Chem. Commun.

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Inherent anchorages in UiO-66 nanoparticles for efficient capture of alendronate and its mediated release

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8779-8782
DOI: 10.1039/C4CC02570A, CommunicationXiangyang Zhu, Jinlou Gu, Yao Wang, Bing Li, Yongsheng Li, Wenru Zhao, Jianlin Shi
An unprecedented alendronate loading capacity was achieved in UiO-66 nanoparticles thanks to the inherent drug anchorages of Zr-O clusters therein.
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Asymmetric epoxidation of alkenes and benzylic hydroxylation with P450tol monooxygenase from Rhodococcus coprophilus TC-2

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8771-8774
DOI: 10.1039/C4CC03491K, CommunicationAitao Li, Shuke Wu, Joseph P. Adams, Radka Snajdrova, Zhi Li
P450tol monooxygenase was discovered as a unique and highly enantioselective enzyme for asymmetric epoxidation of some terminal alkenes and benzylic hydroxylation of several ethylbenzenes giving the corresponding useful and valuable products in high ee.
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Flexible and practical synthesis of 3-oxyindoles through gold-catalyzed intermolecular oxidation of o-ethynylanilines

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8689-8692
DOI: 10.1039/C4CC03565H, CommunicationChao Shu, Long Li, Xin-Yu Xiao, Yong-Fei Yu, Yi-Fan Ping, Jin-Mei Zhou, Long-Wu Ye
A novel gold-catalyzed intermolecular oxidation of o-ethynylanilines has been developed, which provides a reliable access to synthetically useful 3-oxyindoles. Importantly, this gold-catalyzed oxidative process outcompetes the typical indole formation.
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Self-assembly of gold nanoparticles on deep eutectic solvent (DES) surfaces

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8693-8696
DOI: 10.1039/C4CC02588A, CommunicationV. S. Raghuwanshi, M. Ochmann, F. Polzer, A. Hoell, K. Rademann
Self-assembly of gold nanoparticles in 1st and 2nd shell ordering is observed in a deep eutectic solvent (DES) by SAXS investigations.
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Highly conductive and dispersible graphene and its application in P3HT-based solar cells

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8705-8708
DOI: 10.1039/C4CC03692A, CommunicationTahmineh Mahmoudi, Won-Yeop Rho, Hwa-Young Yang, S. Ravi P. Silva, Yoon-Bong Hahn
Structure of an inverted solar cell with the P3HT-PCA-rGO hybrid in the active layer and graphene oxide as the hole transport layer.
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Conjugates of tetraphenylethene and diketopyrrolopyrrole: tuning the emission properties with phenyl bridges

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8747-8750
DOI: 10.1039/C4CC03024A, CommunicationXiao Yuan Shen, Yi Jia Wang, Haoke Zhang, Anjun Qin, Jing Zhi Sun, Ben Zhong Tang
Bridging DPP (ACQ-gen) and TPE (AIE-gen) with phenyls derived TPE-ph-DPP conjugates displaying enhanced and red-shifted emission in the solid state.
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Novel topotactically transformed carbon-CoO-NiO-NiCo2O4 nanosheet hybrid hetero-structured arrays as ultrahigh performance supercapacitors

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8697-8700
DOI: 10.1039/C4CC01965B, CommunicationHai Wang, Junling Guo, Chen Qing, Daming Sun, Bixiao Wang, Yiwen Tang
A novel carbon-CoO-NiO-NiCo2O4 integrated electrode was designed and synthesized from NiCo2O4 in a topotactical transformation. Such unique nanoarchitectures exhibit excellent electrochemical performance with ultrahigh capacitance.
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A colorimetric and near-infrared fluorescent probe with high sensitivity and selectivity for acid phosphatase and inhibitor screening

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8677-8680
DOI: 10.1039/C3CC49254K, CommunicationYongqian Xu, Benhao Li, Liangliang Xiao, Jia Ouyang, Shiguo Sun, Yi Pang
A dual-channel including a colorimetric and fluorescent probe based on the aggregation-caused quenching (ACQ) and enzymolysis approach has been presented to screen acid phosphatase (ACP) and its inhibitor.
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Identification of novel inhibitors that disrupt STAT3-DNA interaction from a [gamma]-AApeptide OBOC combinatorial library

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8739-8742
DOI: 10.1039/C4CC03909B, CommunicationPeng Teng, Xiaolei Zhang, Haifan Wu, Qiao Qiao, Said M. Sebti, Jianfeng Cai
[gamma]-AApeptides identified from a combinatorial library selectively inhibit STAT3-DNA interaction.
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Syntheses and electronic structures of [small mu ]-nitrido bridged pyridine, diimine iridium complexes

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8735-8738
DOI: 10.1039/C4CC03624G, CommunicationFriedrich Angersbach-Bludau, Christopher Schulz, Julia Schoffel, Peter Burger
Oxidation states in late transition metal nitrido complexes.
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A lock-and-key mechanism for the controllable fabrication of DNA origami structures

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8743-8746
DOI: 10.1039/C4CC02244K, CommunicationArivazhagan Rajendran, Masayuki Endo, Kumi Hidaka, Naohiko Shimada, Atsushi Maruyama, Hiroshi Sugiyama
Controllable fabrication of DNA origami structures was achieved using cationic comb-type copolymers as locks and polyvinyl sulphonic acid as a key.
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Synthesis and photovoltaic performances in solution-processed BHJs of oligothiophene-substituted organocobalt complexes [([small eta]4-C4(nT)4)Co([small eta]5-C5H5)]

12 July, 2014 - 11:54

Chem. Commun., 2014, 50,8663-8666
DOI: 10.1039/C4CC03530E, CommunicationGuillaume H. V. Bertrand, Ludovic Tortech, Vincent Gandon, Corinne Aubert, Denis Fichou
New cobalt complexes substituted by four oligothiophene arms have been synthesized. Solution processed solar cells based on CpCoCb(3T)4 exhibit conversion efficiencies of up to 2.1%.
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