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In-situ monitoring of corrosion mechanisms and phosphate inhibitor surface deposition during corrosion of Zinc Magnesium Aluminium (ZMA) alloys using novel time-lapse microscopy.

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00251B, PaperJames Sullivan, Nathan Cooze, Callum Gallagher, Thomas Lewis, Tomas Prosek, Dominique Thierry
In-situ time-lapse optical microscopy was used to examine the microstructural corrosion mechanisms in three zinc-magnesium-aluminium (ZMA) alloy coated steels immersed in 1% NaCl pH 7. Preferential corrosion of MgZn2 lamellae...
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Probing deactivation pathways of DNA nucleobases by two-dimensional electronic spectroscopy: first principles simulations

31 January, 2015 - 06:54
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C4FD00175C, PaperArtur Nenov, Javier Segarra-Marti, Angelo Giussani, Irene Conti, Ivan Rivalta, Elise Dumont, Vishal K. Jaiswal, Salvatore Flavio Altavilla, Shaul Mukamel, Marco Garavelli
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Vibronic structure in the far-UV electronic circular dichroism spectra of proteins

31 January, 2015 - 06:54
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C4FD00163J, PaperZhuo Li, David Robinson, Jonathan D. Hirst
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Excited state dynamics of organic semi-conducting materials

31 January, 2015 - 06:54
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C4FD00171K, PaperKenneth P. Ghiggino, Andrew J. Tilley, Benjamin Robotham, Jonathan M. White
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On the photophysics of butadiyne bridged pyrene-phenyl molecular conjugates: multiple emissive pathways through locally excited, intramolecular charge transfer and excimer states

31 January, 2015 - 06:54
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C4FD00170B, PaperAvik Kumar Pati, Santosh J. Gharpure, Ashok K. Mishra
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The effect on structural and solvent water molecules of substrate binding to ferric horseradish peroxidase

31 January, 2015 - 06:54
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C4FD00161C, PaperNiall Simpson, Katrin Adamczyk, Gordon Hithell, Daniel J. Shaw, Gregory M. Greetham, Michael Towrie, Anthony W. Parker, Neil T. Hunt
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X-ray diffraction in temporally and spatially resolved biomolecular science

31 January, 2015 - 06:54
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C4FD00166D, PaperJohn R. Helliwell, Alice Brink, Surasak Kaenket, Victoria Laurina Starkey, Simon W. M. Tanley
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Nanocrystal Superlattices that Exhibit Improved Order On Heating: An Example of Inverse Melting?

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00006H, PaperYixuan Yu, Avni Jain, Adrien Guillaussier, Vikas Reddy, Thomas M Truskett, Detlef Smilgies, Brian A Korgel
Grazing incidence small angle X-ray scattering (GISAXS) measurements reveal that superlattices of 1.7 nm diameter, gold (Au) nanocrystals capped with octadecanethiol become significantly more ordered when heated to modest temperatures...
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FD Nucleation:On a role of liquid intermediates in nucleation of gold sulfide nanoparticles in aqueous media

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00258J, PaperMaxim N. Likhatski, Anton A. Karacharov, Alexander A Kondrasenko, Yuri Mikhlin
Previously, we found a series of fluid nanoscale intermediates preceding nucleation of gold sulfide in the reaction between aqueous HAuCl4 and sodium sulfide. Here, the effect of temperature, addition of...
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The Influence of Hydrogen Peroxide and Hydrogen on the Corrosion of Simulated Spent Nuclear Fuel

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00221K, PaperMayuri Razdan, D W Shoesmith
The synergistic influence between H2O2 and H2 on the corrosion of SIMFUEL (simulated spent nuclear fuel) has been studied in solutions with and without added HCO3-/CO32-. The response of the...
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In situ TEM study of the Li-Au reaction in an electrochemical liquid cell

31 January, 2015 - 06:54
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00145A, PaperZhiyuan Zeng, Wen-I. Liang, Ying-Hao Chu, Haimei Zheng
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FD Corrosion Chemistry Structure-charge relationship - the case of hematite (001)

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00260A, PaperJohannes Lutzenkirchen, Frank Heberling, Filip Supljika, Tajana Preocanin, Nikola Kallay, Florian Johann, Ludger Weisser, Peter Eng
We present a multidisciplinary study on the hematite (001) - aqueous solution interface, in particular the relationship between surface structure (studied via surface diffraction in the presence of a water...
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FD Corrosion Chemistry - Atmospheric pitting corrosion of 304L stainless steel: the role of highly concentrated chloride solutions

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00246F, PaperTrevor Rayment, Steven Richard Street, Na Mi, Angus J M C Cook, Haval B Mohammed-Ali, Liya Guo, Alison Davenport
The morphology of atmospheric pitting corrosion in 304L stainless steel plate was analysed using MgCl2 droplets in relation to changes in relative humidity (RH) and chloride deposition density (CDD). It...
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FD Corrosion: Determination of Mg alloys local corrosion rate using shear force mounted scanning microcapillary method

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00276H, PaperPhilippe Dauphin-Ducharme, W. Jeffrey Binns, Michael E Snowden, D W Shoesmith, Janine Mauzeroll
The successful development of scanning probe techniques to characterize corrosion in situ using multifunctional probes is intrinsically tied to surface topography signal decoupling from that of the measured electrochemical fluxes....
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Data-driven discovery of energy materials: efficient BaM2Si3O10 : Eu2+ (M = Sc, Lu) phosphors for application in solid state white lighting

31 January, 2015 - 06:54
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00125G, PaperJakoah Brgoch, Kathryn Hasz, Kristin A. Denault, Christopher K. H. Borg, Alexander A. Mikhailovsky, Ram Seshadri
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Aqueous Solution/Metal Interfaces Investigated in operando by Photoelectron Spectroscopy

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00003C, PaperOsman Karslioglu, Slavo Nemsak, Ioannis Zegkinoglou, Andrey Shavorskiy, Matthias Hartl, Farhad Salmassi, Eric Gullikson, May-Ling Ng, Chrisptoph Rameshan, Bruce Rude, Davide Bianculli, Amy Cordones-Hahn, Stephanus Axnanda, Ethan Crumlin, P N Ross, Claus M. Schneider, Zahid Hussain, Zhi Liu, Charles S Fadley, Hendrik Bluhm
We describe a new in operando approach for the investigation of heterogeneous processes at solid/liquid interfaces with elemental and chemical specificity which combines the preparation of thin liquid films using...
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Soft-patchy nanoparticles: modeling and self-organization

31 January, 2015 - 06:54
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C4FD00271G, PaperEmanuela Bianchi, Barbara Capone, Gerhard Kahl, Christos N Likos
We consider a novel class of patchy particles inspired by polymer-based complex units where the limited valence in bonding is accompanied by soft interactions and incessant fluctuations of the patch...
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Ion counting in supercapacitor electrodes using NMR spectroscopy

31 January, 2015 - 06:54
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00138A, PaperJohn M. Griffin, Alexander C. Forse, Hao Wang, Nicole M. Trease, Pierre-Louis Taberna, Patrice Simon, Clare P. Grey
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Optical nanoparticles: general discussion

31 January, 2015 - 06:54
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD90079K, DiscussionPeter Dobson, Lanry L. Yung, Liane Rossi, Zoe Pikramenou, Sara Carreira, Paresh Ray, Catherine Amiens, Katherine Brown, Maha Abdollah, Dejian Zhou, Mauro Prato, Sandhya Moise, Lucio Litti, Matthew Todd, Kristian Goeken, Stefan Borsley, Amelie Heuer-Jungemann, Oliver Reiser, Peter Harvey, Thomas Carter, Maya Thanou, Dalibor Soukup, Anna Lesniak, Hedi Mattoussi, Siti Fatimah Abdul Ghani
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Magnetic Nanoparticles: general discussion

31 January, 2015 - 06:54
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD90078B, DiscussionPeter Dobson, Lanry L. Yung, Liane Rossi, Sara Carreira, Paresh Ray, Catherine Amiens, Katherine Brown, Dejian Zhou, Asterios Gavriilidis, Nguyen T. K. Thanh, Sandhya Moise, Lucio Litti, Hedi Mattoussi, Matthew Todd, Scott Mitchell, Stefan Borsley, Amelie Heuer-Jungemann, Oliver Reiser, Edman Tsang, Maya Thanou, Tom Berkleman, Dalibor Soukup, Kerry Chester, Ivan Parkin, Yuri Antonio Diaz Fernandez, Benjamin P. Burke
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