Chem. Soc. Rev.

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Recent advances in magnetic nanoparticle-based multi-modal imaging

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00345D, Tutorial ReviewTae-Hyun Shin, Youngseon Choi, Soojin Kim, Jinwoo Cheon
This tutorial review discusses the concept and up-to-date applications of magnetic nanoparticle-based multi-modal imaging.
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The chemistry and engineering of polymeric hydrogel adhesives for wound closure: a tutorial

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00332B, Tutorial ReviewC. Ghobril, M. W. Grinstaff
This tutorial review highlights the key features and design requirements for the use of polymeric hydrogel adhesives in the clinic.
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Electron transfer in peptides

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1015-1027
DOI: 10.1039/C4CS00297K, Review ArticleAfzal Shah, Bimalendu Adhikari, Sanela Martic, Azeema Munir, Suniya Shahzad, Khurshid Ahmad, Heinz-Bernhard Kraatz
In this review, we discuss the factors that influence electron transfer in peptides.
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Fluorescent and colorimetric ion probes based on conjugated oligopyrroles

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1101-1112
DOI: 10.1039/C4CS00436A, Tutorial ReviewYubin Ding, Yunyu Tang, Weihong Zhu, Yongshu Xie
In this tutorial review, the design strategies, syntheses, and ion sensing properties of conjugated oligopyrroles are described.
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Hydrogen bonding in ionic liquids

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1257-1288
DOI: 10.1039/C4CS00278D, Review ArticlePatricia A. Hunt, Claire R. Ashworth, Richard P. Matthews
Doubly ionic H-bonds are not a rare or esoteric form of the H-bond, rather they constitute a broad class found commonly within ionic liquids, which has yet to be fully explored.
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The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1083-1100
DOI: 10.1039/C4CS00244J, Tutorial ReviewZhuqi Chen, Guochuan Yin
The relationships of active metal oxo and hydroxo moieties have been summarized with their implications for biological and chemical oxidations.
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Nucleic acid aptamers in cancer research, diagnosis and therapy

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1240-1256
DOI: 10.1039/C4CS00357H, Review ArticleHaitao Ma, Jinping Liu, M. Monsur Ali, M. Arif Iftakher Mahmood, Louai Labanieh, Mengrou Lu, Samir M. Iqbal, Qun Zhang, Weian Zhao, Yuan Wan
A comprehensive, up-to-date aptamer review with a specific focus on the cancer field.
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Break junction under electrochemical gating: testbed for single-molecule electronics

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,889-901
DOI: 10.1039/C4CS00242C, Tutorial ReviewCancan Huang, Alexander V. Rudnev, Wenjing Hong, Thomas Wandlowski
This tutorial review highlights recent developments using break junction techniques, and emphasizes the concept of "electrochemical gating" on single-molecule junctions.
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Olefinic C-H functionalization through radical alkenylation

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1070-1082
DOI: 10.1039/C4CS00347K, Tutorial ReviewShan Tang, Kun Liu, Chao Liu, Aiwen Lei
This tutorial review provides a comprehensive overview of olefinic C-H functionalization through radical addition and following SET oxidation/elimination.
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Incorporating single molecules into electrical circuits. The role of the chemical anchoring group

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,920-942
DOI: 10.1039/C4CS00264D, Review ArticleEdmund Leary, Andrea La Rosa, M. Teresa Gonzalez, Gabino Rubio-Bollinger, Nicolas Agrait, Nazario Martin
Constructing electronic circuits containing singly wired molecules is at the frontier of electrical device miniaturisation. Understanding the behaviour of different anchoring groups is key to this goal because of their significant role in determining the properties of the junction.
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Molecules with a sense of logic: a progress report

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1053-1069
DOI: 10.1039/C4CS00342J, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Joakim Andreasson, Uwe Pischel
Ones and zeros can be handled by molecules through the input-control of their signaling features. The progress in this exciting field during the last five years is covered in this tutorial review.
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Synthetic biology for the directed evolution of protein biocatalysts: navigating sequence space intelligently

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1172-1239
DOI: 10.1039/C4CS00351A, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrew Currin, Neil Swainston, Philip J. Day, Douglas B. Kell
Improving enzymes by directed evolution requires the navigation of very large search spaces; we survey how to do this intelligently.
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Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1155-1171
DOI: 10.1039/C4CS00288A, Review ArticleHuawen Huang, Xiaochen Ji, Wanqing Wu, Huanfeng Jiang
The N-oxyenamine internal oxidant gives more chance to investigate the C-H bond activation under mild reaction conditions.
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Ordered nanoparticle arrays interconnected by molecular linkers: electronic and optoelectronic properties

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,999-1014
DOI: 10.1039/C4CS00225C, Review ArticleJianhui Liao, Sander Blok, Sense Jan van der Molen, Sandra Diefenbach, Alexander W. Holleitner, Christian Schonenberger, Anton Vladyka, Michel Calame
Arrays of metal nanoparticles in an organic matrix have attracted a lot of interest due to their diverse electronic and optoelectronic properties.
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How valence bond theory can help you understand your (bio)chemical reaction

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,1037-1052
DOI: 10.1039/C4CS00241E, Tutorial ReviewAvital Shurki, Etienne Derat, Alexandre Barrozo, Shina Caroline Lynn Kamerlin
This Tutorial Review describes modern VB theory, using a didactic example of an SN2 reaction to illustrate its immediate applications.
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Molecular wires - impact of [small pi]-conjugation and implementation of molecular bottlenecks

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,988-998
DOI: 10.1039/C4CS00262H, Review ArticleC. Schubert, J. T. Margraf, T. Clark, D. M. Guldi
We highlight recent progress in the field of electron transport through molecular bridges as integrative parts of electron donor-bridge-acceptor conjugates.
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Single-molecule transistors

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,902-919
DOI: 10.1039/C4CS00231H, Review ArticleMickael L. Perrin, Enrique Burzuri, Herre S. J. van der Zant
Artist impression of a single-molecule transistor, where a molecule is connected to the source and the drain electrodes. The red lines illustrated the electric field caused by the gate electrode, located below.
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Basic concepts of quantum interference and electron transport in single-molecule electronics

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,875-888
DOI: 10.1039/C4CS00203B, Tutorial ReviewC. J. Lambert
This tutorial outlines the basic theoretical concepts and tools which underpin the fundamentals of phase-coherent electron transport through single molecules.
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Current advances in fused tetrathiafulvalene donor-acceptor systems

4 March, 2015 - 15:54

Chem. Soc. Rev., 2015, 44,863-874
DOI: 10.1039/C4CS00255E, Tutorial ReviewJesse J. Bergkamp, Silvio Decurtins, Shi-Xia Liu
Development and applications of tetrathiafulvalene-fused electron donor-acceptor systems will be covered within this tutorial review.
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Progress in asymmetric biomimetic transamination of carbonyl compounds

2 March, 2015 - 15:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00507D, Tutorial ReviewYing Xie, Hongjie Pan, Mao Liu, Xiao Xiao, Yian Shi
Transamination of [small alpha]-keto acids is an important process to form [small alpha]-amino acids in biological systems. Various biomimetic transamination systems have been developed for carbonyl compounds with chiral vitamin B6 analogues, artificial transaminase mimics, chiral nitrogen sources, and chiral catalysts. This review provides a brief summary in this area.
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