetic and structural details of imidazol-2-ylidene-N[prime or minute]-phenylureate ligand supported two potassium complexes with a hetero-cubane K4O4 core and a polymeric structure, along with a mixed metal Ca-K complex are presented.
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The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and characterization of a trinuclear iridium(III) based catalyst for the photocatalytic reduction of CO2

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6466-6472
DOI: 10.1039/C5DT00370A, PaperR. O. Reithmeier, S. Meister, A. Siebel, B. Rieger
A trimetallic Ir(III) based photocatalyst for the reduction of CO2 was developed and investigated, regarding the influence of spatial proximity between the catalyst centers towards the catalytic performance.
The content of this RSS Feed (c) The Royal Society of Chemistry

Terbium doped SnO2 nanoparticles as white emitters and SnO2:5Tb/Fe3O4 magnetic luminescent nanohybrids for hyperthermia application and biocompatibility with HeLa cancer cells

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6457-6465
DOI: 10.1039/C4DT03000A, PaperLaishram Priyobarta Singh, Ningthoujam Premananda Singh, Sri Krishna Srivastava
SnO2:5Tb (SnO2 doped with 5 at% Tb3+) nanoparticles were synthesised by a polyol method and their luminescence properties at different annealing temperatures were studied.
The content of this RSS Feed (c) The Royal Society of Chemistry

A dual-responsive "turn-on" bifunctional receptor: a chemosensor for Fe3+ and chemodosimeter for Hg2+

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03778B, CommunicationSujay Mukhopadhyay, Rakesh Kumar Gupta, Arnab Biswas, Amit Kumar, Mrigendra Dubey, Maninder Singh Hundal, Daya Shankar Pandey
Synthesis and characterization of L1-L3 along with their selective detection toward Fe3+ and Hg2+ at ppb level, exhibiting bifunctional behaviour have been presented.
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Morphology control of the perovskite films for efficient solar cells

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03869J, PerspectiveLingling Zheng, Danfei Zhang, Yingzhuang Ma, Zelin Lu, Zhijian Chen, Shufeng Wang, Lixin Xiao, Qihuang Gong
In the past two years, the power conversion efficiency (PCE) of organic-inorganic hybrid perovskite solar cells has significantly increased up to 20.1%.
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A CH2Cl2 complex of a [Rh(pincer)]+ cation

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6340-6342
DOI: 10.1039/C5DT00481K, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gemma M. Adams, F. Mark Chadwick, Sebastian D. Pike, Andrew S. Weller
The CH2Cl2 adduct of a Rh-PONOP-pincer complex is reported, that is also a latent low coordinate synthon for the synthesis of other species.
The content of this RSS Feed (c) The Royal Society of Chemistry

A lanthanide salen "square prism" and a wrapped exo-lanthanide salen "double decker"

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6353-6357
DOI: 10.1039/C4DT03959A, CommunicationYu-Bo Shu, Wei-Sheng Liu
We succeeded in building a lanthanide salen "square prism" and in wrapping a labile exo-lanthanide salen "double decker" by cuprous cyanide netting. Both lanthanide edifices show near-infrared (NIR) luminescence.
The content of this RSS Feed (c) The Royal Society of Chemistry

Highly bright multicolour emission through energy migration in core/shell nanotubes

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6645-6654
DOI: 10.1039/C5DT00581G, PaperLu Liu, Nannan Zhang, Zhihua Leng, Yimai Liang, Ruiqing Li, Lianchun Zou, Shucai Gan
Multicolour photoluminescence was achieved in gadolinium-based core/shell nanotube structures via energy migration of Ce3+[rightward arrow]Gd3+[rightward arrow]Ln3+ and Ce3+[rightward arrow]Ln3+ (Ln = Eu, Tb, Dy and Sm) in separated layers.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ligand field variations: tuning the toroidal moment of Dy6 rings

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6343-6347
DOI: 10.1039/C5DT00237K, CommunicationAmer Baniodeh, Nicola Magnani, Stefan Brase, Christopher E. Anson, Annie K. Powell
We show how the toroidal moment in Dy6 cyclic coordination clusters can be tuned and optimised.
The content of this RSS Feed (c) The Royal Society of Chemistry

Reduction of hydroxy-functionalised carbaboranyl carboxylic acids and ketones by organolithium reagents

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6638-6644
DOI: 10.1039/C5DT00761E, PaperW. Neumann, M. Hiller, M. B. Sarosi, P. Lonnecke, E. Hey-Hawkins
A hydroxyl group at the carbaborane cluster reduces exo-polyhedral C-C cleavage and enables reduction of carbaboranyl carboxylic acids and ketones to tertiary alcohols by organolithium reagents.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ligand assisted carbon dioxide activation and hydrogenation using molybdenum and tungsten amides

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6560-6570
DOI: 10.1039/C5DT00278H, PaperSubrata Chakraborty, Olivier Blacque, Heinz Berke
Molybdenum and tungsten amides M(NO)(CO)(PNP) {M = Mo, 3a; W, 3b; PNP = (iPr2PCH2CH2)2N} can activate CO2 at room temperature forming carbamate species M(NO)(CO)(PNP)(OCO) (M = Mo, 4a(trans); W = 4b(trans). Employing 3a,b stoichiometric hydrogenation of carbon dioxide could be demonstrated.
The content of this RSS Feed (c) The Royal Society of Chemistry

A two-photon fluorescent probe for detecting endogenous hypochlorite in living cells

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6613-6619
DOI: 10.1039/C5DT00012B, PaperXunming Wang, Xiaohui Wang, Yan Feng, Manzhou Zhu, Hang Yin, QingXiang Guo, Xiangming Meng
A highly selective two-photon fluorescent probe (HQ) for endogenous hypochlorite (ClO-) was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Exposing the intermolecular nature of the second relaxation pathway in a mononuclear cobalt(II) single-molecule magnet with positive anisotropy

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6368-6373
DOI: 10.1039/C5DT00258C, PaperFatemah Habib, Ilia Korobkov, Muralee Murugesu
The investigation of a pentagonal bipyramidal Co(II) complex with large positive anisotropy (D [approximate] +30 cm-1) revealed field induced Single-Molecule Magnet behaviour with Ueff [approximate] 50 K at 1.0 kOe.
The content of this RSS Feed (c) The Royal Society of Chemistry

Palladium(II)-1-phenylthio-2-arylchalcogenoethane complexes: palladium phosphide nano-peanut and ribbon formation controlled by chalcogen and Suzuki coupling activation

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6600-6612
DOI: 10.1039/C4DT03471F, PaperGyandshwar Kumar Rao, Arun Kumar, Fariha Saleem, Mahabir P. Singh, Satyendra Kumar, Bharat Kumar, Goutam Mukherjee, Ajai K. Singh
Suzuki coupling (cocktail pathway) by complexes of S/Se-ligand/PdP2 NPs prepared from Pd-complexes in TOP (temperature [greater-than-or-equal] 280 [degree]C) is efficient.
The content of this RSS Feed (c) The Royal Society of Chemistry

Nitrogen enriched mesoporous organic polymer anchored copper(II) material: an efficient and reusable catalyst for the synthesis of esters and amides from aromatic systems

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6546-6559
DOI: 10.1039/C4DT03838J, PaperRostam Ali Molla, Md. Asif Iqubal, Kajari Ghosh, Kamaluddin, Sk. Manirul Islam
New mesoporous polymer anchored copper acetate (Cu-mPMF) has been synthesized and well characterized. The catalytic performance of this complex has been tested for the synthesis of esters and amides.
The content of this RSS Feed (c) The Royal Society of Chemistry

Cyclic tetramers of a five-membered palladacycle based on a head-to-tail-linked isocyanate dimer and their reactivity in cyclotrimerization of isocyanates

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6537-6545
DOI: 10.1039/C5DT00534E, PaperSeon Gye Lee, Keun-Young Choi, Yong-Joo Kim, SuJin Park, Soon W. Lee
Cyclic tetramers of a five-membered palladacycle involving an isocyanate dimer were prepared, and catalytic cyclotrimerization from a palladium zero-compound or a single palladacycle with organic isocyanates was performed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Copper-incorporated mono- and di-TeRu5 metal carbonyl complexes: syntheses, structures, and an unusual skeletal arrangement

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6526-6536
DOI: 10.1039/C5DT00546A, PaperMinghuey Shieh, Chia-Yeh Miu, Kai-Jieah Hsing, Li-Fing Jang, Chien-Nan Lin
A series of semiconducting Cux-incorporated TeRu5-based clusters with differing structural features, facile skeletal arrangements, and effective electronic communication is described.
The content of this RSS Feed (c) The Royal Society of Chemistry

Solvent effects on the structures and magnetic properties of two doubly interpenetrated metal-organic frameworks

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6593-6599
DOI: 10.1039/C4DT04006F, PaperFu-Ping Huang, Cheng Yang, Hai-Ye Li, Peng-Fei Yao, Xiao-Huan Qin, Shi-Ping Yan, Mohamedally Kurmoo
Two doubly interpenetrated Co(II) coordination polymers were obtained, and the solvent effects on the structures and magnetic properties were investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry

In situ characterization of uranium and americium oxide solid solution formation for CRMP process: first combination of in situ XRD and XANES measurements

Dalton Transactions - 7 hours 57 min ago

Dalton Trans., 2015, 44,6391-6399
DOI: 10.1039/C4DT03515A, PaperMarie Caisso, Sebastien Picart, Renaud C. Belin, Florent Lebreton, Philippe M. Martin, Kathy Dardenne, Jorg Rothe, Daniel R. Neuville, Thibaud Delahaye, Andre Ayral
First results on mineralization of (U,Am) loaded resin microspheres are presented in this paper.
The content of this RSS Feed (c) The Royal Society of Chemistry

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