Chem. Soc. Rev.

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Supramolecular polymers constructed by orthogonal self-assembly based on host-guest and metal-ligand interactions

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00327F, Review ArticlePeifa Wei, Xuzhou Yan, Feihe Huang
This review describes recent progress in the orthogonal construction of supramolecular polymers based on host-guest and metal coordination interactions.
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Emergence of fiber supercapacitors

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00286E, Tutorial ReviewDingshan Yu, Qihui Qian, Li Wei, Wenchao Jiang, Kunli Goh, Jun Wei, Jie Zhang, Yuan Chen
Fiber supercapacitors utilizing one-dimensional cylindrically shaped fibers as electrodes have shown great application potential in wearable electronics and smart textiles.
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Transition metal-catalyzed C-H functionalization of N-oxyenamine internal oxidants

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00288A, Review ArticleHuawen Huang, Xiaochen Ji, Wanqing Wu, Huanfeng Jiang
The N-oxyenamine internal oxidant gives more chance to investigate the C-H bond activation under mild reaction conditions.
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Surface chemical-modification for engineering the intrinsic physical properties of inorganic two-dimensional nanomaterials

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00302K, Tutorial ReviewYuqiao Guo, Kun Xu, Changzheng Wu, Jiyin Zhao, Yi Xie
This tutorial review summarizes the recent advances in engineering the intrinsic physical properties of inorganic two-dimensional nanomaterials by surface chemical modification.
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Electrosprayed nanoparticles and electrospun nanofibers based on natural materials: applications in tissue regeneration, drug delivery and pharmaceuticals

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00226A, Review ArticleRadhakrishnan Sridhar, Rajamani Lakshminarayanan, Kalaipriya Madhaiyan, Veluchamy Amutha Barathi, Keith Hsiu Chin Lim, Seeram Ramakrishna
The role of electrospun and electrosprayed natural polymers or drug ingredients for pharmaceutical and tissue engineering applications is presented in this review.
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Carbon nanomaterials: multi-functional agents for biomedical fluorescence and Raman imaging

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00306C, Review ArticleJ. Bartelmess, S. J. Quinn, S. Giordani
This review article gives a comparative overview over carbon nanomaterials utilized for in vitro as well as in vivo fluorescence and Raman imaging, including multi-functional theranostic approaches.
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Silica-based nanoparticles: a versatile tool for the development of efficient imaging agents

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00270A, Review ArticleClaudia Caltagirone, Alexandre Bettoschi, Alessandra Garau, Riccardo Montis
In this review a selection of the most recent examples of imaging techniques applied to silica-based NPs for imaging is reported.
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Fluorescent, MRI, and colorimetric chemical sensors for the first-row d-block metal ions

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00285G, Review ArticleHao Zhu, Jiangli Fan, Benhua Wang, Xiaojun Peng
This critical review focuses on the development of fluorescent sensors (fall into three classes: "turn-off", "turn-on", and ratiometric), colorimetric sensors, and responsive MRI contrast agents for the first-row d-block metals (except Cu and Zn): Cr, Mn, Fe, Co, and Ni (242 references).
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Atomically-thin two-dimensional sheets for understanding active sites in catalysis

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00236A, Tutorial ReviewYongfu Sun, Shan Gao, Fengcai Lei, Yi Xie
Atomically-thin two-dimensional sheets can serve as an ideal model to disclose the role of active sites in catalysis.
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Biosensing by luminogens with aggregation-induced emission characteristics

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00325J, Tutorial ReviewRyan T. K. Kwok, Chris W. T. Leung, Jacky W. Y. Lam, Ben Zhong Tang
This tutorial review outlines the concept of aggregation-induced emission and its utility in biosensing applications.
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Integrative self-sorting: a versatile strategy for the construction of complex supramolecular architecture

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00305E, Review ArticleZhenfeng He, Wei Jiang, Christoph A. Schalley
Integrative self-sorting expands the concepts of self-assembly and allows the programming of supramolecular architecture on a higher level of complexity.
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Ordered nanoparticle arrays interconnected by molecular linkers: electronic and optoelectronic properties

27 November, 2014 - 16:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00225C, Review ArticleJianhui Liao, Sander Blok, Sense Jan van der Molen, Sandra Diefenbach, Alexander W. Holleitner, Christian Schonenberger, Anton Vladyka, Michel Calame
Arrays of metal nanoparticles in an organic matrix have attracted a lot of interest due to their diverse electronic and optoelectronic properties.
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Understanding catalysis

27 November, 2014 - 16:17

Chem. Soc. Rev., 2014, 43,8226-8239
DOI: 10.1039/C4CS00210E, Tutorial ReviewEmil Roduner
Catalysts often perform miraculous transformations of reactants A to very different products P in seemingly a single step. Such catalysts appear as a black box. This tutorial shows how we can shine light into this black box and understand the reaction mechanism. In particular, it aims at explaining some of the fundamental principles of the action of a catalyst.
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Jack of all trades: versatile catechol crosslinking mechanisms

27 November, 2014 - 16:17

Chem. Soc. Rev., 2014, 43,8271-8298
DOI: 10.1039/C4CS00185K, Review ArticleJuan Yang, Martien A. Cohen Stuart, Marleen Kamperman
This review discusses the versatile and complex chemistry of catechols, detailing the various mechanisms and affecting parameters under different reaction conditions.
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Towards polymetallic lanthanide complexes as dual contrast agents for magnetic resonance and optical imaging

27 November, 2014 - 16:17

Chem. Soc. Rev., 2014, 43,8178-8192
DOI: 10.1039/C4CS00201F, Review ArticleElke Debroye, Tatjana N. Parac-Vogt
In the spotlight: polymetallic complexes permitting efficient sensitization of lanthanide luminescence and exhibiting favorable relaxometric properties.
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Artificial photosynthesis over graphene-semiconductor composites. Are we getting better?

27 November, 2014 - 16:17

Chem. Soc. Rev., 2014, 43,8240-8254
DOI: 10.1039/C4CS00213J, Review ArticleMin-Quan Yang, Nan Zhang, Mario Pagliaro, Yi-Jun Xu
This review highlights a few problems associated with improving the photocatalytic performance of semiconductors via methodological coupling with graphene (GR) and particularly addresses the strategies for harnessing the structure and electronic conductivity of GR, which is hoped to advance the research in designing the next-generation artificial photosynthesis systems based on GR-semiconductor composites with high performance.
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Transition-metal-free C-C bond forming reactions of aryl, alkenyl and alkynylboronic acids and their derivatives

27 November, 2014 - 16:17

Chem. Soc. Rev., 2014, 43,8215-8225
DOI: 10.1039/C4CS00195H, Tutorial ReviewS. Roscales, A. G. Csaky
Transition-metal-free C-C bond forming reactions of boronic acids are new emerging tools in organic synthesis which complement metal-based procedures.
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Near-infrared spectroscopy and hyperspectral imaging: non-destructive analysis of biological materials

27 November, 2014 - 16:17

Chem. Soc. Rev., 2014, 43,8200-8214
DOI: 10.1039/C4CS00062E, Tutorial ReviewMarena Manley
Principles, interpretation and applications of near-infrared (NIR) spectroscopy and NIR hyperspectral imaging are reviewed.
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Steam electrolysis by solid oxide electrolysis cells (SOECs) with proton-conducting oxides

27 November, 2014 - 16:17

Chem. Soc. Rev., 2014, 43,8255-8270
DOI: 10.1039/C4CS00194J, Review ArticleLei Bi, Samir Boulfrad, Enrico Traversa
Proton-conducting SOECs enable storage of renewable energies in the form of H2 and provide electricity for various applicators when working reversely.
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Monolithic cells for solar fuels

27 November, 2014 - 16:17

Chem. Soc. Rev., 2014, 43,7963-7981
DOI: 10.1039/C3CS60424A, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jan Ronge, Tom Bosserez, David Martel, Carlo Nervi, Luca Boarino, Francis Taulelle, Gero Decher, Silvia Bordiga, Johan A. Martens
A tutorial review explaining the many processes occurring in photoelectrochemical cells for solar fuel production, and prospects for future developments.
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