Chem. Soc. Rev.
Mechanochemistry of fullerenes and related materials
DOI: 10.1039/C3CS35494F, Review ArticleSan-E Zhu, Fei Li, Guan-Wu Wang
Functionalizations of fullerenes and related materials have been achieved by ball milling and hand grinding.
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Categories: Royal Society of Chemistry
Responsive hydrogels - structurally and dimensionally optimized smart frameworks for applications in catalysis, micro-system technology and material science
DOI: 10.1039/C3CS60031A, Review ArticleArtjom Doring, Wolfgang Birnbaum, Dirk Kuckling
The review covers the most recent developments in the field of responsive hydrogels focussing on catalysis, sensors and actuators.
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Categories: Royal Society of Chemistry
The modern interpretation of the Wittig reaction mechanism
DOI: 10.1039/C3CS60105F, Review ArticlePeter A. Byrne, Declan G. Gilheany
Li salt-free Wittig reactions of all ylide types occur under kinetic control, and by a common [2+2] cycloaddition mechanism in which oxaphosphetane is the first-formed and only intermediate.
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Categories: Royal Society of Chemistry
Mechanochemical organic synthesis
DOI: 10.1039/C3CS35526H, Review ArticleGuan-Wu Wang
Various solvent-free mechanochemical organic reactions can be realized by ball milling techniques.
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Categories: Royal Society of Chemistry
Application of mass spectrometric techniques to delineate the modes-of-action of anticancer metallodrugs
DOI: 10.1039/C3CS35532B, Review ArticleChristian G. Hartinger, Michael Groessl, Samuel M. Meier, Angela Casini, Paul J. Dyson
Mass spectrometric methods are increasingly being used to help elucidate the modes of action of metal-based anticancer agents. Nascent developments and recent applications are discussed in this review.
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Glycoclusters on oligonucleotide and PNA scaffolds: synthesis and applications
DOI: 10.1039/C2CS35406C, Tutorial ReviewNicolas Spinelli, Eric Defrancq, Francois Morvan
Oligonucleotide glycocluster conjugates are involved in several approaches for cellular delivery, carbohydrate microarray or supramolecular glycoclusters.
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Categories: Royal Society of Chemistry
Multivalent glycoconjugates as anti-pathogenic agents
DOI: 10.1039/C2CS35408J, Review ArticleAnna Bernardi, Jesus Jimenez-Barbero, Alessandro Casnati, Cristina De Castro, Tamis Darbre, Franck Fieschi, Jukka Finne, Horst Funken, Karl-Erich Jaeger, Martina Lahmann, Thisbe K. Lindhorst, Marco Marradi, Paul Messner, Antonio Molinaro, Paul V. Murphy, Cristina Nativi, Stefan Oscarson, Soledad Penades, Francesco Peri, Roland J. Pieters, Olivier Renaudet, Jean-Louis Reymond, Barbara Richichi, Javier Rojo, Francesco Sansone, Christina Schaffer, W. Bruce Turnbull, Trinidad Velasco-Torrijos, Sebastien Vidal, Stephane Vincent, Tom Wennekes, Han Zuilhof, Anne Imberty
Glycocompounds interfere with infection and immunity.
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Categories: Royal Society of Chemistry
Clustered carbohydrates in synthetic vaccines
DOI: 10.1039/C2CS35422E, Tutorial ReviewFrancesco Peri
Are there general rules for the design of efficient carbohydrate vaccines? Recent achievements in the field of carbohydrate immunization.
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Categories: Royal Society of Chemistry
Sweet carbon nanostructures: carbohydrate conjugates with carbon nanotubes and graphene and their applications
DOI: 10.1039/C2CS35396B, Tutorial ReviewYanan Chen, Alexander Star, Sebastien Vidal
This review highlights the strategies for the covalent and noncovalent functionalization of carbon nanostructures with carbohydrates and applications in biology.
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Categories: Royal Society of Chemistry
Multivalency in heterogeneous glycoenvironments: hetero-glycoclusters, -glycopolymers and -glycoassemblies
DOI: 10.1039/C2CS35219B, Tutorial ReviewJose L. Jimenez Blanco, Carmen Ortiz Mellet, Jose M. Garcia Fernandez
"Shuffled", multidomain and fluidic displays of different glycotopes allow assessing the effect of heterogeneity in carbohydrate-lectin or -antibody interactions.
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Categories: Royal Society of Chemistry
Chemical routes to top-down nanofabrication
DOI: 10.1039/C3CS60113G, Tutorial ReviewHai-Dong Yu, Michelle D. Regulacio, Enyi Ye, Ming-Yong Han
This tutorial review summarizes the different chemical routes to top-down nanofabrication that have enabled the construction of three-dimensional nanostructures with unique structural features and promising applications.
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Near-infrared phosphorescence: materials and applications
DOI: 10.1039/C3CS60029G, Review ArticleHaifeng Xiang, Jinghui Cheng, Xiaofeng Ma, Xiangge Zhou, Jason Joseph Chruma
An overview of the latest developments and applications in the field of room-temperature near-infrared phosphorescent transition-metal complexes is given.
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From powder to technical body: the undervalued science of catalyst scale up
DOI: 10.1039/C3CS60076A, Review ArticleSharon Mitchell, Nina-Luisa Michels, Javier Perez-Ramirez
This review examines the complexity associated with the scale up of heterogeneous catalysts, proposing directions to strengthen the fundamental understanding of this exciting, but often neglected field.
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Multivalent scaffolds in glycoscience: an overview
DOI: 10.1039/C3CS90029K, EditorialOlivier Renaudet, Rene Roy
Guest editors Olivier Renaudet and Rene Roy introduce the Multivalent scaffolds in glycosciences themed issue of Chemical Society Reviews.
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Categories: Royal Society of Chemistry
How do multivalent glycodendrimers benefit from sulfur chemistry?
DOI: 10.1039/C3CS60090D, Review ArticleMarc Gingras, Yoann M. Chabre, Myriam Roy, Rene Roy
The combination of sugar and sulfur chemistry is reported to benefit multivalent glycodendrimer chemistry. Besides the contribution of sulfur to structural linking strategies, we emphasized some novelties in the modulation of optoelectronic properties of those ligands and their uses in glycobiology, in materials science and in nanoscience.
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Categories: Royal Society of Chemistry
Multivalent glycoliposomes and micelles to study carbohydrate-protein and carbohydrate-carbohydrate interactions
DOI: 10.1039/C3CS00001J, Tutorial ReviewNarayanaswamy Jayaraman, Krishnagopal Maiti, Kottari Naresh
The synthetic design of glycolipids, and formation of glycoliposomes and micelles thereof to study multivalent carbohydrate-protein and carbohydrate-carbohydrate interactions are presented.
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Categories: Royal Society of Chemistry
Multivalent glycoconjugate syntheses and applications using aromatic scaffolds
DOI: 10.1039/C3CS35483K, Review ArticleYoann M. Chabre, Rene Roy
This review describes the chemical syntheses and biological properties of multivalent glycoarchitectures prepared around aromatic backbones.
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Categories: Royal Society of Chemistry
Glycopeptide dendrimers as Pseudomonas aeruginosa biofilm inhibitors
DOI: 10.1039/C3CS35504G, Review ArticleJean-Louis Reymond, Myriam Bergmann, Tamis Darbre
Inhibition and dispersal of Pseudomonas aeruginosa biofilms were achieved with multivalent glycopeptide dendrimer inhibitors of lectins LecA and LecB.
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Categories: Royal Society of Chemistry
Multivalent glycocalixarenes for recognition of biological macromolecules: glycocalyx mimics capable of multitasking
DOI: 10.1039/C2CS35437C, Tutorial ReviewFrancesco Sansone, Alessandro Casnati
Glycocalixarenes, like the cell-wall glycocalyx, recognise macromolecules through multivalency. Their possibility to simultaneously perform other tasks such as drug-delivery, imaging or immunostimulation suggests their potential application in bionanotechnology and nanomedicine.
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Categories: Royal Society of Chemistry
Binding sugars: from natural lectins to synthetic receptors and engineered neolectins
DOI: 10.1039/C2CS35435G, Review ArticleJulie Arnaud, Aymeric Audfray, Anne Imberty
From structural knowledge of natural lectins, artificial carbohydrate-binders are developed based either on engineered biomolecules or on biomimetics systems.
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Categories: Royal Society of Chemistry

