Chem. Soc. Rev.
Mechanochemistry of fullerenes and related materials
DOI: 10.1039/C3CS35494F, Review ArticleSan-E Zhu, Fei Li, Guan-Wu Wang
Functionalizations of fullerenes and related materials have been achieved by ball milling and hand grinding.
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Categories: Royal Society of Chemistry
Responsive hydrogels - structurally and dimensionally optimized smart frameworks for applications in catalysis, micro-system technology and material science
DOI: 10.1039/C3CS60031A, Review ArticleArtjom Doring, Wolfgang Birnbaum, Dirk Kuckling
The review covers the most recent developments in the field of responsive hydrogels focussing on catalysis, sensors and actuators.
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The modern interpretation of the Wittig reaction mechanism
DOI: 10.1039/C3CS60105F, Review ArticlePeter A. Byrne, Declan G. Gilheany
Li salt-free Wittig reactions of all ylide types occur under kinetic control, and by a common [2+2] cycloaddition mechanism in which oxaphosphetane is the first-formed and only intermediate.
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Mechanochemical organic synthesis
DOI: 10.1039/C3CS35526H, Review ArticleGuan-Wu Wang
Various solvent-free mechanochemical organic reactions can be realized by ball milling techniques.
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Application of mass spectrometric techniques to delineate the modes-of-action of anticancer metallodrugs
DOI: 10.1039/C3CS35532B, Review ArticleChristian G. Hartinger, Michael Groessl, Samuel M. Meier, Angela Casini, Paul J. Dyson
Mass spectrometric methods are increasingly being used to help elucidate the modes of action of metal-based anticancer agents. Nascent developments and recent applications are discussed in this review.
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Glycoclusters on oligonucleotide and PNA scaffolds: synthesis and applications
DOI: 10.1039/C2CS35406C, Tutorial ReviewNicolas Spinelli, Eric Defrancq, Francois Morvan
Oligonucleotide glycocluster conjugates are involved in several approaches for cellular delivery, carbohydrate microarray or supramolecular glycoclusters.
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Categories: Royal Society of Chemistry
Multivalent glycoconjugates as anti-pathogenic agents
DOI: 10.1039/C2CS35408J, Review ArticleAnna Bernardi, Jesus Jimenez-Barbero, Alessandro Casnati, Cristina De Castro, Tamis Darbre, Franck Fieschi, Jukka Finne, Horst Funken, Karl-Erich Jaeger, Martina Lahmann, Thisbe K. Lindhorst, Marco Marradi, Paul Messner, Antonio Molinaro, Paul V. Murphy, Cristina Nativi, Stefan Oscarson, Soledad Penades, Francesco Peri, Roland J. Pieters, Olivier Renaudet, Jean-Louis Reymond, Barbara Richichi, Javier Rojo, Francesco Sansone, Christina Schaffer, W. Bruce Turnbull, Trinidad Velasco-Torrijos, Sebastien Vidal, Stephane Vincent, Tom Wennekes, Han Zuilhof, Anne Imberty
Glycocompounds interfere with infection and immunity.
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Categories: Royal Society of Chemistry
Clustered carbohydrates in synthetic vaccines
DOI: 10.1039/C2CS35422E, Tutorial ReviewFrancesco Peri
Are there general rules for the design of efficient carbohydrate vaccines? Recent achievements in the field of carbohydrate immunization.
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Categories: Royal Society of Chemistry
Sweet carbon nanostructures: carbohydrate conjugates with carbon nanotubes and graphene and their applications
DOI: 10.1039/C2CS35396B, Tutorial ReviewYanan Chen, Alexander Star, Sebastien Vidal
This review highlights the strategies for the covalent and noncovalent functionalization of carbon nanostructures with carbohydrates and applications in biology.
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Categories: Royal Society of Chemistry
Multivalency in heterogeneous glycoenvironments: hetero-glycoclusters, -glycopolymers and -glycoassemblies
DOI: 10.1039/C2CS35219B, Tutorial ReviewJose L. Jimenez Blanco, Carmen Ortiz Mellet, Jose M. Garcia Fernandez
"Shuffled", multidomain and fluidic displays of different glycotopes allow assessing the effect of heterogeneity in carbohydrate-lectin or -antibody interactions.
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Categories: Royal Society of Chemistry
Chemical routes to top-down nanofabrication
DOI: 10.1039/C3CS60113G, Tutorial ReviewHai-Dong Yu, Michelle D. Regulacio, Enyi Ye, Ming-Yong Han
This tutorial review summarizes the different chemical routes to top-down nanofabrication that have enabled the construction of three-dimensional nanostructures with unique structural features and promising applications.
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Near-infrared phosphorescence: materials and applications
DOI: 10.1039/C3CS60029G, Review ArticleHaifeng Xiang, Jinghui Cheng, Xiaofeng Ma, Xiangge Zhou, Jason Joseph Chruma
An overview of the latest developments and applications in the field of room-temperature near-infrared phosphorescent transition-metal complexes is given.
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From powder to technical body: the undervalued science of catalyst scale up
DOI: 10.1039/C3CS60076A, Review ArticleSharon Mitchell, Nina-Luisa Michels, Javier Perez-Ramirez
This review examines the complexity associated with the scale up of heterogeneous catalysts, proposing directions to strengthen the fundamental understanding of this exciting, but often neglected field.
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Alkaline polymer electrolyte membranes for fuel cell applications
DOI: 10.1039/C3CS60053J, Review ArticleYan-Jie Wang, Jinli Qiao, Ryan Baker, Jiujun Zhang
In this review, we examine the most recent progress in the area of alkaline polymer electrolyte membrane (PEM) development in terms of material selection, synthesis, characterization, and theoretical approach, as well as their fabrication into alkaline PEM-based membrane electrode assemblies and the corresponding fuel cell performance.
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Magnetic responsive polymer composite materials
DOI: 10.1039/C3CS60058K, Tutorial ReviewJulie Thevenot, Hugo Oliveira, Olivier Sandre, Sebastien Lecommandoux
Magnetic responsive materials and their potential breakthrough applications in the biomedical, coatings, microfluidics and microelectronics fields are highlighted in this review.
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Stimuli responsive synthetic polypeptides derived from N-carboxyanhydride (NCA) polymerisation
DOI: 10.1039/C3CS60063G, Review ArticleJin Huang, Andreas Heise
Advanced polymerisation and modification approaches have opened new avenues to produce novel biologically inspired responsive synthetic polypeptides.
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Proteotyping for the rapid identification of influenza virus and other biopathogens
DOI: 10.1039/C3CS60081E, Tutorial ReviewKevin M. Downard
A new proteotyping approach to characterise the influenza virus, and by extension other biopathogens, through the detection of signature peptides.
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Multivalent scaffolds in glycoscience: an overview
DOI: 10.1039/C3CS90029K, EditorialOlivier Renaudet, Rene Roy
Guest editors Olivier Renaudet and Rene Roy introduce the Multivalent scaffolds in glycosciences themed issue of Chemical Society Reviews.
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Categories: Royal Society of Chemistry
Ubiquitous trisulfur radical anion: fundamentals and applications in materials science, electrochemistry, analytical chemistry and geochemistry
DOI: 10.1039/C3CS60119F, Tutorial ReviewTristram Chivers, Philip J. W. Elder
The fundamental chemistry and multi-faceted influence of the paramagnetic, deep blue sulfur species [S3][radical dot]- in materials science, electrochemistry, analytical chemistry and geochemistry are discussed.
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Dendritic architectures based on bis-MPA: functional polymeric scaffolds for application-driven research
DOI: 10.1039/C3CS60101C, Review ArticleAnna Carlmark, Eva Malmstrom, Michael Malkoch
This review covers the array of synthetic methodologies as well as potential applications of dendritic architectures based on bis-MPA.
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