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In situ TEM study of the Li-Au reaction in an electrochemical liquid cell

16 February, 2015 - 10:54
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00145A, PaperZhiyuan Zeng, Wen-I. Liang, Ying-Hao Chu, Haimei Zheng
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FD Corrosion Chemistry Structure-charge relationship - the case of hematite (001)

12 February, 2015 - 09:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00260A, PaperJohannes Lutzenkirchen, Frank Heberling, Filip Supljika, Tajana Preocanin, Nikola Kallay, Florian Johann, Ludger Weisser, Peter Eng
We present a multidisciplinary study on the hematite (001) - aqueous solution interface, in particular the relationship between surface structure (studied via surface diffraction in the presence of a water...
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FD Corrosion Chemistry - Atmospheric pitting corrosion of 304L stainless steel: the role of highly concentrated chloride solutions

12 February, 2015 - 09:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00246F, PaperTrevor Rayment, Steven Richard Street, Na Mi, Angus J M C Cook, Haval B Mohammed-Ali, Liya Guo, Alison Davenport
The morphology of atmospheric pitting corrosion in 304L stainless steel plate was analysed using MgCl2 droplets in relation to changes in relative humidity (RH) and chloride deposition density (CDD). It...
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FD Corrosion: Determination of Mg alloys local corrosion rate using shear force mounted scanning microcapillary method

12 February, 2015 - 09:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00276H, PaperPhilippe Dauphin-Ducharme, W. Jeffrey Binns, Michael E Snowden, D W Shoesmith, Janine Mauzeroll
The successful development of scanning probe techniques to characterize corrosion in situ using multifunctional probes is intrinsically tied to surface topography signal decoupling from that of the measured electrochemical fluxes....
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Data-driven discovery of energy materials: efficient BaM2Si3O10 : Eu2+ (M = Sc, Lu) phosphors for application in solid state white lighting

12 February, 2015 - 09:54
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00125G, PaperJakoah Brgoch, Kathryn Hasz, Kristin A. Denault, Christopher K. H. Borg, Alexander A. Mikhailovsky, Ram Seshadri
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Aqueous Solution/Metal Interfaces Investigated in operando by Photoelectron Spectroscopy

12 February, 2015 - 09:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00003C, PaperOsman Karslioglu, Slavo Nemsak, Ioannis Zegkinoglou, Andrey Shavorskiy, Matthias Hartl, Farhad Salmassi, Eric Gullikson, May-Ling Ng, Chrisptoph Rameshan, Bruce Rude, Davide Bianculli, Amy Cordones-Hahn, Stephanus Axnanda, Ethan Crumlin, P N Ross, Claus M. Schneider, Zahid Hussain, Zhi Liu, Charles S Fadley, Hendrik Bluhm
We describe a new in operando approach for the investigation of heterogeneous processes at solid/liquid interfaces with elemental and chemical specificity which combines the preparation of thin liquid films using...
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Soft-patchy nanoparticles: modeling and self-organization

12 February, 2015 - 09:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00271G, PaperEmanuela Bianchi, Barbara Capone, Gerhard Kahl, Christos N Likos
We consider a novel class of patchy particles inspired by polymer-based complex units where the limited valence in bonding is accompanied by soft interactions and incessant fluctuations of the patch...
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Ion counting in supercapacitor electrodes using NMR spectroscopy

12 February, 2015 - 09:54
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00138A, PaperJohn M. Griffin, Alexander C. Forse, Hao Wang, Nicole M. Trease, Pierre-Louis Taberna, Patrice Simon, Clare P. Grey
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Synthesis of multivalent silica nanoparticles combining both enthalpic and entropic patchiness

10 February, 2015 - 09:17
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00241E, PaperCeline Hubert, Cyril Chomette, Anthony Desert, ming SUN, Mona Treguer, Stephane Mornet, Adeline Perro, Etienne Duguet, Serge Ravaine
Silica particles with a controlled number of entropic patches, i.e. dimples, are synthesized through the growth of the silica core of binary multipods that have been produced by a seeded-growth...
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FD Nucleation: Chiral habit selection on nanostructured epitaxial quartz films

10 February, 2015 - 09:17
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00266K, PaperAdrian Carretero-Genevrier, Marti Gich, Laura Picas, Clement Sanchez, Juan Rodriguez-Carvajal
Understanding the crystallization of enantiomorphically pure systems can be relevant to diverse fields such as the study of the origins of life or the purification of racemates. Here we report...
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The corrosion protection of AA 2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatings

8 February, 2015 - 08:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00237G, PaperPeter Visser, Yanwen Lui, Xiaorong Zhou, Teruo Hashimoto, George Thompson, Stuart Lyon, Leendert G.J. van der Ven, Arjan J.M.C. Mol, Herman Terryn
Lithium carbonate and lithium oxalate were incorporated as leachable corrosion inhibitors in model organic coatings for the protection of AA2024-T3. The coated samples were artificially damaged with a scribe. It...
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FD Nucleation: High-resolution insights into the early stages of silver nucleation and growth

8 February, 2015 - 08:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00269E, PaperCornelia Voelkle, Denis Gebauer, Helmut Coelfen
Nucleation and growth of silver nanoparticles has already been investigated with various experimental and computational tools, however, owing to inherent problems associated with the analytical characterization of nucleation processes, there...
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FD Nucleation: On the question of two-step nucleation in protein crystallization

8 February, 2015 - 08:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00225C, PaperAndrea Sauter, Felix Roosen-Runge, Fajun Zhang, Gudrun Lotze, Artem Feoktystov, Robert Jacobs, Frank Schreiber
We report a real-time study on protein crystallization in the presence of multivalent salts using small angle X-ray scattering (SAXS) and optical microscopy, particularly focusing on the nucleation mechanism as...
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FD Corrosion Chemistry

8 February, 2015 - 08:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00238E, PaperMira Todorova , Jorg Neugebauer
We discuss how electronic-structure calculations can be used to identify the dominant point defects that control the growth and dissolution of the oxide barrier layer formed if a metal gets...
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Effects of molybdenum on the composition and nanoscale morphology of passivated austenitic stainless steel surfaces

8 February, 2015 - 08:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00231H, PaperVincent Maurice, Hao Peng, Lorena H. Klein, Antoine Seyeux, Sandrine Zanna, Philippe Marcus
Surface analysis by time-of-flight secondary ion mass spectrometry, X-Ray photoelectron spectroscopy and scanning tunnelling microscopy has been applied to bring new insight on Mo effects on the composition and nanostructure...
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Urea homogeneous nucleation mechanism is solvent dependent

6 February, 2015 - 08:17
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00235K, PaperMatteo Salvalaglio, Marco Mazzotti, Michele Parrinello
The composition of the mother phase plays a primary role in crystallization processes, affecting both crystal nucleation and growth. In this work the influence of solvents on urea nucleation has...
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Directing the orientational alignment of anisotropic magnetic nanoparticles using dynamic magnetic fields

4 February, 2015 - 07:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00242C, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Daniel Hoffelner, Matthias Kundt, Annette Monika Schmidt, Emmanuel Kentzinger, Philipp Bender, Sabrina Disch
The structure-directing influence of static and dynamic, i. e. rotating, magnetic fields on the orientational alignment of spindle-type hematite particles with a high aspect ratio is investigated. Structural characterization using...
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FD Nucleation:Formation of New Polymorphs Without any Nucleation Step Desolvation of the Rimonabant Monohydrate: Directional Crystallisation Concomitant to Smooth Dehydration

4 February, 2015 - 07:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00222A, PaperBaptiste FOURS, Yohann CARTIGNY, Samuel PETIT, Gerard Coquerel
Rimonabant monohydrate can be dehydrated at 100[degree]C or above with complete loss of structural information; in this case the amorphous material can lead to nucleation and crystal growth. The water...
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FD Nucleation: A design equation for low dosage additives that accelerate nucleation

4 February, 2015 - 07:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00226A, PaperGeoffrey G. Poon, Stefan Seritan, Baron Peters
Additives are used to control nucleation in many natural and industrial environments. However, the mechanisms by which additives inhibit or accelerate solute precipitate nucleation are not well understood. We propose...
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Multiphysics modelling, quantum chemistry and risk analysis for corrosion inhibitor design and lifetime prediction

4 February, 2015 - 07:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00220B, PaperChristopher Taylor, Ashwini Chandra, Jose Vera, Narasi Sridhar
Organic corrosion inhibitors can provide an effective means to extend the life of equipment in aggressive environments, decrease the environmental, economic, health and safety risks associated with corrosion failures and...
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