Chem. Soc. Rev.

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Mechanochemistry of fullerenes and related materials

12 June, 2013 - 06:17

Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS35494F, Review ArticleSan-E Zhu, Fei Li, Guan-Wu Wang
Functionalizations of fullerenes and related materials have been achieved by ball milling and hand grinding.
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Responsive hydrogels - structurally and dimensionally optimized smart frameworks for applications in catalysis, micro-system technology and material science

12 June, 2013 - 06:17

Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS60031A, Review ArticleArtjom Doring, Wolfgang Birnbaum, Dirk Kuckling
The review covers the most recent developments in the field of responsive hydrogels focussing on catalysis, sensors and actuators.
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The modern interpretation of the Wittig reaction mechanism

10 June, 2013 - 05:54

Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS60105F, Review ArticlePeter A. Byrne, Declan G. Gilheany
Li salt-free Wittig reactions of all ylide types occur under kinetic control, and by a common [2+2] cycloaddition mechanism in which oxaphosphetane is the first-formed and only intermediate.
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Mechanochemical organic synthesis

6 June, 2013 - 04:54

Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS35526H, Review ArticleGuan-Wu Wang
Various solvent-free mechanochemical organic reactions can be realized by ball milling techniques.
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Application of mass spectrometric techniques to delineate the modes-of-action of anticancer metallodrugs

6 June, 2013 - 04:54

Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS35532B, Review ArticleChristian G. Hartinger, Michael Groessl, Samuel M. Meier, Angela Casini, Paul J. Dyson
Mass spectrometric methods are increasingly being used to help elucidate the modes of action of metal-based anticancer agents. Nascent developments and recent applications are discussed in this review.
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Glycoclusters on oligonucleotide and PNA scaffolds: synthesis and applications

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4557-4573
DOI: 10.1039/C2CS35406C, Tutorial ReviewNicolas Spinelli, Eric Defrancq, Francois Morvan
Oligonucleotide glycocluster conjugates are involved in several approaches for cellular delivery, carbohydrate microarray or supramolecular glycoclusters.
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Multivalent glycoconjugates as anti-pathogenic agents

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4709-4727
DOI: 10.1039/C2CS35408J, Review ArticleAnna Bernardi, Jesus Jimenez-Barbero, Alessandro Casnati, Cristina De Castro, Tamis Darbre, Franck Fieschi, Jukka Finne, Horst Funken, Karl-Erich Jaeger, Martina Lahmann, Thisbe K. Lindhorst, Marco Marradi, Paul Messner, Antonio Molinaro, Paul V. Murphy, Cristina Nativi, Stefan Oscarson, Soledad Penades, Francesco Peri, Roland J. Pieters, Olivier Renaudet, Jean-Louis Reymond, Barbara Richichi, Javier Rojo, Francesco Sansone, Christina Schaffer, W. Bruce Turnbull, Trinidad Velasco-Torrijos, Sebastien Vidal, Stephane Vincent, Tom Wennekes, Han Zuilhof, Anne Imberty
Glycocompounds interfere with infection and immunity.
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Clustered carbohydrates in synthetic vaccines

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4543-4556
DOI: 10.1039/C2CS35422E, Tutorial ReviewFrancesco Peri
Are there general rules for the design of efficient carbohydrate vaccines? Recent achievements in the field of carbohydrate immunization.
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Sweet carbon nanostructures: carbohydrate conjugates with carbon nanotubes and graphene and their applications

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4532-4542
DOI: 10.1039/C2CS35396B, Tutorial ReviewYanan Chen, Alexander Star, Sebastien Vidal
This review highlights the strategies for the covalent and noncovalent functionalization of carbon nanostructures with carbohydrates and applications in biology.
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Multivalency in heterogeneous glycoenvironments: hetero-glycoclusters, -glycopolymers and -glycoassemblies

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4518-4531
DOI: 10.1039/C2CS35219B, Tutorial ReviewJose L. Jimenez Blanco, Carmen Ortiz Mellet, Jose M. Garcia Fernandez
"Shuffled", multidomain and fluidic displays of different glycotopes allow assessing the effect of heterogeneity in carbohydrate-lectin or -antibody interactions.
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Chemical routes to top-down nanofabrication

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS60113G, Tutorial ReviewHai-Dong Yu, Michelle D. Regulacio, Enyi Ye, Ming-Yong Han
This tutorial review summarizes the different chemical routes to top-down nanofabrication that have enabled the construction of three-dimensional nanostructures with unique structural features and promising applications.
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Near-infrared phosphorescence: materials and applications

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS60029G, Review ArticleHaifeng Xiang, Jinghui Cheng, Xiaofeng Ma, Xiangge Zhou, Jason Joseph Chruma
An overview of the latest developments and applications in the field of room-temperature near-infrared phosphorescent transition-metal complexes is given.
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From powder to technical body: the undervalued science of catalyst scale up

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, Advance Article
DOI: 10.1039/C3CS60076A, Review ArticleSharon Mitchell, Nina-Luisa Michels, Javier Perez-Ramirez
This review examines the complexity associated with the scale up of heterogeneous catalysts, proposing directions to strengthen the fundamental understanding of this exciting, but often neglected field.
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Multivalent scaffolds in glycoscience: an overview

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4515-4517
DOI: 10.1039/C3CS90029K, EditorialOlivier Renaudet, Rene Roy
Guest editors Olivier Renaudet and Rene Roy introduce the Multivalent scaffolds in glycosciences themed issue of Chemical Society Reviews.
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How do multivalent glycodendrimers benefit from sulfur chemistry?

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4823-4841
DOI: 10.1039/C3CS60090D, Review ArticleMarc Gingras, Yoann M. Chabre, Myriam Roy, Rene Roy
The combination of sugar and sulfur chemistry is reported to benefit multivalent glycodendrimer chemistry. Besides the contribution of sulfur to structural linking strategies, we emphasized some novelties in the modulation of optoelectronic properties of those ligands and their uses in glycobiology, in materials science and in nanoscience.
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Multivalent glycoliposomes and micelles to study carbohydrate-protein and carbohydrate-carbohydrate interactions

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4640-4656
DOI: 10.1039/C3CS00001J, Tutorial ReviewNarayanaswamy Jayaraman, Krishnagopal Maiti, Kottari Naresh
The synthetic design of glycolipids, and formation of glycoliposomes and micelles thereof to study multivalent carbohydrate-protein and carbohydrate-carbohydrate interactions are presented.
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Multivalent glycoconjugate syntheses and applications using aromatic scaffolds

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4657-4708
DOI: 10.1039/C3CS35483K, Review ArticleYoann M. Chabre, Rene Roy
This review describes the chemical syntheses and biological properties of multivalent glycoarchitectures prepared around aromatic backbones.
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Glycopeptide dendrimers as Pseudomonas aeruginosa biofilm inhibitors

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4814-4822
DOI: 10.1039/C3CS35504G, Review ArticleJean-Louis Reymond, Myriam Bergmann, Tamis Darbre
Inhibition and dispersal of Pseudomonas aeruginosa biofilms were achieved with multivalent glycopeptide dendrimer inhibitors of lectins LecA and LecB.
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Multivalent glycocalixarenes for recognition of biological macromolecules: glycocalyx mimics capable of multitasking

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4623-4639
DOI: 10.1039/C2CS35437C, Tutorial ReviewFrancesco Sansone, Alessandro Casnati
Glycocalixarenes, like the cell-wall glycocalyx, recognise macromolecules through multivalency. Their possibility to simultaneously perform other tasks such as drug-delivery, imaging or immunostimulation suggests their potential application in bionanotechnology and nanomedicine.
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Binding sugars: from natural lectins to synthetic receptors and engineered neolectins

4 June, 2013 - 04:17

Chem. Soc. Rev., 2013, 42,4798-4813
DOI: 10.1039/C2CS35435G, Review ArticleJulie Arnaud, Aymeric Audfray, Anne Imberty
From structural knowledge of natural lectins, artificial carbohydrate-binders are developed based either on engineered biomolecules or on biomimetics systems.
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