Chem. Soc. Rev.

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Design, synthesis and photophysical studies of dipyrromethene-based materials: insights into their applications in organic photovoltaic devices

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3342-3405
DOI: 10.1039/C3CS60411J, Review ArticleAndre Bessette, Garry S. Hanan
This review article presents the most recent developments in the use of materials based on dipyrromethene and some structurally related azadipyrromethenes for OPV applications.
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Functional group directed C-H borylation

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3229-3243
DOI: 10.1039/C3CS60418G, Tutorial ReviewA. Ros, R. Fernandez, J. M. Lassaletta
Different strategies designed to enable directing group effects have been applied to achieve regioselective borylation of C(sp2)-H and C(sp3)-H bonds.
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Recent advances in heterogeneous selective oxidation catalysis for sustainable chemistry

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3480-3524
DOI: 10.1039/C3CS60282F, Review ArticleZhen Guo, Bin Liu, Qinghong Zhang, Weiping Deng, Ye Wang, Yanhui Yang
Selective oxidations of CH4, alcohols and CO over heterogeneous catalysts are reviewed from the viewpoint of green and sustainable chemistry.
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Polyelectrolyte multilayered assemblies in biomedical technologies

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3453-3479
DOI: 10.1039/C3CS60393H, Review ArticleRui R. Costa, Joao F. Mano
This review highlights the current role and broad potential of layer-by-layer (LbL) based strategies in the development of biomedical devices.
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Nanomaterials enhanced surface plasmon resonance for biological and chemical sensing applications

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3426-3452
DOI: 10.1039/C3CS60479A, Review ArticleShuwen Zeng, Dominique Baillargeat, Ho-Pui Ho, Ken-Tye Yong
A comprehensive review of nanomaterials-based enhanced surface plasmon resonance sensing of chemical and biological analytes is presented.
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The electrochemical reduction processes of solid compounds in high temperature molten salts

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3215-3228
DOI: 10.1039/C3CS60327J, Tutorial ReviewWei Xiao, Dihua Wang
The electrochemical reduction mechanisms of solid compounds in molten salts influence the chemical composition, the microstructure of the electrolytic products and the energy efficiency of the electrolysis.
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Recent progress in metal-organic complexes for optoelectronic applications

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3259-3302
DOI: 10.1039/C3CS60449G, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hui Xu, Runfeng Chen, Qiang Sun, Wenyong Lai, Qianqian Su, Wei Huang, Xiaogang Liu
This critical review reports recent advances in the development of metal-organic complexes for optoelectronic applications.
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Engineering nanointerfaces for nanocatalysis

15 May, 2014 - 18:17

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C3CS60389J, Review ArticleZhi-cheng Zhang, Biao Xu, Xun Wang
We focus on recent advances in the delicate design of well-defined nanointerfaces to promote nanocatalysis towards renewable energy.
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The chemistry of cationic polyphosphorus cages - syntheses, structure and reactivity

15 May, 2014 - 18:17

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00019F, Review ArticleMichael H. Holthausen, Jan J. Weigand
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.
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Cholesterol and metal ions in Alzheimer's disease

5 May, 2014 - 15:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00005F, Tutorial ReviewHyuck Jin Lee, Kyle J. Korshavn, Akiko Kochi, Jeffrey S. Derrick, Mi Hee Lim
This review describes the possible involvement of cholesterol and metal ions in AD neuropathogenesis in both individual and interconnected manners.
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Soft templates in encapsulation complexes

5 May, 2014 - 15:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00065J, Review ArticleDariush Ajami, Lijuan Liu, Julius Rebek Jr.
The ethanolamide of arachidonic acid (anandamide) nucleates the assembly of a capsule incorporating 8 spacer units.
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Allene ether Nazarov cyclization

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2979-3002
DOI: 10.1039/C3CS60333D, Review ArticleMarcus A. Tius
The ease of synthesis and the exceptional reactivity of alkoxyallenes has led to their use in a large number of highly diverse applications.
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Progress in allene chemistry

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2886-2887
DOI: 10.1039/C4CS90020K, EditorialBenito Alcaide, Pedro Almendros
Guest editors Benito Alcaide and Pedro Almendros introduce the Progress in allene chemistry themed issue of Chemical Society Reviews.
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Mechanistic insights into the gold chemistry of allenes

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2941-2955
DOI: 10.1039/C3CS60441A, Tutorial ReviewWeibo Yang, A. Stephen K. Hashmi
In the last few years numerous new gold-catalysed reactions of allenes have been developed. The current mechanistic knowledge about different versatile reaction types like cycloadditions, hydroarylations, hydroalkoxylations and additions of carbonyl derivatives is based on experimental evidence and computational studies.
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Synthesis and properties of long [n]cumulenes (n [greater-than-or-equal] 5)

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,3184-3203
DOI: 10.1039/C4CS00022F, Review ArticleJohanna A. Januszewski, Rik R. Tykwinski
This review highlights the synthesis and reactivity of longer [n]cumulenes (n [greater-than-or-equal] 5) and summarizes their electronic and structural properties.
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Silver and platinum-catalysed addition of O-H and N-H bonds to allenes

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,3164-3183
DOI: 10.1039/C3CS60408J, Review ArticleMaria Paz Munoz
Silver and platinum-catalysed reactions of allenes with oxygen and nitrogen nucleophiles are presented in this review as powerful tools for the synthesis of functionalized molecules containing heteroatoms.
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Phosphine catalysis of allenes with electrophiles

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2927-2940
DOI: 10.1039/C4CS00054D, Tutorial ReviewZhiming Wang, Xingzhu Xu, Ohyun Kwon
This article compiles the most representative examples of phosphine-catalyzed annulations between allenes and electrophiles to form various carbo- and heterocycles.
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The conversion of allenes to strained three-membered heterocycles

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,3136-3163
DOI: 10.1039/C3CS60416K, Review ArticleC. S. Adams, C. D. Weatherly, E. G. Burke, J. M. Schomaker
The addition of heteroatoms to an allenic double bond yields strained heterocycles that serve as scaffolds for further useful transformations.
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Electrophilic activation of allenenes and allenynes: analogies and differences between Bronsted and Lewis acid activation

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2916-2926
DOI: 10.1039/C4CS00023D, Tutorial ReviewT. Caneque, F. M. Truscott, R. Rodriguez, G. Maestri, M. Malacria
This review focuses on electrophilic activation of allenes by an acid. Key mechanistic features are presented together with recent synthetic applications.
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[4+2] and [4+3] catalytic cycloadditions of allenes

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2904-2915
DOI: 10.1039/C4CS00024B, Tutorial ReviewFernando Lopez, Jose L. Mascarenas
This review summarizes the different catalytic [4+2] and [4+3] cycloadditions that have been developed by using allenes as 2C, 3C or even 4C atom partners.
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