Chem. Soc. Rev.

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Functional hyperbranched polymers with advanced optical, electrical and magnetic properties

26 September, 2014 - 00:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00224E, Review ArticleWenbo Wu, Runli Tang, Qianqian Li, Zhen Li
This review summarizes the recent progress in functional HBPs and their application in optics, electronics and magnetics, including light-emitting devices, aggregation-induced emission materials, nonlinear optical materials, chemosensors, solar cells, magnetic materials, etc., and provides outlooks for further exploration in the field.
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Protein film photoelectrochemistry of the water oxidation enzyme photosystem II

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6485-6497
DOI: 10.1039/C4CS00031E, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Masaru Kato, Jenny Z. Zhang, Nicholas Paul, Erwin Reisner
This review describes key functions of the water oxidation enzyme photosystem II, protein film photoelectrochemistry of photosystem II and bio-inspired photoelectrochemical water oxidation systems.
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Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6555-6569
DOI: 10.1039/C3CS60468C, Review ArticleCarlos G. Morales-Guio, Lucas-Alexandre Stern, Xile Hu
Nanostructuring is a useful strategy to improve the activity of some known hydrotreating catalysts for electrochemical hydrogen evolution.
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Contributors to the emerging investigators issue 2014

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6482-6484
DOI: 10.1039/C4CS90064B, Profile
Chemical Society Reviews profiles the Emerging Investigators featuring work in this issue.
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Transition metal-mediated bioorthogonal protein chemistry in living cells

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6511-6526
DOI: 10.1039/C4CS00117F, Review ArticleMaiyun Yang, Jie Li, Peng R. Chen
Transition metal-mediated chemical conversions have rapidly expanded our intracellular protein chemistry toolbox, which would broaden our view on bioorthogonal chemistry.
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An atlas of two-dimensional materials

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6537-6554
DOI: 10.1039/C4CS00102H, Review ArticlePere Miro, Martha Audiffred, Thomas Heine
The discovery of graphene and other two-dimensional (2D) materials together with recent advances in exfoliation techniques have set the foundations for the manufacturing of single layered sheets from any layered 3D material.
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Polymer-encapsulated organic nanoparticles for fluorescence and photoacoustic imaging

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6570-6597
DOI: 10.1039/C4CS00014E, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kai Li, Bin Liu
In this Critical Review, we summarize the latest advances in the development of polymer encapsulated nanoparticles based on conjugated polymers and fluorogens with aggregation induced emission (AIE) characteristics, elucidate the importance of matrix selection and structure-property relationship of these nanoparticles and discuss their applications in fluorescence and photoacoustic imaging.
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Addition of CF3 across unsaturated moieties: a powerful functionalization tool

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6598-6608
DOI: 10.1039/C4CS00025K, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Estibaliz Merino, Cristina Nevado
This review summarizes recent methodologies for the simultaneous formation of C-CF3 and C-C or C-heteroatom bonds by formal addition reactions to alkenes.
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Natural and engineered biosynthesis of fluorinated natural products

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6527-6536
DOI: 10.1039/C4CS00027G, Review ArticleMark C. Walker, Michelle C. Y. Chang
Studying the biosynthesis of naturally-occurring and engineered organofluorine natural products may enable the development of new bioactive small molecules.
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Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6609-6638
DOI: 10.1039/C4CS00061G, Review ArticleKarl J. Bonney, Franziska Schoenebeck
This review emphasises the power of combining computation and experiment in the mechanistic study and reactivity design of palladium-mediated chemistry.
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The chemistry of cationic polyphosphorus cages - syntheses, structure and reactivity

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6639-6657
DOI: 10.1039/C4CS00019F, Review ArticleMichael H. Holthausen, Jan J. Weigand
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.
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Metalloprotein design using genetic code expansion

13 September, 2014 - 22:54

Chem. Soc. Rev., 2014, 43,6498-6510
DOI: 10.1039/C4CS00018H, Tutorial ReviewCheng Hu, Sunney I. Chan, Elizabeth B. Sawyer, Yang Yu, Jiangyun Wang
Genetic code expansion has become an essential new tool for designing functional small protein models for complex metalloenzymes.
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The biosafety of lanthanide upconversion nanomaterials

9 September, 2014 - 22:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00175C, Review ArticleYun Sun, Wei Feng, Pengyuan Yang, Chunhui Huang, Fuyou Li
The association between the chemo-physical properties of UCNPs and their biodistribution, excretion, and toxic effects is presented in this review.
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Diffusion NMR of molecular cages and capsules

7 September, 2014 - 21:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00197D, Review ArticleLiat Avram, Yoram Cohen
The applications of diffusion NMR and DOSY in the field of molecular capsules and cages are reviewed focusing on the added value of using these methods when studying such systems in solution.
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Lanthanide-doped upconversion nano-bioprobes: electronic structures, optical properties, and biodetection

1 September, 2014 - 20:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00178H, Review ArticleWei Zheng, Ping Huang, Datao Tu, En Ma, Haomiao Zhu, Xueyuan Chen
The latest advances in lanthanide-doped upconversion nanoparticles were comprehensively reviewed, which covers from their fundamental photophysics to biodetection.
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Molecular containers assembled through the hydrophobic effect

1 September, 2014 - 20:17

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00191E, Review ArticleJacobs H. Jordan, Bruce C. Gibb
This review focuses on molecular containers formed by assembly processes driven by the hydrophobic effect, and summarizes the progress made in the field over the last ten years.
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Trianionic pincer and pincer-type metal complexes and catalysts

1 September, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6325-6369
DOI: 10.1039/C4CS00111G, Review ArticleMatthew E. O'Reilly, Adam S. Veige
This review provides a comprehensive examination of the synthesis, characterization, properties, and catalytic applications of trianionic pincer metal complexes.
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Yellow/orange emissive heavy-metal complexes as phosphors in monochromatic and white organic light-emitting devices

1 September, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6439-6469
DOI: 10.1039/C4CS00110A, Review ArticleCong Fan, Chuluo Yang
This article reviews the development of the yellow/orange emissive heavy-metal complexes used in organic light-emitting devices.
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Design, synthesis and excited-state properties of mononuclear Ru(II) complexes of tridentate heterocyclic ligands

1 September, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6184-6197
DOI: 10.1039/C4CS00123K, Tutorial ReviewAmlan K. Pal, Garry S. Hanan
Mononuclear Ru(II) complexes of tridentate ligands now exhibit long excited-state lifetimes at room temperature.
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Oxidative etching for controlled synthesis of metal nanocrystals: atomic addition and subtraction

1 September, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6288-6310
DOI: 10.1039/C4CS00136B, Review ArticleRan Long, Shan Zhou, Benjamin J. Wiley, Yujie Xiong
This review outlines recent progress in oxidative etching that has provided highly important opportunities for controlled synthesis of metal nanocrystals.
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