Chem. Commun.

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Remote rearrangement of the metal center in a ([small eta]6-C6Me6)Ru(II) complex

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC09699A, CommunicationKoichi Takano, Yousuke Ikeda, Shintaro Kodama, Youichi Ishii
Reaction of [([small eta]6-C6Me6)Ru(Ph)(PMe3)]+ with internal alkynes gave rise to the 1,4-Ru migration to form the o-vinylaryl complex, providing the first example of 1,4-metal migration of a group 8 metal center; in one case further isomerization to an [small eta]3-allyl complex was observed.
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First-principles study of electronic structure and photocatalytic properties of MnNiO3 as an alkaline oxygen-evolution photocatalyst

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08111K, CommunicationJie Yu, Qimin Yan, Wei Chen, Anubhav Jain, Jeffrey B. Neaton, Kristin A. Persson
We present a first-principles study of MnNiO3, a promising oxygen-evolution photocatalyst.
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Metal-organic framework materials for light-harvesting and energy transfer

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC09596K, Feature ArticleMonica C. So, Gary P. Wiederrecht, Joseph E. Mondloch, Joseph T. Hupp, Omar K. Farha
This contribution highlights recent work on the photon collection and energy transport behavior of metal-organic frameworks for excitonic solar cells.
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N, S co-doped graphene quantum dots from a single source precursor used for photodynamic cancer therapy under two-photon excitation

14 January, 2015 - 11:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC09280E, CommunicationRijun Gui, Xifeng Liu, Hui Jin, Zonghua Wang, Feifei Zhang, Jianfei Xia, Min Yang, Sai Bi, Yanzhi Xia
Using polythiophene derivatives as single source precursors, nitrogen (N) and sulfur (S) co-doped graphene quantum dots (NS-GQD) were prepared.
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Discovery of two new classes of potent monoamine oxidase-B inhibitors by tricky chemistry

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08798D, CommunicationF. Cagide, T. Silva, J. Reis, A. Gaspar, F. Borges, L. R. Gomes, J. N. Low
Discovery of monoamine oxidase-B inhibitors based on chromane-2,4-dione and chromone-3-carboxamide scaffolds for the management of neurodegenerative diseases.
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On-surface formation of two-dimensional polymer via direct C-H activation of metal phthalocyanine

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08299K, CommunicationQiang Sun, Chi Zhang, Liangliang Cai, Lei Xie, Qinggang Tan, Wei Xu
From high-resolution UHV-STM imaging and DFT calculations, we successfully obtained a 2D polymer structure formed through direct C-H activation followed by an aryl-aryl coupling of a metal-phthalocyanine (CoPc) on Ag(110).
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Site-specific tagging proteins via a rigid, stable and short thiolether tether for paramagnetic spectroscopic analysis

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08493D, CommunicationYin Yang, Jin-Tao Wang, Ying-Ying Pei, Xun-Cheng Su
The reaction of phenylsulfonated pyridine derivatives and protein thiols is suitable for high-resolution spectroscopic analysis by generation of a rigid, stable and short thiolether tether.
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Contributions to activity enhancement via Fe incorporation in Ni-(oxy)hydroxide/borate catalysts for near-neutral pH oxygen evolution

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08670H, CommunicationAdam M. Smith, Lena Trotochaud, Michaela S. Burke, Shannon W. Boettcher
Increases in the activity of Ni-borate oxygen evolution catalysts with anodic conditioning are accompanied by Fe incorporation from electrolyte impurities; Fe-free films show poor activity.
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Modulating protein-protein interactions: the potential of peptides

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08565E, Feature ArticleLaura Nevola, Ernest Giralt
An updated review focused on the latest progress in the field of peptides as modulators of protein-protein interactions.
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Dependence of crystal size on the catalytic performance of a porous coordination polymer

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07562E, CommunicationTomokazu Kiyonaga, Masakazu Higuchi, Takashi Kajiwara, Yohei Takashima, Jingui Duan, Kazuro Nagashima, Susumu Kitagawa
Submicrosized MOF-76(Yb) exhibits a higher catalytic performance for esterification than microsized MOF-76(Yb).
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Reaction of cyclopropenes with a trichloromethyl radical: unprecedented ring-opening reaction of cyclopropanes with migration

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC09649E, CommunicationMasafumi Ueda, Nobuyoshi Doi, Hitoki Miyagawa, Shoichi Sugita, Norihiko Takeda, Tetsuro Shinada, Okiko Miyata
The triethylborane-mediated direct addition of chloroform to cyclopropenes afforded trichloromethylcyclopropanes. In contrast, the use of dimethylzinc gave the unconjugated diene via ring-opening reactions.
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Enzyme-based logic systems interfaced with signal-responsive materials and electrodes

14 January, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC09851J, Feature ArticleEvgeny Katz, Sergiy Minko
Enzyme-based biocomputing systems were interfaced with signal-responsive membranes and electrodes resulting in bioelectronic devices switchable by logically processed biomolecular signals.
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