J. Material Chem.
Enhanced activity of Pt nano-crystals supported on a novel TiO2@N-doped C nano-composite for methanol oxidation reaction
DOI: 10.1039/C2JM33926A, PaperXiao Zhao, Jianbing Zhu, Liang Liang, Jianhui Liao, Changpeng Liu, Wei Xing
A novel N-doped carbon coated hydrophilic TiO2 nanocomposite was constructed to enhance the electro-catalytic performance of Pt nanocrystals for MOR.
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Biopolymer-directed synthesis of high-surface-area magnetite colloidal nanocrystal clusters for dual drug delivery in prostate cancer
DOI: 10.1039/C2JM34877B, PaperShuai Xu, Chuanyu Sun, Jia Guo, Ke Xu, Changchun Wang
Diverse biopolymers were applied to controllably synthesized high-surface-area magnetite colloidal nanocrystal clusters (MCNCs) for dual drug delivery in prostate cancer.
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Novel porous carbon materials with ultrahigh nitrogen contents for selective CO2 capture
DOI: 10.1039/C2JM33091A, PaperYunfeng Zhao, Lan Zhao, Ke Xin Yao, Yang Yang, Qiang Zhang, Yu Han
A highly adsorptive and selective sorbent was prepared for CO2 capture by increasing the N-doping concentration in activated carbon.
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Novel highly conjugated push-pull 4,5-diazafluoren-9-ylidene based efficient NLO chromophores as a springboard for coordination complexes with large second-order NLO properties
DOI: 10.1039/C2JM33509C, PaperAlessia Colombo, Claudia Dragonetti, Stefania Righetto, Dominique Roberto, Adriana Valore, Tiziana Benincori, Francesca Colombo, Francesco Sannicolo
The [small mu ][small beta]1.91 EFISH value of [Zn(CF3SO3)2L2] (L2 = (1E,3E)-N,N-dibutyl-5-(4,5-diazafluoren-5-ylidene)penta-1,3-dienamine) is strongly dependent on concentration reaching a really huge value.
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Induction of the surface plasmon resonance from C-incorporated Au catalyst in Si1-xCx nanowires
DOI: 10.1039/C2JM33527A, PaperWoo-Jung Lee, Jin Won Ma, Jung Min Bae, Sang Han Park, Kwang-Sik Jeong, Mann-Ho Cho, Chul Lee, Kyong-Joo Han, Kwun-Bum Jeong
Si1-xCx nanowires (NWs) were synthesized by varying the ratio of SiH4 and CH3SiH3 gases using a vapor-liquid-solid (VLS) procedure using Au as a catalyst.
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Synthesis and properties of charge-transfer solids with cluster units [Mo6X14]2- (X = Br, I)
DOI: 10.1039/C2JM33086E, PaperGunzi Saito, Hidemasa Hosoda, Yukihiro Yoshida, Jun Hagiwara, Kazukuni Nishimura, Hideki Yamochi, Akihiro Otsuka, Takaaki Hiramatsu, Yuichi Shimazaki, Kaplan Kirakci, Stephane Cordier, Christiane Perrin
Structural, optical, and physical properties of charge-transfer solids of [Mo6X14]2- (X = Br, I) clusters with various electron donors were studied.
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MOF derived porous carbon-Fe3O4 nanocomposite as a high performance, recyclable environmental superadsorbent
DOI: 10.1039/C2JM33798C, PaperAbhik Banerjee, Rohan Gokhale, Sumit Bhatnagar, Jyoti Jog, Monika Bhardwaj, Benoit Lefez, Beatrice Hannoyer, Satishchandra Ogale
A high surface area, magnetic Fe3O4-carbon composite is obtained by the pyrolysis of an Fe containing MOF. We demonstrate the remarkable characteristics of this environmental superadsorbent in terms of its oil and organic pollutant removal characteristics, magnetic recoverability and high recyclability.
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Calcium-based functionalization of carbon nanostructures for peptide immobilization in aqueous media
DOI: 10.1039/C2JM33811D, PaperC. Cazorla, V. Rojas-Cervellera, C. Rovira
Calcium doping is predicted as a promising route for precise immobilization of peptides on carbon nanostructures immersed in water.
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Synthesis and characterization of a Li-rich layered cathode material Li1.15[(Mn1/3Ni1/3Co1/3)0.5(Ni1/4Mn3/4)0.5]0.85O2 with spherical core-shell structure
DOI: 10.1039/C2JM34259F, PaperXiukang Yang, Xianyou Wang, Qiliang Wei, Hongbo Shu, Li Liu, Shunyi Yang, Benan Hu, Yunfeng Song, Guishan Zou, Liang Hu, Lanhua Yi
A novel Li-rich layered cathode material with a spherical core-shell structure was synthesized for high-performance lithium ion batteries.
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A highly sensitive, single selective, real-time and "turn-on" fluorescent sensor for Al3+ detection in aqueous media
DOI: 10.1039/C2JM33393G, PaperXiaoyan Shi, Huan Wang, Tianyu Han, Xiao Feng, Bin Tong, Jianbing Shi, Junge Zhi, Yuping Dong
Turn-on detection for Al3+: a turn-on fluorescence sensor has been developed for the detection of Al3+ in aqueous solution. Based on aggregation-induced emission (AIE) mechanism, the sensor can be applied to detect Al3+ with a quick fluorescent response, a high selectivity over other metal ions and a wide quantitative detection range.
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In situ generation of Li2FeSiO4 coating on MWNT as a high rate cathode material for lithium ion batteries
DOI: 10.1039/C2JM33855F, CommunicationYi Zhao, Jiaxin Li, Ning Wang, Chuxin Wu, Yunhai Ding, Lunhui Guan
We reported more than one lithium extraction from a MWNT@Li2FeSiO4 coaxial nanocable as a cathode material for lithium ion batteries.
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Quiescent water-in-oil Pickering emulsions as a route toward healthier fruit juice infused chocolate confectionary
DOI: 10.1039/C2JM34233B, PaperThomas S. Skelhon, Nadia Grossiord, Adam R. Morgan, Stefan A. F. Bon
Using a quiescent Pickering emulsion as a tool we show the fabrication of chocolate confectionary in which 50 wt% of fats are replaced with micron-sized droplets of fruit juice or soda drink.
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Uniform PtIr catalysts supported on carbon nanotubes prepared with assistance from phosphomolybdic acid, and their enhanced performance in the oxidation of methanol
DOI: 10.1039/C2JM33808D, PaperJunhua Yuan, Bo He, Liji Hong, Juan Lu, Jigen Miao, Li Niu
Polyoxometalate assists uniform deposition of PtIr nanoparticles on carbon nanotubes, which show high performance in methanol-oxidation and CO-tolerance.
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Microphase separation-promoted crystallization in all-conjugated poly(3-alkylthiophene) diblock copolymers with high crystallinity and carrier mobility
DOI: 10.1039/C2JM33204C, PaperJing Ge, Ming He, Xiubao Yang, Zhi Ye, Xiaofeng Liu, Feng Qiu
The crystallinity of all-conjugated diblock copolymer, poly(3-butylthiophene)-b-poly(3-dodecylthiophene) (P3BDDT), with varied block ratios was significantly enhanced by a "two-step" thermal annealing treatment.
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Incorporating a stable fluorenone unit into D-A-[small pi]-A organic dyes for dye-sensitized solar cells
DOI: 10.1039/C2JM33105E, PaperChuanjiang Qin, Ashraful Islam, Liyuan Han
Two novel fluorenone-based organic dyes were synthesized, characterized, and successfully employed in dye-sensitized solar cells.
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Synthesis of zeolitic imidazolate framework-78 molecular-sieve membrane: defect formation and elimination
DOI: 10.1039/C2JM34102F, PaperXueliang Dong, Kang Huang, Sainan Liu, Rufei Ren, Wanqin Jin, Y. S. Lin
A reactive seeding route combined with a novel activating strategy was proposed for the preparation of a high-quality ZIF-78 molecular sieving membrane.
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Controlled synthesis of CdTe nanocrystals for high performanced Schottky thin film solar cells
DOI: 10.1039/C2JM34280D, PaperShi Sun, Hongmei Liu, Yuping Gao, Donghuan Qin, Junwu Chen
CdTe NCs solar cells devices were prepared by a layer by layer sintering process using a relatively low concentration of CdTe NCs with a thickness of about 500 nm. These optimal conditions can give rise to increased ITO/CdTe/Al solar cell performance.
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Facile preparation of three-dimensionally ordered macroporous Bi2WO6 with high photocatalytic activity
DOI: 10.1039/C2JM34211A, PaperSongmei Sun, Wenzhong Wang, Ling Zhang
Three-dimensionally ordered macroporous Bi2WO6 (3DOM Bi2WO6) with mesoporous walls is prepared successfully and functions as a highly efficient photocatalyst.
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Oxygen diffusion mechanism in the mixed ion-electron conductor NdBaCo2O5+x
DOI: 10.1039/C2JM34396G, CommunicationY. Hu, O. Hernandez, T. Broux, M. Bahout, J. Hermet, A. Ottochian, C. Ritter, G. Geneste, G. Dezanneau
3D oxide ion diffusion maps in NdBaCo2O5+x as obtained from neutron diffraction and molecular dynamics simulations.
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Can morphology tailoring based on functionalized fullerene nanostructures improve the performance of organic solar cells?
DOI: 10.1039/C2JM33380E, CommunicationLie Chen, Kai Yao, Yiwang Chen
The crystallinity of P3HT and phase segregation can be controlled by adding various supramolecular assemblies of fullerenes.
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