Chem. Commun.

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Correction: Modular and orthogonal synthesis of hybrid polymers and networks

16 March, 2015 - 02:54
Chem. Commun., 2015, 51,5534-5534
DOI: 10.1039/C5CC90042E, CorrectionShuang Liu, Kevin T. Dicker, Xinqiao Jia
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Large phenyl-substituted acenes by cycloaddition reactions of the 2,6-naphthodiyne synthon

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5418-5420
DOI: 10.1039/C5CC00205B, CommunicationDiego Rodriguez-Lojo, Dolores Perez, Diego Pena, Enrique Guitian
Diverse large acenes with promising photoelectronic properties can be obtained simply by bisaryne cycloadditions.
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DNA-aptamer gating membranes

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5471-5474
DOI: 10.1039/C4CC09660F, CommunicationThomas Schafer, Veli Cengiz Ozalp
This report describes a membrane barrier whose permeability is modulated through the recognition of a small-molecule target, adenosine triphosphate (ATP), by a DNA-aptamer.
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Probing post-synthetic metallation in metal-organic frameworks: insights from X-ray crystallography

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5486-5489
DOI: 10.1039/C4CC09639H, CommunicationWitold M. Bloch, Alexandre Burgun, Christian J. Doonan, Christopher J. Sumby
Post-synthetic metallation is a key route to modifying MOFs but as shown here the choice of solvent affects the extent of reaction and the form of the metallated product.
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A modular DNA origami-based enzyme cascade nanoreactor

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5351-5354
DOI: 10.1039/C4CC08472A, CommunicationVeikko Linko, Marika Eerikainen, Mauri A. Kostiainen
In this communication, we present a nanoscale reactor assembled from tuneable and spatially addressable tubular DNA origami units.
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Target profiling of zerumbone using a novel cell-permeable clickable probe and quantitative chemical proteomics

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5497-5500
DOI: 10.1039/C4CC09527H, CommunicationKarunakaran A. Kalesh, James A. Clulow, Edward W. Tate
The first target profile for zerumbone in live cancer cells determined through quantitative competitive chemical proteomics with a cell-permeable probe.
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Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5257-5260
DOI: 10.1039/C4CC08656B, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.K. Ackermann, A. Giannoulis, D. B. Cordes, A. M. Z. Slawin, B. E. Bode
Pulsed electron paramagnetic resonance (EPR) spectroscopy is used for titrating spin-labelled terpyridine with Zn(II)-solution to study complex formation. This system can serve as a small-molecule model system for tuneable dimerisation.
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Synthetic peptides caged on histidine residues with a bisbipyridyl ruthenium(II) complex that can be photolyzed by visible light

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5501-5504
DOI: 10.1039/C4CC08049A, CommunicationJesus Mosquera, Mateo I. Sanchez, Jose L. Mascarenas, M. Eugenio Vazquez
We report a light-sensitive histidine building block for Fmoc/tBu solid-phase peptide synthesis in which the imidazole side chain is coordinated to a ruthenium complex.
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Enhanced reactivity of dendrons in the Passerini three-component reaction

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5456-5459
DOI: 10.1039/C4CC10091C, CommunicationJo-Ann Jee, Shuang Song, Jonathan G. Rudick
An unexpected substituent effect that accelerates Passerini reactions in THF has enabled the synthesis of three generations of dendrimers.
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An efficient route to highly strained cyclobutenes: indium-catalyzed reactions of enynals with alkynes

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5530-5533
DOI: 10.1039/C4CC08506J, CommunicationRenxiao Liang, Huanfeng Jiang, Shifa Zhu
A catalytic method to synthesize the highly strained cyclobutene was developed. The reaction was believed to proceed through a formal indium-catalyzed [2+2] cycloaddition between electron-deficient enynals and a variety of alkynes.
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Formation and in situ reactions of hypervalent iodonium alkynyl triflates to form cyanocarbenes

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5287-5289
DOI: 10.1039/C4CC08676G, CommunicationI. F. Dempsey Hyatt, Daniel J. Nasrallah, Michael A. Maxwell, A. Christina F. Hairston, Manahil M. Abdalhameed, Mitchell P. Croatt
The conversion of readily available silylalkynes, iodobenzene diacetate, and azide anions was utilized to form and react cyanocarbenes.
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Modular and orthogonal synthesis of hybrid polymers and networks

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5218-5237
DOI: 10.1039/C4CC09568E, Feature ArticleShuang Liu, Kevin T. Dicker, Xinqiao Jia
In this review, we highlight and discuss recent progress in the synthesis of hybrid biomaterials using modular, molecular building blocks and employing novel, bioorthogonal chemistries.
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Determination of receptor specificities for whole influenza viruses using multivalent glycan arrays

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5326-5329
DOI: 10.1039/C4CC08613A, CommunicationMia L. Huang, Miriam Cohen, Christopher J. Fisher, Robert T. Schooley, Pascal Gagneux, Kamil Godula
A multivalent glycan array for interrogating the binding preferences of intact influenza viruses.
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Ethanol induces the formation of water-permeable defects in model bilayers of skin lipids

16 March, 2015 - 02:54

Chem. Commun., 2015, 51,5406-5409
DOI: 10.1039/C4CC08527B, CommunicationR. Thind, D. W. O'Neill, A. Del Regno, R. Notman
We observe that ethanol can induce the formation of water-permeable defects in model bilayers of skin lipids and propose this as a new mechanism of action of ethanol as a membrane modulator.
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