Chem. Soc. Rev.

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Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization

21 July, 2014 - 09:17

Chem. Soc. Rev., 2014, 43,5009-5031
DOI: 10.1039/C3CS60447K, Review ArticleDjamaladdin G. Musaev, Travis M. Figg, Alexey L. Kaledin
The C-H functionalization strategies, complexity in Pd-catalyzed chemical transformations, unprecedented Pd-clustering, base (Cs-halide) and weakly coordinated amino acid ligand effects.
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Conceptual DFT: chemistry from the linear response function

21 July, 2014 - 09:17

Chem. Soc. Rev., 2014, 43,4989-5008
DOI: 10.1039/C3CS60456J, Review ArticlePaul Geerlings, Stijn Fias, Zino Boisdenghien, Frank De Proft
This review highlights the evaluation, visualization and interpretation of the linear response function, retrieving physical and chemical concepts like the atomic shell structure, electron delocalisation, aromaticity and anti-aromaticity,....
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Self-assembled capsules based on tetrafunctionalized calix[4]resorcinarene cavitands

15 July, 2014 - 07:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00153B, Review ArticleKenji Kobayashi, Masamichi Yamanaka
The hemispherical structures of calix[4]resorcinarene cavitands are suitable for forming capsular assemblies with guest encapsulations through various intermolecular interactions.
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Recycling of carbon dioxide to methanol and derived products - closing the loop

15 July, 2014 - 07:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00122B, Review ArticleAlain Goeppert, Miklos Czaun, John-Paul Jones, G. K. Surya Prakash, George A. Olah
Possible pathways to recycle CO2 to methanol, dimethyl ether and derived products in a sustainable anthropogenic carbon cycle are discussed.
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Gated molecular baskets

11 July, 2014 - 06:54

Chem. Soc. Rev., 2014, Advance Article
DOI: 10.1039/C4CS00140K, Review ArticleKeith Hermann, Yian Ruan, Alex M. Hardin, Christopher M. Hadad, Jovica D. Badjic
The process of molecular gating is important for controlling the trafficking of guests to and from artificial molecular capsules.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Recent developments of direct rhenium-catalyzed [1,3]-transpositions of allylic alcohols and their silyl ethers

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4381-4394
DOI: 10.1039/C4CS00036F, Tutorial ReviewIvan Volchkov, Daesung Lee
This tutorial review describes recent developments of various allylic transposition strategies involving rhenium-catalyzed rearrangement followed by regio- and stereostereoselective trapping processes and their applications to natural product synthesis.
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The OPEP protein model: from single molecules, amyloid formation, crowding and hydrodynamics to DNA/RNA systems

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4871-4893
DOI: 10.1039/C4CS00048J, Review ArticleFabio Sterpone, Simone Melchionna, Pierre Tuffery, Samuela Pasquali, Normand Mousseau, Tristan Cragnolini, Yassmine Chebaro, Jean-Francois St-Pierre, Maria Kalimeri, Alessandro Barducci, Yoann Laurin, Alex Tek, Marc Baaden, Phuong Hoang Nguyen, Philippe Derreumaux
The OPEP coarse-grained protein model has been applied to a wide range of applications since its first release 15 years ago.
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Chemical sensing of neurotransmitters

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4684-4713
DOI: 10.1039/C3CS60477B, Review ArticleTuhin Pradhan, Hyo Sung Jung, Joo Hee Jang, Tae Woo Kim, Chulhun Kang, Jong Seung Kim
This review focuses on the chemosensors for neurotransmitters published for the last 12 years, covering biogenic amines (dopamine, epinephrine, norepinephrine, serotonin, histamine and acetylcholine), amino acids (glutamate, aspartate, GABA, glycine and tyrosine), and adenosine.
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Catalytic bismetallative multicomponent coupling reactions: scope, applications, and mechanisms

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4368-4380
DOI: 10.1039/C3CS60482A, Tutorial ReviewHee Yeon Cho, James P. Morken
This review covers the bis-metallative coupling of unsaturated functional groups under the agency of transition metal catalysts.
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Structural modification strategies for the rational design of red/NIR region BODIPYs

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4778-4823
DOI: 10.1039/C4CS00030G, Review ArticleHua Lu, John Mack, Yongchao Yang, Zhen Shen
The structure-property relationships of red/NIR region BODIPY dyes is analyzed, so that trends in their photophysical properties can be readily compared.
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AIE macromolecules: syntheses, structures and functionalities

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4494-4562
DOI: 10.1039/C4CS00044G, Review ArticleRongrong Hu, Nelson L. C. Leung, Ben Zhong Tang
A comprehensive review of macromolecules with aggregation-induced emission attributes is presented, covering the frontiers of syntheses, structures, functionalities and applications.
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Atomistic simulation of transport phenomena in nanoelectronic devices

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4357-4367
DOI: 10.1039/C4CS00084F, Tutorial ReviewMathieu Luisier
This paper presents a sophisticated approach to treat quantum transport in nanostructures, covering the basic equations up to relevant applications.
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Anti-cancer palladium complexes: a focus on PdX2L2, palladacycles and related complexes

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4751-4777
DOI: 10.1039/C4CS00063C, Review ArticleAnant R. Kapdi, Ian J. S. Fairlamb
Much success has been achieved with platinum-based chemotherapeutic agents, i.e. through interactions with DNA. The long-term application of Pt complexes is thwarted by issues, leading scientists to examine other metals such as palladium which could exhibit complementary modes of action.
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Macro-/micro-environment-sensitive chemosensing and biological imaging

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4563-4601
DOI: 10.1039/C4CS00051J, Review ArticleZhigang Yang, Jianfang Cao, Yanxia He, Jung Ho Yang, Taeyoung Kim, Xiaojun Peng, Jong Seung Kim
We have summarized the research progress on fluorescent sensors responsive to environmental factors, including local viscosity, polarity, temperature, hypoxia and pH.
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Applications of Bartoli indole synthesis

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4728-4750
DOI: 10.1039/C4CS00045E, Review ArticleGiuseppe Bartoli, Renato Dalpozzo, Monica Nardi
Bartoli indole synthesis is the reaction of choice for the synthesis of many biologically interesting 7-substituted indoles.
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Porous carbon spheres and monoliths: morphology control, pore size tuning and their applications as Li-ion battery anode materials

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4341-4356
DOI: 10.1039/C4CS00071D, Tutorial ReviewAled D. Roberts, Xu Li, Haifei Zhang
Various synthetic techniques are employed to fabricate porous carbon spheres and monoliths for improved performance as Li-ion battery anode materials.
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Organic nanophotonics: from controllable assembly of functional molecules to low-dimensional materials with desired photonic properties

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4325-4340
DOI: 10.1039/C4CS00098F, Tutorial ReviewYongli Yan, Yong Sheng Zhao
The tutorial review aims to provide an insight into the relationship among opto-functional molecules, controllable assembly, diverse nanostructures and photonic properties, which can further guide the function-oriented design and synthesis of low-dimensional materials for integrated photonic devices.
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Nanoparticles meet electrospinning: recent advances and future prospects

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4423-4448
DOI: 10.1039/C3CS60426H, Review ArticleChuan-Ling Zhang, Shu-Hong Yu
In this critical review, the latest advances on nanoparticles-electrospun fibres by post-treatment of the as-prepared electrospun fibres or directly adding nanoparticles into electrospun solution have been overviewed. The application potentials of the nanoparticle-electrospun fibre composites and the trends in this emerging field have been described.
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Structure of organic solids at low temperature and high pressure

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4300-4311
DOI: 10.1039/C4CS00046C, Tutorial ReviewRachael Lee, Judith A. K. Howard, Michael R. Probert, Jonathan W. Steed
This tutorial review summarises the current state of the art in low temperature and high pressure crystallography of molecular organic and coordination compounds.
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Garnet-type solid-state fast Li ion conductors for Li batteries: critical review

7 July, 2014 - 05:54

Chem. Soc. Rev., 2014, 43,4714-4727
DOI: 10.1039/C4CS00020J, Review ArticleVenkataraman Thangadurai, Sumaletha Narayanan, Dana Pinzaru
This review covers the research developments in the last decade on the most favored fast Li ion conducting garnet-type metal oxides for all-solid-state Li ion batteries.
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