Chem. Soc. Rev.

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Fluorometric imaging methods for palladium and platinum and the use of palladium for imaging biomolecules

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00323C, Review ArticleMatthew P. Tracey, Dianne Pham, Kazunori Koide
Palladium and platinum metals have been used to facilitate novel bioimaging methods.
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Donor-acceptor conjugated polymers based on multifused ladder-type arenes for organic solar cells

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1113-1154
DOI: 10.1039/C4CS00250D, Review ArticleJhong-Sian Wu, Sheng-Wen Cheng, Yen-Ju Cheng, Chain-Shu Hsu
In this review, we summarize the recent development of the multifused ladder-type conjugated building blocks for making donor-acceptor conjugated copolymers.
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Fluorescent and colorimetric ion probes based on conjugated oligopyrroles

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1101-1112
DOI: 10.1039/C4CS00436A, Tutorial ReviewYubin Ding, Yunyu Tang, Weihong Zhu, Yongshu Xie
In this tutorial review, the design strategies, syntheses, and ion sensing properties of conjugated oligopyrroles are described.
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Hydrogen bonding in ionic liquids

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1257-1288
DOI: 10.1039/C4CS00278D, Review ArticlePatricia A. Hunt, Claire R. Ashworth, Richard P. Matthews
Doubly ionic H-bonds are not a rare or esoteric form of the H-bond, rather they constitute a broad class found commonly within ionic liquids, which has yet to be fully explored.
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The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1083-1100
DOI: 10.1039/C4CS00244J, Tutorial ReviewZhuqi Chen, Guochuan Yin
The relationships of active metal oxo and hydroxo moieties have been summarized with their implications for biological and chemical oxidations.
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Nucleic acid aptamers in cancer research, diagnosis and therapy

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1240-1256
DOI: 10.1039/C4CS00357H, Review ArticleHaitao Ma, Jinping Liu, M. Monsur Ali, M. Arif Iftakher Mahmood, Louai Labanieh, Mengrou Lu, Samir M. Iqbal, Qun Zhang, Weian Zhao, Yuan Wan
A comprehensive, up-to-date aptamer review with a specific focus on the cancer field.
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Olefinic C-H functionalization through radical alkenylation

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1070-1082
DOI: 10.1039/C4CS00347K, Tutorial ReviewShan Tang, Kun Liu, Chao Liu, Aiwen Lei
This tutorial review provides a comprehensive overview of olefinic C-H functionalization through radical addition and following SET oxidation/elimination.
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Molecules with a sense of logic: a progress report

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1053-1069
DOI: 10.1039/C4CS00342J, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joakim Andreasson, Uwe Pischel
Ones and zeros can be handled by molecules through the input-control of their signaling features. The progress in this exciting field during the last five years is covered in this tutorial review.
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Synthetic biology for the directed evolution of protein biocatalysts: navigating sequence space intelligently

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1172-1239
DOI: 10.1039/C4CS00351A, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrew Currin, Neil Swainston, Philip J. Day, Douglas B. Kell
Improving enzymes by directed evolution requires the navigation of very large search spaces; we survey how to do this intelligently.
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Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1155-1171
DOI: 10.1039/C4CS00288A, Review ArticleHuawen Huang, Xiaochen Ji, Wanqing Wu, Huanfeng Jiang
The N-oxyenamine internal oxidant gives more chance to investigate the C-H bond activation under mild reaction conditions.
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How valence bond theory can help you understand your (bio)chemical reaction

22 March, 2015 - 20:54

Chem. Soc. Rev., 2015, 44,1037-1052
DOI: 10.1039/C4CS00241E, Tutorial ReviewAvital Shurki, Etienne Derat, Alexandre Barrozo, Shina Caroline Lynn Kamerlin
This Tutorial Review describes modern VB theory, using a didactic example of an SN2 reaction to illustrate its immediate applications.
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Current developments in fluorescent PET (photoinduced electron transfer) sensors and switches

18 March, 2015 - 19:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00334A, HighlightBrian Daly, Jue Ling, A. Prasanna de Silva
A fluorophore can be combined with a receptor according to a molecular engineering design in order to yield fluorescent sensing and switching devices.
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Synthetic fluorescent probes for studying copper in biological systems

18 March, 2015 - 19:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00346B, Review ArticleJoseph A. Cotruvo, Jr., Allegra T. Aron, Karla M. Ramos-Torres, Christopher J. Chang
This review surveys fluorescent probes for copper, emphasizing desirable criteria for their effective use for discovery and study of new metal biology.
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Aromaticity of metallabenzenes and related compounds

18 March, 2015 - 19:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00004A, Review ArticleIsrael Fernandez, Gernot Frenking, Gabriel Merino
In this review, we focus on the aromaticity of a particular family of organometallic compounds known as metallabenzenes, which are characterized by the formal replacement of a CH group in benzene by an isolobal transition metal fragment.
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Specific light-up bioprobes based on AIEgen conjugates

16 March, 2015 - 19:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00444B, Tutorial ReviewJing Liang, Ben Zhong Tang, Bin Liu
This review summarizes the synthesis, the operation mechanism and design principles of specific AIE light-up bioprobes with applications in bio-analyte sensing, cell imaging and cancer therapy.
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Phonon and Raman scattering of two-dimensional transition metal dichalcogenides from monolayer, multilayer to bulk material

12 March, 2015 - 18:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00282B, Review ArticleXin Zhang, Xiao-Fen Qiao, Wei Shi, Jiang-Bin Wu, De-Sheng Jiang, Ping-Heng Tan
This review focuses on the basic properties and potential applications of Raman spectroscopy of two-dimensional transition metal dichalcogenides from monolayer, multilayer to bulk materials.
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Luminescent probes for the bioimaging of small anionic species in vitro and in vivo

12 March, 2015 - 18:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00372A, Review ArticleTrent D. Ashton, Katrina A. Jolliffe, Frederick M. Pfeffer
This comprehensive review examines recent developments in the use of fluorescent/luminescent probes for the bioimaging of anionic species. Images in cover art reproduced with permission from .
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Industrial applications of nanoparticles

10 March, 2015 - 18:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00362D, Tutorial ReviewW. J. Stark, P. R. Stoessel, W. Wohlleben, A. Hafner
This tutorial review analyses where nanoparticle research has left the laboratory and today contributes to valuable products.
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Molecular wires

10 March, 2015 - 18:17

Chem. Soc. Rev., 2015, 44,842-844
DOI: 10.1039/C5CS90010G, EditorialDirk M. Guldi, Hiroshi Nishihara, Latha Venkataraman
Guest editors Dirk M. Guldi, Hiroshi Nishihara and Latha Venkataraman introduce the Molecular Wires issue of Chemical Society Reviews.
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Nanoparticle characterization based on STM and STS

10 March, 2015 - 18:17

Chem. Soc. Rev., 2015, 44,970-987
DOI: 10.1039/C4CS00204K, Review ArticleShinya Kano, Tsukasa Tada, Yutaka Majima
Scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) can characterize intriguing nanoparticle properties towards solid-state nanodevices.
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