Chem. Soc. Rev.

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Metal-Organic Frameworks (MOFs)

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5415-5418
DOI: 10.1039/C4CS90059F, EditorialHong-Cai "Joe" Zhou, Susumu Kitagawa
Guest editors Hong-Cai "Joe" Zhou and Susumu Kitagawa introduce the Metal-Organic Frameworks (MOFs) themed issue of Chemical Society Reviews.
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A supermolecular building approach for the design and construction of metal-organic frameworks

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,6141-6172
DOI: 10.1039/C4CS00135D, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vincent Guillerm, Dongwook Kim, Jarrod F. Eubank, Ryan Luebke, Xinfang Liu, Karim Adil, Myoung Soo Lah, Mohamed Eddaoudi
A toolbox for the design of made-to-order MOFs: Pinpointing the rationale and benefits of the Supermolecular Building Block (SBB) and Supermolecular Building Layer (SBL) approaches.
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Polyoxometalate based open-frameworks (POM-OFs)

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5679-5699
DOI: 10.1039/C4CS00097H, Review ArticleHaralampos N. Miras, Laia Vila-Nadal, Leroy Cronin
Polyoxometalate-based open frameworks (POM-OFs) are extended architectures incorporating metal-oxide cluster units and comprise an emergent family of materials with a large diversity of topologies, structural flexibility and functionality at the nanoscale.
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Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5789-5814
DOI: 10.1039/C4CS00129J, Review ArticleJie-Peng Zhang, Pei-Qin Liao, Hao-Long Zhou, Rui-Biao Lin, Xiao-Ming Chen
This review gives a brief overview of single-crystal X-ray diffraction studies and single-crystal to single-crystal transformations of porous coordination polymers.
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Metal-organic framework membranes: from synthesis to separation application

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,6116-6140
DOI: 10.1039/C4CS00159A, Review ArticleShilun Qiu, Ming Xue, Guangshan Zhu
This review provides current techniques for the fabrication of MOF membranes and separation applications of diverse MOF membranes.
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High valence 3p and transition metal based MOFs

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,6097-6115
DOI: 10.1039/C4CS00081A, Review ArticleThomas Devic, Christian Serre
This article focuses on high valence 3p and transition metal based metal organic frameworks.
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Flexible metal-organic frameworks

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,6062-6096
DOI: 10.1039/C4CS00101J, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.A. Schneemann, V. Bon, I. Schwedler, I. Senkovska, S. Kaskel, R. A. Fischer
Flexible metal-organic frameworks are state-of-the-art materials and their tailor made synthesis, in situ analysis and possible applications have gained wide attention in the scientific community.
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Water adsorption in MOFs: fundamentals and applications

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5594-5617
DOI: 10.1039/C4CS00078A, Review ArticleJerome Canivet, Alexandra Fateeva, Youmin Guo, Benoit Coasne, David Farrusseng
MOF and water, friend or enemy?
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Applications of metal-organic frameworks in heterogeneous supramolecular catalysis

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,6011-6061
DOI: 10.1039/C4CS00094C, Review ArticleJiewei Liu, Lianfen Chen, Hao Cui, Jianyong Zhang, Li Zhang, Cheng-Yong Su
The contributions of MOFs to the field of heterogeneous supramolecular catalysis are comprehensively reviewed with regard to active sites, selectivity, as well as host-guest chemistry.
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Template-directed synthesis of metal-organic materials

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5444-5455
DOI: 10.1039/C4CS00075G, Tutorial ReviewZhenjie Zhang, Michael J. Zaworotko
This tutorial review details the emergence of template-directed synthesis of metal-organic materials (MOMs) with emphasis upon reports of MOMs in which the template is retained, template@MOMs, and structurally characterized.
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Cation exchange at the secondary building units of metal-organic frameworks

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5456-5467
DOI: 10.1039/C4CS00002A, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.C. K. Brozek, M. Dinca
This review examines the governing factors of cation exchange at the secondary building units of MOFs and reviews its applications.
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Supramolecular templating of hierarchically porous metal-organic frameworks

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5431-5443
DOI: 10.1039/C4CS00127C, Tutorial ReviewDarren Bradshaw, Samir El-Hankari, Lucia Lupica-Spagnolo
This tutorial review summarises recent advances in the soft templating of metal-organic frameworks with hierarchical porosity across the micro- and mesoporous regimes.
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Structuring of metal-organic frameworks at the mesoscopic/macroscopic scale

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5700-5734
DOI: 10.1039/C4CS00106K, Review ArticleShuhei Furukawa, Julien Reboul, Stephane Diring, Kenji Sumida, Susumu Kitagawa
This review conceptually categorizes the available synthetic methodologies for structuring of MOFs in the mesoscopic and macroscopic scales.
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MOF positioning technology and device fabrication

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5513-5560
DOI: 10.1039/C4CS00089G, Review ArticlePaolo Falcaro, Raffaele Ricco, Cara M. Doherty, Kang Liang, Anita J. Hill, Mark J. Styles
Methods for permanent localisation, dynamic localisation and spatial control of functional materials within MOF crystals are critical for the development of miniaturised MOF-based devices for a number of technological applications.
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MOF-based electronic and opto-electronic devices

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5994-6010
DOI: 10.1039/C4CS00096J, Review ArticleV. Stavila, A. A. Talin, M. D. Allendorf
Emergent properties resulting from the ordered structure and synthetic versatility of nanoporous metal-organic frameworks offer exciting possibilities for electronic devices.
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High-throughput computational screening of metal-organic frameworks

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5735-5749
DOI: 10.1039/C4CS00070F, Review ArticleYamil J. Colon, Randall Q. Snurr
High-throughput computational screening of MOFs allows identification of promising candidates, new structure-property relationships, and performance limits.
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Metal-organic frameworks for artificial photosynthesis and photocatalysis

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5982-5993
DOI: 10.1039/C4CS00103F, Review ArticleTeng Zhang, Wenbin Lin
This article reviews the latest progress in light-harvesting, organic photocatalysis, proton and CO2 reduction, and water oxidation using MOFs.
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Substitution reactions in metal-organic frameworks and metal-organic polyhedra

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5952-5981
DOI: 10.1039/C4CS00033A, Review ArticleYi Han, Jian-Rong Li, Yabo Xie, Guangsheng Guo
This review summarizes the advances in the study of substitution reactions in metal-organic frameworks (MOFs) and metal-organic polyhedra (MOPs).
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Post-synthetic metalation of metal-organic frameworks

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5933-5951
DOI: 10.1039/C4CS00076E, Review ArticleJack D. Evans, Christopher J. Sumby, Christian J. Doonan
Post-synthetic metalation (PSMet) offers expansive scope for a targeted approach to tailoring the properties of MOFs.
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MOFs as proton conductors - challenges and opportunities

18 August, 2014 - 17:54

Chem. Soc. Rev., 2014, 43,5913-5932
DOI: 10.1039/C4CS00093E, Review ArticlePadmini Ramaswamy, Norman E. Wong, George K. H. Shimizu
Recent developments in the field of proton-conducting MOFs are reviewed, with a special focus on the design strategies and structural characteristics of the best performers in the low temperature (<100 [degree]C) and the high-temperature (>100 [degree]C) regimes.
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