Chem. Soc. Rev.

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Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3525-3550
DOI: 10.1039/C3CS60289C, Review ArticleCarlo Sambiagio, Stephen P. Marsden, A. John Blacker, Patrick C. McGowan
Copper-catalysed arylations represent valid and complementary alternatives to Pd catalysis. This review discusses the different mechanisms suggested for these reactions, and summarises some of their latest applications in synthesis.
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Design, synthesis and photophysical studies of dipyrromethene-based materials: insights into their applications in organic photovoltaic devices

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3342-3405
DOI: 10.1039/C3CS60411J, Review ArticleAndre Bessette, Garry S. Hanan
This review article presents the most recent developments in the use of materials based on dipyrromethene and some structurally related azadipyrromethenes for OPV applications.
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Functional group directed C-H borylation

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3229-3243
DOI: 10.1039/C3CS60418G, Tutorial ReviewA. Ros, R. Fernandez, J. M. Lassaletta
Different strategies designed to enable directing group effects have been applied to achieve regioselective borylation of C(sp2)-H and C(sp3)-H bonds.
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Recent advances in heterogeneous selective oxidation catalysis for sustainable chemistry

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3480-3524
DOI: 10.1039/C3CS60282F, Review ArticleZhen Guo, Bin Liu, Qinghong Zhang, Weiping Deng, Ye Wang, Yanhui Yang
Selective oxidations of CH4, alcohols and CO over heterogeneous catalysts are reviewed from the viewpoint of green and sustainable chemistry.
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Polyelectrolyte multilayered assemblies in biomedical technologies

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3453-3479
DOI: 10.1039/C3CS60393H, Review ArticleRui R. Costa, Joao F. Mano
This review highlights the current role and broad potential of layer-by-layer (LbL) based strategies in the development of biomedical devices.
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Nanomaterials enhanced surface plasmon resonance for biological and chemical sensing applications

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3426-3452
DOI: 10.1039/C3CS60479A, Review ArticleShuwen Zeng, Dominique Baillargeat, Ho-Pui Ho, Ken-Tye Yong
A comprehensive review of nanomaterials-based enhanced surface plasmon resonance sensing of chemical and biological analytes is presented.
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The electrochemical reduction processes of solid compounds in high temperature molten salts

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3215-3228
DOI: 10.1039/C3CS60327J, Tutorial ReviewWei Xiao, Dihua Wang
The electrochemical reduction mechanisms of solid compounds in molten salts influence the chemical composition, the microstructure of the electrolytic products and the energy efficiency of the electrolysis.
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Recent progress in metal-organic complexes for optoelectronic applications

19 May, 2014 - 19:17

Chem. Soc. Rev., 2014, 43,3259-3302
DOI: 10.1039/C3CS60449G, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hui Xu, Runfeng Chen, Qiang Sun, Wenyong Lai, Qianqian Su, Wei Huang, Xiaogang Liu
This critical review reports recent advances in the development of metal-organic complexes for optoelectronic applications.
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Engineering nanointerfaces for nanocatalysis

15 May, 2014 - 18:17

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C3CS60389J, Review ArticleZhi-cheng Zhang, Biao Xu, Xun Wang
We focus on recent advances in the delicate design of well-defined nanointerfaces to promote nanocatalysis towards renewable energy.
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The chemistry of cationic polyphosphorus cages - syntheses, structure and reactivity

15 May, 2014 - 18:17

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00019F, Review ArticleMichael H. Holthausen, Jan J. Weigand
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.
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Post-synthetic metalation of metal-organic frameworks

13 May, 2014 - 17:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00076E, Review ArticleJack D. Evans, Christopher J. Sumby, Christian J. Doonan
Post-synthetic metalation (PSMet) offers expansive scope for a targeted approach to tailoring the properties of MOFs.
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MOFs as proton conductors - challenges and opportunities

13 May, 2014 - 17:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00093E, Review ArticlePadmini Ramaswamy, Norman E. Wong, George K. H. Shimizu
Recent developments in the field of proton-conducting MOFs are reviewed, with a special focus on the design strategies and structural characteristics of the best performers in the low temperature (<100 [degree]C) and the high-temperature (>100 [degree]C) regimes.
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Beyond post-synthesis modification: evolution of metal-organic frameworks via building block replacement

9 May, 2014 - 16:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00067F, Review ArticlePravas Deria, Joseph E. Mondloch, Olga Karagiaridi, Wojciech Bury, Joseph T. Hupp, Omar K. Farha
Metal-organic frameworks (MOFs) are hybrid porous materials with many potential applications, which intimately depend on the presence of chemical functionality either at the organic linkers and/or at the metal nodes.
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Cholesterol and metal ions in Alzheimer's disease

5 May, 2014 - 15:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00005F, Tutorial ReviewHyuck Jin Lee, Kyle J. Korshavn, Akiko Kochi, Jeffrey S. Derrick, Mi Hee Lim
This review describes the possible involvement of cholesterol and metal ions in AD neuropathogenesis in both individual and interconnected manners.
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Soft templates in encapsulation complexes

5 May, 2014 - 15:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00065J, Review ArticleDariush Ajami, Lijuan Liu, Julius Rebek Jr.
The ethanolamide of arachidonic acid (anandamide) nucleates the assembly of a capsule incorporating 8 spacer units.
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Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours

5 May, 2014 - 15:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C3CS60475F, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Elisa Barea, Carmen Montoro, Jorge A. R. Navarro
The adsorptive and catalytic properties of metal-organic frameworks are advantageous for the capture, sensing and degradation of harmful gases and vapors.
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Allene ether Nazarov cyclization

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2979-3002
DOI: 10.1039/C3CS60333D, Review ArticleMarcus A. Tius
The ease of synthesis and the exceptional reactivity of alkoxyallenes has led to their use in a large number of highly diverse applications.
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Progress in allene chemistry

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2886-2887
DOI: 10.1039/C4CS90020K, EditorialBenito Alcaide, Pedro Almendros
Guest editors Benito Alcaide and Pedro Almendros introduce the Progress in allene chemistry themed issue of Chemical Society Reviews.
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Mechanistic insights into the gold chemistry of allenes

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,2941-2955
DOI: 10.1039/C3CS60441A, Tutorial ReviewWeibo Yang, A. Stephen K. Hashmi
In the last few years numerous new gold-catalysed reactions of allenes have been developed. The current mechanistic knowledge about different versatile reaction types like cycloadditions, hydroarylations, hydroalkoxylations and additions of carbonyl derivatives is based on experimental evidence and computational studies.
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Synthesis and properties of long [n]cumulenes (n [greater-than-or-equal] 5)

3 May, 2014 - 15:17

Chem. Soc. Rev., 2014, 43,3184-3203
DOI: 10.1039/C4CS00022F, Review ArticleJohanna A. Januszewski, Rik R. Tykwinski
This review highlights the synthesis and reactivity of longer [n]cumulenes (n [greater-than-or-equal] 5) and summarizes their electronic and structural properties.
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