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General synthesis of carbon-coated nanostructure Li4Ti5O12 as a high rate electrode material for Li-ion intercalation

J. Material Chem. - 20 November 2009 - 12:00am

Liang Cheng, Jing Yan, Guan-Nan Zhu, Jia-Yan Luo, Cong-Xiao Wang, Yong-Yao Xia
(Paper from J. Mater. Chem.)
Liang Cheng, J. Mater. Chem., 2010, DOI: 10.1039/b914604k
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Facile and controllable electrochemical reduction of graphene oxide and its applications

J. Material Chem. - 20 November 2009 - 12:00am

Yuyan Shao, Jun Wang, Mark Engelhard, Chongmin Wang, Yuehe Lin
(Paper from J. Mater. Chem.)
Yuyan Shao, J. Mater. Chem., 2010, DOI: 10.1039/b917975e
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Stepwise and hysteretic sorption of N2, O2, CO2, and H2 gases in a porous metal-organic framework [Zn2(BPnDC)2(bpy)]

Chem. Commun. - 20 November 2009 - 12:00am

Hye Jeong Park, Myunghyun Paik Suh
(Communication from Chem. Commun.)
Hye Jeong Park, Chem. Commun., 2010, DOI: 10.1039/b913067e
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One-pot tandem 1,4-1,2-addition of phosphites to quinolines

Chem. Commun. - 20 November 2009 - 12:00am

Ann De Blieck, Kurt G. R. Masschelein, Frederic Dhaene, Ewa Rozycka-Sokolowska, Bernard Marciniak, Jozef Drabowicz, Christian V. Stevens
(Communication from Chem. Commun.)
Ann De Blieck, Chem. Commun., 2010, DOI: 10.1039/b906808b
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Aminoclay: a permselective matrix to stabilize copper nanoparticles

Chem. Commun. - 20 November 2009 - 12:00am

K. K. R. Datta, C. Kulkarni, M. Eswaramoorthy
(Communication from Chem. Commun.)
K. K. R. Datta, Chem. Commun., 2010, DOI: 10.1039/b919421e
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Degradable hollow spheres based on self-assembly inclusion

Chem. Commun. - 20 November 2009 - 12:00am

Xian-Wei Meng, Jie Qin, Yan Liu, Min-Min Fan, Bang-Jing Li, Sheng Zhang, Xiao-Qi Yu
(Communication from Chem. Commun.)
Xian-Wei Meng, Chem. Commun., 2010, DOI: 10.1039/b916224k
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Sensitization of the NIR emission of Nd(iii) by the [small alpha]4 atropoisomer of a meso-tetraphenyl porphyrin bearing four 8-hydroxyquinolinylamide chelates

Chem. Commun. - 20 November 2009 - 12:00am

Fabrice Eckes, Veronique Bulach, Aurelie Guenet, Cristian A. Strassert, Luisa De Cola, Mir Wais Hosseini
(Communication from Chem. Commun.)
Fabrice Eckes, Chem. Commun., 2010, DOI: 10.1039/b920676k
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Nanoscale Si coating on the pore walls of SnO2 nanotube anode for Li rechargeable batteries

Chem. Commun. - 20 November 2009 - 12:00am

Woo Jin Lee, Mi-Hee Park, Yong Wang, Jim Yang Lee, Jaephil Cho
(Communication from Chem. Commun.)
Woo Jin Lee, Chem. Commun., 2010, DOI: 10.1039/b916483a
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Cellular uptake and binding of guanidine-modified phthalocyanines to KRAS/HRAS G-quadruplexes

Chem. Commun. - 20 November 2009 - 12:00am

Alexandro Membrino, Manikandan Paramasivam, Susanna Cogoi, Jawad Alzeer, Nathan W. Luedtke, Luigi E. Xodo
(Communication from Chem. Commun.)
Alexandro Membrino, Chem. Commun., 2010, DOI: 10.1039/b918964e
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Hydrophobic chromophore cargo in micellar structures: a different strategy to sensitize lanthanide cations

Chem. Commun. - 20 November 2009 - 12:00am

Celia S. Bonnet, Laurent Pellegatti, Frederic Buron, Chad M. Shade, Sandrine Villette, Vojtech Kubicek, Gerald Guillaumet, Franck Suzenet, Stephane Petoud, Eva Toth
(Communication from Chem. Commun.)
Celia S. Bonnet, Chem. Commun., 2010, DOI: 10.1039/b918881a
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A TRLFS study on the complexation of Cm(iii) and Eu(iii) with 4-t-butyl-6,6[prime or minute]-bis-(5,6-diethyl-1,2,4-triazin-3-yl)-2,2[prime or minute]-bipyridine in a water/2-propanol mixture

Dalton Transactions - 20 November 2009 - 12:00am

Sascha Trumm, Georg Lieser, Mark R. S. J. Foreman, Petra J. Panak, Andreas Geist, Thomas Fanghanel
(Paper from Dalton Trans.)
Sascha Trumm, Dalton Trans., 2010, DOI: 10.1039/b919247f
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Synthesis and structural and magnetic characterisation of copper(ii) complexes of mixed phosphonate-antimonate ligands

Dalton Transactions - 20 November 2009 - 12:00am

Shoaib Ali, Christopher A. Muryn, Floriana Tuna, Richard E. P. Winpenny
(Paper from Dalton Trans.)
Shoaib Ali, Dalton Trans., 2010, DOI: 10.1039/b913467k
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Crystallization of synthetic haemozoin ([small beta]-haematin) nucleated at the surface of lipid particles

Dalton Transactions - 20 November 2009 - 12:00am

Anh N. Hoang, Kanyile K. Ncokazi, Katherine A. de Villiers, David W. Wright, Timothy J. Egan
(Paper from Dalton Trans.)
Anh N. Hoang, Dalton Trans., 2010, DOI: 10.1039/b914359a
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Trinuclear ruthenium dioxolene complexes based on the bridging ligand hexahydroxytriphenylene: electrochemistry, spectroscopy, and near-infrared electrochromic behaviour associated with a reversible seven-membered redox chain

Dalton Transactions - 20 November 2009 - 12:00am

Christopher S. Grange, Anthony J. H. M. Meijer, Michael D. Ward
(Paper from Dalton Trans.)
Christopher S. Grange, Dalton Trans., 2010, DOI: 10.1039/b918086a
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Reactivity of a rhenium hydroxo-carbonyl complex toward carbon disulfide: insights from theory

Dalton Transactions - 20 November 2009 - 12:00am

Violeta Yeguas, Pablo Campomanes, Ramon Lopez
(Paper from Dalton Trans.)
Violeta Yeguas, Dalton Trans., 2010, DOI: 10.1039/b915766b
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Seeing Laser Beams [Built on Facts]

Science Blogs Physcial Sciences - 19 November 2009 - 9:15pm

Ok, see counselor Troi firing her phaser?

troi.png

You see this kind of thing all the time on film in scifi. Whether it's Star Trek, Star Wars, or pretty much anything else, energy beams fired from future weapons are visible. Usually someone will point out that in fact laser beams are not visible in this manner. To see light, it has to reach your eyes. This is clearly not possible when all the light is actually traveling down the beam path. You can see this in action with laser pointers - only the spot where the light hits and diffusely reflects is visible. The path is not.

Writers of TV shows usually explain this by saying that the beam is not strictly light, but some stream of particles that slightly emits to the sides along its main path. While this has its own problems, at least it acknowledges the issue.

But what's even more interesting is that in fact there are already automatically particles present along the beam path in the atmosphere. Some of them are sizable particles like dust, others are individual atoms and molecules. Generally they don't scatter much light, but if the light is intense enough then the small amount they do scatter is enough to see. And so you have a visible laser beam. Here's one in my lab:

laserbeam.png

The beam scatters off the air and you can actually see it as a straight line. Apologies for the terrible camera phone picture, I really need to get a classy camera that can take nice pictures. This is not actually a laser I'm working on, so honestly I'm not sure which variant of frequency-doubled Nd:something laser this is. Probably Nd:YLF.

This is used to pump an infrared ultrashort-pulse laser with a repetition rate of 1 kHz. This can itself be focused to a point in the air, which becomes visible as a little stationary spark as the intense beam ionizes the air. This produces a 1 kHz buzz which can easily be heard by the unassisted ear.

I have to say it's a nice job perk that I can see old science fiction tropes come to life pretty much every day. :)

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Categories: Education

I Can Haz Books! [Uncertain Principles]

Science Blogs Physcial Sciences - 19 November 2009 - 8:52pm

It's not often that I regret having a cell phone that is just a phone, but this is one of those occasions-- I stopped by my publisher today to talk about marketing and publicity, and record a video for the web, and got a stack of finished copies of the book, hot off the presses. If I had a cell phone camera, I'd post a picture, but I don't, so you'll have to settle for a plain-text "Woo-hoo!"

On an only vaguely related note, our cultural activities in NYC will include some college hoops, as there's a preseason "tournament" taking place at Madison Square garden tonight. Syracuse vs. Cal, and UNC vs. Ohio State. Not a bad double bill for November basketball.

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Categories: Education

A Selective Redox and Chromogenic Probe for Hg(II) in Aqueous Environment Based on a Ferrocene−Azaquinoxaline Dyad

Inorganic Chemistry - 19 November 2009 - 8:43pm
Inorganic Chemistry, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable).
Categories: ACS journal feeds

Novel Method and Parameters for Testing and Characterization of Foam Stability

Langmuir - 19 November 2009 - 8:22pm
Langmuir, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable).
Categories: ACS journal feeds

Enantioselective Intramolecular Oxidative Aminocarbonylation of Alkenylureas Catalyzed by Palladium−Spiro Bis(isoxazoline) Complexes

J. Org. Chem. - 19 November 2009 - 8:06pm
The Journal of Organic Chemistry, Volume 0, Issue 0, Articles ASAP (As Soon As Publishable).
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